IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v239y2022ipes0360544221025962.html
   My bibliography  Save this article

Thermodynamic and kinetic modeling of a novel polyamine-based solvent for energy-efficient CO2 capture with energy analysis

Author

Listed:
  • Jung, Wonho
  • Lee, Jinwon

Abstract

Polyamine-based solvents (PSs) are regarded to be emerging energy-efficient alternatives to conventional solvents for use in absorption-based CO2 capture. In this paper, we propose a novel polyamine, 3,3′-iminobis (N,N-dimethylpropylamine) (IBDMPA), based aqueous amine solution. The solvent was composed of 45 wt% IBDMPA and 48 wt% water, with a non-amine chemical making up the rest of the mixture. Thermodynamic modeling work of CO2 solubility was carried out using Aspen Plus® V10, and the Elec-NRTL model with the Redlick-Kwong equation was integrated with the equilibrium model. For CO2 solubility modeling, measurement data was obtained from the equilibrium cell and 1H/13C nuclear magnetic resonance and used to validate the CO2 solubility modeling. Kinetic modeling of the proposed PS was conducted using a tertiary amine reaction mechanism, and the measurement data for the overall mass transfer coefficient was obtained using a wetted wall column. PS has cyclic capacity of approximately 1.05 mol-CO2/mol-IBD and overall mass transfer coefficient of 2.51e-03 mol m−2 kPa−1 sec−1, which is much higher than that of conventional MEA 30 wt% solution (0.35 mol-CO2/mol-MEA and 1.05e-03 mol m−2 kPa−1 sec−1). As a result, the minimum energy required for reboiler was calculated to be 2.3 GJ t-CO2−1 at 1 bara of the desorber pressure. Such a low energy demand value supports the commercial feasibility of polyamine-based solvents for large-scale CO2 capture.

Suggested Citation

  • Jung, Wonho & Lee, Jinwon, 2022. "Thermodynamic and kinetic modeling of a novel polyamine-based solvent for energy-efficient CO2 capture with energy analysis," Energy, Elsevier, vol. 239(PE).
    • Handle: RePEc:eee:energy:v:239:y:2022:i:pe:s0360544221025962
    DOI: 10.1016/j.energy.2021.122347
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221025962
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.122347?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Jung, Wonho & Park, Junhyung & Won, Wangyun & Lee, Kwang Soon, 2018. "Simulated moving bed adsorption process based on a polyethylenimine-silica sorbent for CO2 capture with sensible heat recovery," Energy, Elsevier, vol. 150(C), pages 950-964.
    2. Chu, Fengming & Yang, Lijun & Du, Xiaoze & Yang, Yongping, 2016. "CO2 capture using MEA (monoethanolamine) aqueous solution in coal-fired power plants: Modeling and optimization of the absorbing columns," Energy, Elsevier, vol. 109(C), pages 495-505.
    3. Michaelides, Efstathios E., 2021. "Thermodynamic analysis and power requirements of CO2 capture, transportation, and storage in the ocean," Energy, Elsevier, vol. 230(C).
    4. Jung, Wonho & Lee, Kwang Soon, 2019. "Novel short-cut estimation method for the optimum total energy demand of solid sorbents in an adsorption-based CO2 capture process," Energy, Elsevier, vol. 180(C), pages 640-648.
    5. Hosseini-Ardali, Seyed Mohsen & Hazrati-Kalbibaki, Majid & Fattahi, Moslem & Lezsovits, Ferenc, 2020. "Multi-objective optimization of post combustion CO2 capture using methyldiethanolamine (MDEA) and piperazine (PZ) bi-solvent," Energy, Elsevier, vol. 211(C).
    6. Mores, Patricia & Scenna, Nicolás & Mussati, Sergio, 2012. "CO2 capture using monoethanolamine (MEA) aqueous solution: Modeling and optimization of the solvent regeneration and CO2 desorption process," Energy, Elsevier, vol. 45(1), pages 1042-1058.
    7. Wu, Jiafeng & Chen, Yaping & Zhu, Zilong & Zheng, Shuxing, 2020. "Analysis on full CO2 capture schemes in NG/O2 combustion gas and steam mixture cycle (GSMC)," Energy, Elsevier, vol. 191(C).
    8. Wang, Junyao & Sun, Taiwei & Zhao, Jun & Deng, Shuai & Li, Kaixiang & Xu, Yaofeng & Fu, Jianxin, 2019. "Thermodynamic considerations on MEA absorption: Whether thermodynamic cycle could be used as a tool for energy efficiency analysis," Energy, Elsevier, vol. 168(C), pages 380-392.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Neha Agarwal & Le Cao Nhien & Moonyong Lee, 2022. "Rate-Based Modeling and Assessment of an Amine-Based Acid Gas Removal Process through a Comprehensive Solvent Selection Procedure," Energies, MDPI, vol. 15(18), pages 1-17, September.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zheng, Yawen & Gao, Lin & He, Song, 2023. "Analysis of the mechanism of energy consumption for CO2 capture in a power system," Energy, Elsevier, vol. 262(PA).
    2. Zhang, Rui & Yang, Qi & Yu, Bing & Yu, Hai & Liang, Zhiwu, 2018. "Toward to efficient CO2 capture solvent design by analyzing the effect of substituent type connected to N-atom," Energy, Elsevier, vol. 144(C), pages 1064-1072.
    3. Zhao, Jun & Fu, Jianxin & Deng, Shuai & Wang, Junyao & Xu, Yaofeng, 2020. "Decoupled thermal-driven absorption-based CO2 capture into heat engine plus carbon pump: A new understanding with the case study," Energy, Elsevier, vol. 210(C).
    4. Zhang, Minkai & Guo, Yincheng, 2013. "Rate based modeling of absorption and regeneration for CO2 capture by aqueous ammonia solution," Applied Energy, Elsevier, vol. 111(C), pages 142-152.
    5. Chu, Fengming & Yang, Lijun & Du, Xiaoze & Yang, Yongping, 2017. "Mass transfer and energy consumption for CO2 absorption by ammonia solution in bubble column," Applied Energy, Elsevier, vol. 190(C), pages 1068-1080.
    6. Li, Xiaoqiang & Ding, Yudong & Guo, Liheng & Liao, Qiang & Zhu, Xun & Wang, Hong, 2019. "Non-aqueous energy-efficient absorbents for CO2 capture based on porous silica nanospheres impregnated with amine," Energy, Elsevier, vol. 171(C), pages 109-119.
    7. Zhou, Xiaobin & Liu, Chao & Fan, Yinming & Zhang, Lihao & Tang, Shen & Mo, Shengpeng & Zhu, Yinian & Zhu, Zongqiang, 2022. "Energy-efficient carbon dioxide capture using a novel low-viscous secondary amine-based nonaqueous biphasic solvent: Performance, mechanism, and thermodynamics," Energy, Elsevier, vol. 255(C).
    8. Li, Bao-Hong & Zhang, Nan & Smith, Robin, 2016. "Simulation and analysis of CO2 capture process with aqueous monoethanolamine solution," Applied Energy, Elsevier, vol. 161(C), pages 707-717.
    9. Doh Dinga, Christian & Wen, Zongguo, 2021. "Many-objective optimization of energy conservation and emission reduction in China’s cement industry," Applied Energy, Elsevier, vol. 304(C).
    10. Zhou, Xiang & Li, Xiuluan & Shen, Dehuang & Shi, Lanxiang & Zhang, Zhien & Sun, Xinge & Jiang, Qi, 2022. "CO2 huff-n-puff process to enhance heavy oil recovery and CO2 storage: An integration study," Energy, Elsevier, vol. 239(PB).
    11. Han, Siyu & Meng, Yuan & Aihemaiti, Aikelaimu & Gao, Yuchen & Ju, Tongyao & Xiang, Honglin & Jiang, Jianguo, 2022. "Biogas upgrading with various single and blended amines solutions: Capacities and kinetics," Energy, Elsevier, vol. 253(C).
    12. Choe, Bomin & Lee, Shinje & Won, Wangyun, 2020. "Process integration and optimization for economical production of commodity chemicals from lignocellulosic biomass," Renewable Energy, Elsevier, vol. 162(C), pages 242-248.
    13. Kim, Seonggon & Ko, Yunmo & Lee, Geun Jeong & Lee, Jae Won & Xu, Ronghuan & Ahn, Hyungseop & Kang, Yong Tae, 2023. "Sustainable energy harvesting from post-combustion CO2 capture using amine-functionalized solvents," Energy, Elsevier, vol. 267(C).
    14. Abd, Ammar Ali & Othman, Mohd Roslee & Helwani, Zuchra & Kim, Jinsoo, 2023. "Waste to wheels: Performance comparison between pressure swing adsorption and amine-absorption technologies for upgrading biogas containing hydrogen sulfide to fuel grade standards," Energy, Elsevier, vol. 272(C).
    15. A. G. Olabi & Tabbi Wilberforce & Enas Taha Sayed & Nabila Shehata & Abdul Hai Alami & Hussein M. Maghrabie & Mohammad Ali Abdelkareem, 2022. "Prospect of Post-Combustion Carbon Capture Technology and Its Impact on the Circular Economy," Energies, MDPI, vol. 15(22), pages 1-38, November.
    16. Ding, Hongbing & Zhang, Yu & Sun, Chunqian & Yang, Yan & Wen, Chuang, 2022. "Numerical simulation of supersonic condensation flows using Eulerian-Lagrangian and Eulerian wall film models," Energy, Elsevier, vol. 258(C).
    17. Song, Yawei & Su, Sheng & Liu, Yushuai & Zhao, Zheng & Xu, Kai & Xu, Jun & Jiang, Long & Wang, Yi & Hu, Song & Xiang, Jun, 2024. "Characteristics of OH formation during single coal particle ignition and volatile combustion in O2/N2 and O2/CO2 atmospheres," Energy, Elsevier, vol. 288(C).
    18. Hegazy Rezk & Basem Alamri & Mokhtar Aly & Ahmed Fathy & Abdul G. Olabi & Mohammad Ali Abdelkareem & Hamdy A. Ziedan, 2021. "Multicriteria Decision-Making to Determine the Optimal Energy Management Strategy of Hybrid PV–Diesel Battery-Based Desalination System," Sustainability, MDPI, vol. 13(8), pages 1-19, April.
    19. Dutta, Rohan & Nord, Lars O. & Bolland, Olav, 2017. "Selection and design of post-combustion CO2 capture process for 600 MW natural gas fueled thermal power plant based on operability," Energy, Elsevier, vol. 121(C), pages 643-656.
    20. Efstathios E. Michaelides, 2021. "Thermodynamics, Energy Dissipation, and Figures of Merit of Energy Storage Systems—A Critical Review," Energies, MDPI, vol. 14(19), pages 1-41, September.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:239:y:2022:i:pe:s0360544221025962. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.