IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v190y2020ics0360544219320808.html
   My bibliography  Save this article

The role of activated carbon size in the catalytic cracking of naphthalene

Author

Listed:
  • Parrillo, F.
  • Ruoppolo, G.
  • Arena, U.

Abstract

Activated carbons are efficient catalysts for tar cracking, suitable for hot cleaning of the syngas produced during biomass- and waste-to-energy gasification processes. This study investigates the conversion of naphthalene, utilised as reference for tar compounds, when catalysed by a coal-derived activated carbon. The attention focuses on the influence of the operating temperature, in the range 750–900 °C, and the size of selected activated carbon, which has been used under form of pellets, granules and powders. The conversion efficiency improves when the temperature raised from 750 °C to 900 °C (from 79% to 99%, for the pellets), and when the catalyst size reduced from pellets to powders (from 79% to 97%, at 750 °C). The diffusional resistance in the catalyst particles has been then quantified in terms of Thiele modulus and internal effectiveness factor. A gradual reduction of catalyst surface area has been also observed for longer tests, due to the progressive deposition of soot from naphthalene decomposition over and inside the porous structure of the activated carbon. The carbon content of these deposits has been quantified, showing larger percentages on the surface of granules and powders.

Suggested Citation

  • Parrillo, F. & Ruoppolo, G. & Arena, U., 2020. "The role of activated carbon size in the catalytic cracking of naphthalene," Energy, Elsevier, vol. 190(C).
    • Handle: RePEc:eee:energy:v:190:y:2020:i:c:s0360544219320808
    DOI: 10.1016/j.energy.2019.116385
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219320808
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2019.116385?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Shen, Yafei, 2015. "Chars as carbonaceous adsorbents/catalysts for tar elimination during biomass pyrolysis or gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 281-295.
    2. Li, Chunshan & Suzuki, Kenzi, 2009. "Tar property, analysis, reforming mechanism and model for biomass gasification--An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(3), pages 594-604, April.
    3. Ravenni, Giulia & Sárossy, Zsuzsa & Ahrenfeldt, Jesper & Henriksen, Ulrik Birk, 2018. "Activity of chars and activated carbons for removal and decomposition of tar model compounds – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 1044-1056.
    4. Guizani, Chamseddine & Jeguirim, Mejdi & Gadiou, Roger & Escudero Sanz, Fransisco Javier & Salvador, Sylvain, 2016. "Biomass char gasification by H2O, CO2 and their mixture: Evolution of chemical, textural and structural properties of the chars," Energy, Elsevier, vol. 112(C), pages 133-145.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Parrillo, Francesco & Ardolino, Filomena & Calì, Gabriele & Marotto, Davide & Pettinau, Alberto & Arena, Umberto, 2021. "Fluidized bed gasification of eucalyptus chips: Axial profiles of syngas composition in a pilot scale reactor," Energy, Elsevier, vol. 219(C).
    2. Hu, Fan & Xiong, Biao & Huang, Xiaohong & Liu, Zhaohui, 2023. "Theoretical analysis and experimental verification of diminishing the diffusion influence on determination of char oxidation kinetics by thermo-gravimetric analysis," Energy, Elsevier, vol. 275(C).
    3. Ali Abdelaal & Vittoria Benedetti & Audrey Villot & Francesco Patuzzi & Claire Gerente & Marco Baratieri, 2023. "Innovative Pathways for the Valorization of Biomass Gasification Char: A Systematic Review," Energies, MDPI, vol. 16(10), pages 1-24, May.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Korus, Agnieszka & Ravenni, Giulia & Loska, Krzysztof & Korus, Irena & Samson, Abby & Szlęk, Andrzej, 2021. "The importance of inherent inorganics and the surface area of wood char for its gasification reactivity and catalytic activity towards toluene conversion," Renewable Energy, Elsevier, vol. 173(C), pages 479-497.
    2. Ahsanullah Soomro & Shiyi Chen & Shiwei Ma & Wenguo Xiang, 2018. "Catalytic activities of nickel, dolomite, and olivine for tar removal and H2-enriched gas production in biomass gasification process," Energy & Environment, , vol. 29(6), pages 839-867, September.
    3. Wang, Shuxiao & Zhang, Yuyuan & Shan, Rui & Gu, Jing & Yuan, Haoran & Chen, Yong, 2022. "Steam reforming of biomass tar model compound over two waste char-based Ni catalysts for syngas production," Energy, Elsevier, vol. 246(C).
    4. Rakesh N, & Dasappa, S., 2018. "A critical assessment of tar generated during biomass gasification - Formation, evaluation, issues and mitigation strategies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 1045-1064.
    5. Zhang, Zhanming & Zhang, Lijun & Liu, Fang & Sun, Yifan & Shao, Yuewen & Sun, Kai & Zhang, Shu & Liu, Qing & Hu, Guangzhi & Hu, Xun, 2020. "Tailoring the surface properties of Ni/SiO2 catalyst with sulfuric acid for enhancing the catalytic efficiency for steam reforming of guaiacol," Renewable Energy, Elsevier, vol. 156(C), pages 423-439.
    6. Wang, Shuxiao & Shan, Rui & Lu, Tao & Zhang, Yuyuan & Yuan, Haoran & Chen, Yong, 2020. "Pyrolysis char derived from waste peat for catalytic reforming of tar model compound," Applied Energy, Elsevier, vol. 263(C).
    7. Gu, Jing & Wang, Shuxiao & Lu, Tao & Wu, Yufeng & Yuan, Haoran & Chen, Yong, 2020. "Synthesis and evaluation of pyrolysis waste peat char supported catalyst for steam reforming of toluene," Renewable Energy, Elsevier, vol. 160(C), pages 964-973.
    8. Cheng, Long & Wu, Zhiqiang & Zhang, Zhiguo & Guo, Changqing & Ellis, Naoko & Bi, Xiaotao & Paul Watkinson, A. & Grace, John R., 2020. "Tar elimination from biomass gasification syngas with bauxite residue derived catalysts and gasification char," Applied Energy, Elsevier, vol. 258(C).
    9. Gao, Ningbo & Salisu, Jamilu & Quan, Cui & Williams, Paul, 2021. "Modified nickel-based catalysts for improved steam reforming of biomass tar: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    10. Prasertcharoensuk, Phuet & Bull, Steve J. & Phan, Anh N., 2019. "Gasification of waste biomass for hydrogen production: Effects of pyrolysis parameters," Renewable Energy, Elsevier, vol. 143(C), pages 112-120.
    11. Zeng, Xi & Wang, Fang & Han, Zhennan & Han, Jiangze & Zhang, Jianling & Wu, Rongcheng & Xu, Guangwen, 2019. "Assessment of char property on tar catalytic reforming in a fluidized bed reactor for adopting a two-stage gasification process," Applied Energy, Elsevier, vol. 248(C), pages 115-125.
    12. Li, Jian & Jiao, Liguo & Tao, Junyu & Chen, Guanyi & Hu, Jianli & Yan, Beibei & Mansour, Mohy & Guo, Yaoyu & Ye, Peiwen & Ding, Zheng & Yu, Tianxiao, 2020. "Can microwave treat biomass tar? A comprehensive study based on experimental and net energy analysis," Applied Energy, Elsevier, vol. 272(C).
    13. David, E. & Kopač, J., 2021. "Efficient removal of tar from gas fraction resulting from thermo-chemical conversion of biomass using coal fly ash–based catalysts," Renewable Energy, Elsevier, vol. 171(C), pages 1290-1302.
    14. Guo, Feiqiang & Peng, Kuangye & Liang, Shuang & Jia, Xiaopeng & Jiang, Xiaochen & Qian, Lin, 2019. "One-step synthesis of biomass activated char supported copper nanoparticles for catalytic cracking of biomass primary tar," Energy, Elsevier, vol. 180(C), pages 584-593.
    15. Ahmed, A.M.A & Salmiaton, A. & Choong, T.S.Y & Wan Azlina, W.A.K.G., 2015. "Review of kinetic and equilibrium concepts for biomass tar modeling by using Aspen Plus," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1623-1644.
    16. Liu, Zhongzhe & Singer, Simcha & Tong, Yiran & Kimbell, Lee & Anderson, Erik & Hughes, Matthew & Zitomer, Daniel & McNamara, Patrick, 2018. "Characteristics and applications of biochars derived from wastewater solids," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 650-664.
    17. Elhambakhsh, Abbas & Van Duc Long, Nguyen & Lamichhane, Pradeep & Hessel, Volker, 2023. "Recent progress and future directions in plasma-assisted biomass conversion to hydrogen," Renewable Energy, Elsevier, vol. 218(C).
    18. Zhang, Zhikun & Zhu, Zongyuan & Shen, Boxiong & Liu, Lina, 2019. "Insights into biochar and hydrochar production and applications: A review," Energy, Elsevier, vol. 171(C), pages 581-598.
    19. Zhang, Zihang & Yi, Baojun & Sun, Zhengshuai & Zhang, Qi & Feng, He & Hu, Hongyun & Huang, Xiangguo & Zhao, Chunqing, 2021. "Reaction process and characteristics for coal char gasification under changed CO2/H2O atmosphere in various reaction stages," Energy, Elsevier, vol. 229(C).
    20. Yoon, Kwangsuk & Lee, Sang Soo & Ok, Yong Sik & Kwon, Eilhann E. & Song, Hocheol, 2019. "Enhancement of syngas for H2 production via catalytic pyrolysis of orange peel using CO2 and bauxite residue," Applied Energy, Elsevier, vol. 254(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:190:y:2020:i:c:s0360544219320808. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.