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One-step synthesis of biomass activated char supported copper nanoparticles for catalytic cracking of biomass primary tar

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  • Guo, Feiqiang
  • Peng, Kuangye
  • Liang, Shuang
  • Jia, Xiaopeng
  • Jiang, Xiaochen
  • Qian, Lin

Abstract

Activated char supported copper nanocatalysts were synthesized directly by one-step pyrolysis of CuCl2 impregnated biomass together with ZnCl2 as activation agent and applied to the cracking of biomass primary tar in a dual-stage reactor. The characterization of the obtained catalysts using XRD, SEM-EDX, TEM and N2 adsorption-desorption indicated CuCl2 can be reduced to Cu0 nanoparticles as active sites, and the presence of ZnCl2 can significantly enlarge the surface area of biomass char to improve the dispersion of copper nanoparticles. A large number of micropores and mesopores were formed during the synthesis process, which also helps to adsorb tar molecules and prolong the reaction time. The prepared nanocatalysts exhibited excellent catalytic activity in the cracking of primary biomass tar as a result of the combining effect of CuCl2 and ZnCl2, and a high tar conversion efficiency of 94.5% was obtained using RHC-1.0Cu1·0Zn at 800 °C. The yields of H2, CH4, CO and the total gas product increased significantly as a result of the tar reforming reactions using the activated char supported catalysts. GC-MS analysis illustrated that the biomass primary tar was mainly decomposed into oxygenated aromatic compounds and light tar compounds over the biomass char supported copper nanocatalysts.

Suggested Citation

  • Guo, Feiqiang & Peng, Kuangye & Liang, Shuang & Jia, Xiaopeng & Jiang, Xiaochen & Qian, Lin, 2019. "One-step synthesis of biomass activated char supported copper nanoparticles for catalytic cracking of biomass primary tar," Energy, Elsevier, vol. 180(C), pages 584-593.
    • Handle: RePEc:eee:energy:v:180:y:2019:i:c:p:584-593
    DOI: 10.1016/j.energy.2019.05.115
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    References listed on IDEAS

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    1. Shen, Yafei, 2015. "Chars as carbonaceous adsorbents/catalysts for tar elimination during biomass pyrolysis or gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 281-295.
    2. Li, Chunshan & Suzuki, Kenzi, 2009. "Tar property, analysis, reforming mechanism and model for biomass gasification--An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(3), pages 594-604, April.
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    Cited by:

    1. Gu, Jing & Wang, Shuxiao & Lu, Tao & Wu, Yufeng & Yuan, Haoran & Chen, Yong, 2020. "Synthesis and evaluation of pyrolysis waste peat char supported catalyst for steam reforming of toluene," Renewable Energy, Elsevier, vol. 160(C), pages 964-973.
    2. Guo, Feiqiang & Liang, Shuang & Zhao, Xingmin & Jia, Xiaopeng & Peng, Kuangye & Jiang, Xiaochen & Qian, Lin, 2019. "Catalytic reforming of biomass pyrolysis tar using the low-cost steel slag as catalyst," Energy, Elsevier, vol. 189(C).
    3. Zhou, Qiaoqiao & Liu, Zhenyu & Wu, Ta Yeong & Zhang, Lian, 2023. "Furfural from pyrolysis of agroforestry waste: Critical factors for utilisation of C5 and C6 sugars," Renewable and Sustainable Energy Reviews, Elsevier, vol. 176(C).
    4. Du, Shilin & Shu, Rui & Guo, Feiqiang & Mao, Songbo & Bai, Jiaming & Qian, Lin & Xin, Chengyun, 2022. "Porous coal char-based catalyst from coal gangue and lignite with high metal contents in the catalytic cracking of biomass tar," Energy, Elsevier, vol. 249(C).
    5. Wang, Shuxiao & Zhang, Yuyuan & Shan, Rui & Gu, Jing & Yuan, Haoran & Chen, Yong, 2022. "Steam reforming of biomass tar model compound over two waste char-based Ni catalysts for syngas production," Energy, Elsevier, vol. 246(C).
    6. Wang, Shuxiao & Shan, Rui & Lu, Tao & Zhang, Yuyuan & Yuan, Haoran & Chen, Yong, 2020. "Pyrolysis char derived from waste peat for catalytic reforming of tar model compound," Applied Energy, Elsevier, vol. 263(C).
    7. Guo, Feiqiang & Qiao, Qixia & Mao, Songbo & Bai, Jiaming & Dong, Kaiming & Shu, Rui & Xu, Liya & Wei, Haixiao & Qian, Lin & Wang, Yunpu, 2023. "A comprehensive study on the pyrolysis behavior of pine sawdust catalyzed by different metal ions under conventional and microwave heating conditions," Energy, Elsevier, vol. 272(C).

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