IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v234y2021ics0360544221014961.html
   My bibliography  Save this article

Promoted stable combustion of alcohol-based fuel accompanied by inhibition of Leidenfrost effect in a wide temperature range

Author

Listed:
  • Zhao, Zhengchuang
  • Huang, Xiaobin
  • Sheng, Haoqiang
  • Chen, Zhijia
  • Liu, Hong

Abstract

Combustion of bio-alcohols helps alleviate energy crisis and environmental pollution. However, the Leidenfrost effect (LE) of alcohols triggered by the adiabatic vapor layer greatly reduces the heat transfer efficiency, which makes alcohols exhibit a long ignition delay time (IDT) at low temperatures, hindering energy efficiency and clean combustion. Here, we first develop a scalable strategy to inhibit LE via self-propagating oxidation heat release and concomitant in-situ active radical generation. Reliable ignition and stable combustion of alcohol-based fuels are achieved in a wide temperature range by using a reactive organometallic compound methoxydiethylborane (MDEB). The theoretically released heat of MDEB self-oxidation is two orders of magnitude greater than the evaporation latent heat of ethanol or n-decane by thermodynamic calculation. Experiments show that the flammable temperature limits of MDEB/ethanol and MDEB/ethanol/n-decane are extended to 225 and 125 °C, which dropped by 370 and 465 °C, respectively. Moreover, the IDT of MDEB/ethanol/n-decane hybrid fuel significantly decreases to 27 ms. The 100% ignition achievement and disappearance of negative temperature behavior highlight the reliable start-up in the Liedenfrost region. This work thus provides a promising tool for promoting the ignition reliability and combustion stability of alcohols for ICEs at low temperatures, as well as pollutant control.

Suggested Citation

  • Zhao, Zhengchuang & Huang, Xiaobin & Sheng, Haoqiang & Chen, Zhijia & Liu, Hong, 2021. "Promoted stable combustion of alcohol-based fuel accompanied by inhibition of Leidenfrost effect in a wide temperature range," Energy, Elsevier, vol. 234(C).
  • Handle: RePEc:eee:energy:v:234:y:2021:i:c:s0360544221014961
    DOI: 10.1016/j.energy.2021.121248
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221014961
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2021.121248?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Liu, Guibin & Ruan, Can & Li, Zilong & Huang, Guan & Zhou, Qiyan & Qian, Yong & Lu, Xingcai, 2020. "Investigation of engine performance for alcohol/kerosene blends as in spark-ignition aviation piston engine," Applied Energy, Elsevier, vol. 268(C).
    2. Niven, Robert K., 2005. "Ethanol in gasoline: environmental impacts and sustainability review article," Renewable and Sustainable Energy Reviews, Elsevier, vol. 9(6), pages 535-555, December.
    3. Liu, Yang & Tang, Chenglong & Zhan, Cheng & Wu, Yingtao & Yang, Meng & Huang, Zuohua, 2019. "Low temperature auto-ignition characteristics of methylcyclohexane/ethanol blend fuels: Ignition delay time measurement and kinetic analysis," Energy, Elsevier, vol. 177(C), pages 465-475.
    4. Li, Xiaojie & Huang, Xiaobin & Liu, Hong & Du, Jianke, 2020. "Fuel reactivity controlled self-starting and propulsion performance of a scramjet: A model investigation," Energy, Elsevier, vol. 195(C).
    5. Ivan U. Vakarelski & Neelesh A. Patankar & Jeremy O. Marston & Derek Y. C. Chan & Sigurdur T. Thoroddsen, 2012. "Stabilization of Leidenfrost vapour layer by textured superhydrophobic surfaces," Nature, Nature, vol. 489(7415), pages 274-277, September.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Agrawal, Prashant & Wells, Gary G. & Ledesma-Aguilar, Rodrigo & McHale, Glen & Buchoux, Anthony & Stokes, Adam & Sefiane, Khellil, 2019. "Leidenfrost heat engine: Sustained rotation of levitating rotors on turbine-inspired substrates," Applied Energy, Elsevier, vol. 240(C), pages 399-408.
    2. Agrawal, Prashant & Wells, Gary G. & Ledesma-Aguilar, Rodrigo & McHale, Glen & Sefiane, Khellil, 2021. "Beyond Leidenfrost levitation: A thin-film boiling engine for controlled power generation," Applied Energy, Elsevier, vol. 287(C).
    3. Yao, Yung-Chen & Tsai, Jiun-Horng & Wang, I-Ting, 2013. "Emissions of gaseous pollutant from motorcycle powered by ethanol–gasoline blend," Applied Energy, Elsevier, vol. 102(C), pages 93-100.
    4. White, Eric M. & Latta, Greg & Alig, Ralph J. & Skog, Kenneth E. & Adams, Darius M., 2013. "Biomass production from the U.S. forest and agriculture sectors in support of a renewable electricity standard," Energy Policy, Elsevier, vol. 58(C), pages 64-74.
    5. Goh, Chun Sheng & Lee, Keat Teong, 2010. "A visionary and conceptual macroalgae-based third-generation bioethanol (TGB) biorefinery in Sabah, Malaysia as an underlay for renewable and sustainable development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 842-848, February.
    6. Viju, Crina & Kerr, William A., 2010. "Is The Subsidy For Biofuels The Way To Go?," 14th ICABR Conference, June 16-18, 2010, Ravello, Italy 188117, International Consortium on Applied Bioeconomy Research (ICABR).
    7. Cong Liu & Chenguang Lu & Zichao Yuan & Cunjing Lv & Yahua Liu, 2022. "Steerable drops on heated concentric microgroove arrays," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    8. Hernandez, Marcel & Menchaca, Lizette & Mendoza, Alberto, 2014. "Fuel economy and emissions of light-duty vehicles fueled with ethanol–gasoline blends in a Mexican City," Renewable Energy, Elsevier, vol. 72(C), pages 236-242.
    9. Hoekman, S. Kent & Broch, Amber, 2018. "Environmental implications of higher ethanol production and use in the U.S.: A literature review. Part II – Biodiversity, land use change, GHG emissions, and sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 3159-3177.
    10. Tom Beer & John Carras & David Worth & Nick Coplin & Peter K. Campbell & Bin Jalaludin & Dennys Angove & Merched Azzi & Steve Brown & Ian Campbell & Martin Cope & Owen Farrell & Ian Galbally & Stephen, 2011. "The Health Impacts of Ethanol Blend Petrol," Energies, MDPI, vol. 4(2), pages 1-16, February.
    11. Luo, Feiteng & Song, Wenyan & Li, Jianping & Chen, Wenjuan & Long, Yaosong, 2021. "Experimental study of kerosene supersonic combustion with pilot hydrogen and fuel additive under low flight mach conditions," Energy, Elsevier, vol. 222(C).
    12. Costagliola, M.A. & De Simio, L. & Iannaccone, S. & Prati, M.V., 2013. "Combustion efficiency and engine out emissions of a S.I. engine fueled with alcohol/gasoline blends," Applied Energy, Elsevier, vol. 111(C), pages 1162-1171.
    13. Yuanxu Li & Zhi Ning & Chia-fon F. Lee & Timothy H. Lee & Junhao Yan, 2018. "Performance and Regulated/Unregulated Emission Evaluation of a Spark Ignition Engine Fueled with Acetone–Butanol–Ethanol and Gasoline Blends," Energies, MDPI, vol. 11(5), pages 1-16, May.
    14. García, Carlos A. & Manzini, Fabio & Islas, Jorge, 2010. "Air emissions scenarios from ethanol as a gasoline oxygenate in Mexico City Metropolitan Area," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(9), pages 3032-3040, December.
    15. Han, Dandan & E, Jiaqiang & Deng, Yuanwang & Chen, Jingwei & Leng, Erwei & Liao, Gaoliang & Zhao, Xiaohuan & Feng, Changling & Zhang, Feng, 2021. "A review of studies using hydrocarbon adsorption material for reducing hydrocarbon emissions from cold start of gasoline engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    16. Liu, Yang & Tang, Chenglong & Zhan, Cheng & Wu, Yingtao & Yang, Meng & Huang, Zuohua, 2019. "Low temperature auto-ignition characteristics of methylcyclohexane/ethanol blend fuels: Ignition delay time measurement and kinetic analysis," Energy, Elsevier, vol. 177(C), pages 465-475.
    17. Sobrino, Fernando Hernández & Monroy, Carlos Rodríguez, 2009. "Critical analysis of the European Union directive which regulates the use of biofuels: An approach to the Spanish case," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2675-2681, December.
    18. Sheng, Haoqiang & Huang, Xiaobin & Hu, Wenbin & Ji, Yuan & Chen, Junming & Xie, Mingyun & He, Miaoshen & Zhang, Bo & Liu, Hong, 2023. "Stability and combustion performance enhancement of ethanol/kerosene fuel by carbonized poly[cyclotriphosphazene-co-(4,4′-sulfonyldiphenol)] nanotubes via biomimetic hydrogen bonding strategy," Energy, Elsevier, vol. 282(C).
    19. Zhang, Bo & Sarathy, S. Mani, 2016. "Lifecycle optimized ethanol-gasoline blends for turbocharged engines," Applied Energy, Elsevier, vol. 181(C), pages 38-53.
    20. Dodic, Sinisa N. & Popov, Stevan D. & Dodic, Jelena M. & Rankovic, Jovana A. & Zavargo, Zoltan Z., 2009. "Potential contribution of bioethanol fuel to the transport sector of Vojvodina," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(8), pages 2197-2200, October.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:234:y:2021:i:c:s0360544221014961. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.