IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v140y2017ip1p136-143.html
   My bibliography  Save this article

Swapping methane with carbon dioxide in spherical hydrate pellets

Author

Listed:
  • Zhou, Xuebing
  • Li, Dongliang
  • Zhang, Shaohong
  • Liang, Deqing

Abstract

Recovering CH4 with CO2 in hydrocarbon hydrates is renowned as an eco-friendly method for potential energy production and climate change mitigation. Due to the foamy nature of hydrates, determining the effect of hydrate surface area on the CH4 recovering rate has always been a challenge. CH4 hydrates in this work were shaped into spherical pellets 16 mm in diameter, and the CH4-CO2 replacements were carried out at about 274 K, 3.0 MPa by adding different amount of pellets in the reactor. To reveal the kinetic properties, cryo-SEM and a model based on gas diffusion theory was also employed. Results indicated that the CH4 recovery rate in the replacement was proportional to the surface area of hydrate pellets. In each 1400-h replacement, the CH4 production level was found to be about 4.5%, suggesting the gas swapping process took place in each pellet was the same. The kinetic model provided well descriptions of the replacements with the average deviation no more than 10%. The SEM images and the gas diffusion constants obtained from the kinetic model suggested that water mobility determined the gas diffusion rate in hydrates and help to smooth the hydrate surface during replacements.

Suggested Citation

  • Zhou, Xuebing & Li, Dongliang & Zhang, Shaohong & Liang, Deqing, 2017. "Swapping methane with carbon dioxide in spherical hydrate pellets," Energy, Elsevier, vol. 140(P1), pages 136-143.
    • Handle: RePEc:eee:energy:v:140:y:2017:i:p1:p:136-143
    DOI: 10.1016/j.energy.2017.08.082
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217314585
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2017.08.082?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Jiafei Zhao & Kun Xu & Yongchen Song & Weiguo Liu & Weihaur Lam & Yu Liu & Kaihua Xue & Yiming Zhu & Xichong Yu & Qingping Li, 2012. "A Review on Research on Replacement of CH 4 in Natural Gas Hydrates by Use of CO 2," Energies, MDPI, vol. 5(2), pages 1-21, February.
    2. Koh, Dong-Yeun & Kang, Hyery & Lee, Jong-Won & Park, Youngjune & Kim, Se-Joon & Lee, Jaehyoung & Lee, Joo Yong & Lee, Huen, 2016. "Energy-efficient natural gas hydrate production using gas exchange," Applied Energy, Elsevier, vol. 162(C), pages 114-130.
    3. Chong, Zheng Rong & Yang, She Hern Bryan & Babu, Ponnivalavan & Linga, Praveen & Li, Xiao-Sen, 2016. "Review of natural gas hydrates as an energy resource: Prospects and challenges," Applied Energy, Elsevier, vol. 162(C), pages 1633-1652.
    4. Xu, Chun-Gang & Cai, Jing & Lin, Fu-hua & Chen, Zhao-Yang & Li, Xiao-Sen, 2015. "Raman analysis on methane production from natural gas hydrate by carbon dioxide–methane replacement," Energy, Elsevier, vol. 79(C), pages 111-116.
    5. Yuan, Qing & Sun, Chang-Yu & Yang, Xin & Ma, Ping-Chuan & Ma, Zheng-Wei & Liu, Bei & Ma, Qing-Lan & Yang, Lan-Ying & Chen, Guang-Jin, 2012. "Recovery of methane from hydrate reservoir with gaseous carbon dioxide using a three-dimensional middle-size reactor," Energy, Elsevier, vol. 40(1), pages 47-58.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ouyang, Qian & Pandey, Jyoti Shanker & von Solms, Nicolas, 2022. "Insights into multistep depressurization of CH4/CO2 mixed hydrates in unconsolidated sediments," Energy, Elsevier, vol. 260(C).
    2. Shi, Lingli & Li, Junhui & He, Yong & Lu, Jingsheng & Long, Zhen & Liang, Deqing, 2023. "Memory effect test and analysis in methane hydrates reformation process," Energy, Elsevier, vol. 272(C).
    3. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Xiao-Hui & Sun, Yi-Fei & Wang, Yun-Fei & Li, Nan & Sun, Chang-Yu & Chen, Guang-Jin & Liu, Bei & Yang, Lan-Ying, 2017. "Gas production from hydrates by CH4-CO2/H2 replacement," Applied Energy, Elsevier, vol. 188(C), pages 305-314.
    2. Jyoti Shanker Pandey & Charilaos Karantonidis & Adam Paul Karcz & Nicolas von Solms, 2020. "Enhanced CH 4 -CO 2 Hydrate Swapping in the Presence of Low Dosage Methanol," Energies, MDPI, vol. 13(20), pages 1-30, October.
    3. Tsypkin, G.G., 2021. "Analytical study of CO2–CH4 exchange in hydrate at high rates of carbon dioxide injection into a reservoir saturated with methane hydrate and gaseous methane," Energy, Elsevier, vol. 233(C).
    4. Bi, Yuehong & Chen, Jie & Miao, Zhen, 2016. "Thermodynamic optimization for dissociation process of gas hydrates," Energy, Elsevier, vol. 106(C), pages 270-276.
    5. Chen, Bingbing & Sun, Huiru & Zhou, Hang & Yang, Mingjun & Wang, Dayong, 2019. "Effects of pressure and sea water flow on natural gas hydrate production characteristics in marine sediment," Applied Energy, Elsevier, vol. 238(C), pages 274-283.
    6. Gajanan, K. & Ranjith, P.G. & Yang, S.Q. & Xu, T., 2024. "Advances in research and developments on natural gas hydrate extraction with gas exchange," Renewable and Sustainable Energy Reviews, Elsevier, vol. 190(PB).
    7. Sun, You-Hong & Zhang, Guo-Biao & Carroll, John J. & Li, Sheng-Li & Jiang, Shu-Hui & Guo, Wei, 2018. "Experimental investigation into gas recovery from CH4-C2H6-C3H8 hydrates by CO2 replacement," Applied Energy, Elsevier, vol. 229(C), pages 625-636.
    8. Sergey Misyura & Pavel Strizhak & Anton Meleshkin & Vladimir Morozov & Olga Gaidukova & Nikita Shlegel & Maria Shkola, 2023. "A Review of Gas Capture and Liquid Separation Technologies by CO 2 Gas Hydrate," Energies, MDPI, vol. 16(8), pages 1-20, April.
    9. Chen, Xuejun & Lu, Hailong & Gu, Lijuan & Shang, Shilong & Zhang, Yi & Huang, Xin & Zhang, Le, 2022. "Preliminary evaluation of the economic potential of the technologies for gas hydrate exploitation," Energy, Elsevier, vol. 243(C).
    10. Lee, Yohan & Choi, Wonjung & Seo, Young-ju & Lee, Joo Yong & Lee, Jaehyoung & Seo, Yongwon, 2018. "Structural transition induced by cage-dependent guest exchange in CH4 + C3H8 hydrates with CO2 injection for energy recovery and CO2 sequestration," Applied Energy, Elsevier, vol. 228(C), pages 229-239.
    11. Li, Xiao-Sen & Xu, Chun-Gang & Zhang, Yu & Ruan, Xu-Ke & Li, Gang & Wang, Yi, 2016. "Investigation into gas production from natural gas hydrate: A review," Applied Energy, Elsevier, vol. 172(C), pages 286-322.
    12. Sun, Yi-Fei & Zhong, Jin-Rong & Li, Rui & Zhu, Tao & Cao, Xin-Yi & Chen, Guang-Jin & Wang, Xiao-Hui & Yang, Lan-Ying & Sun, Chang-Yu, 2018. "Natural gas hydrate exploitation by CO2/H2 continuous Injection-Production mode," Applied Energy, Elsevier, vol. 226(C), pages 10-21.
    13. Chen, Xuyue & Yang, Jin & Gao, Deli & Hong, Yuqun & Zou, Yiqi & Du, Xu, 2020. "Unlocking the deepwater natural gas hydrate's commercial potential with extended reach wells from shallow water: Review and an innovative method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    14. Tang, Jizhou & Zhang, Min & Guo, Xuyang & Geng, Jianhua & Li, Yuwei, 2024. "Investigation of creep and transport mechanisms of CO2 fracturing within natural gas hydrates," Energy, Elsevier, vol. 300(C).
    15. Pandey, Gaurav & Poothia, Tejaswa & Kumar, Asheesh, 2022. "Hydrate based carbon capture and sequestration (HBCCS): An innovative approach towards decarbonization," Applied Energy, Elsevier, vol. 326(C).
    16. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    17. Xu, Chun-Gang & Cai, Jing & Yu, Yi-Song & Yan, Ke-Feng & Li, Xiao-Sen, 2018. "Effect of pressure on methane recovery from natural gas hydrates by methane-carbon dioxide replacement," Applied Energy, Elsevier, vol. 217(C), pages 527-536.
    18. Lee, Joonseop & Lee, Dongyoung & Seo, Yongwon, 2021. "Experimental investigation of the exact role of large-molecule guest substances (LMGSs) in determining phase equilibria and structures of natural gas hydrates," Energy, Elsevier, vol. 215(PB).
    19. Chong, Zheng Rong & Moh, Jia Wei Regine & Yin, Zhenyuan & Zhao, Jianzhong & Linga, Praveen, 2018. "Effect of vertical wellbore incorporation on energy recovery from aqueous rich hydrate sediments," Applied Energy, Elsevier, vol. 229(C), pages 637-647.
    20. Yang, Mingjun & Dong, Shuang & Zhao, Jie & Zheng, Jia-nan & Liu, Zheyuan & Song, Yongchen, 2021. "Ice behaviors and heat transfer characteristics during the isothermal production process of methane hydrate reservoirs by depressurization," Energy, Elsevier, vol. 232(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:140:y:2017:i:p1:p:136-143. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.