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A Review on Research on Replacement of CH 4 in Natural Gas Hydrates by Use of CO 2

Author

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  • Jiafei Zhao

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology, Dalian 116024, China)

  • Kun Xu

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology, Dalian 116024, China)

  • Yongchen Song

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology, Dalian 116024, China)

  • Weiguo Liu

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology, Dalian 116024, China)

  • Weihaur Lam

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology, Dalian 116024, China
    Department of Civil Engineering, University of Malaya, Kuala Lumpur 50603, Malaysia)

  • Yu Liu

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology, Dalian 116024, China)

  • Kaihua Xue

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology, Dalian 116024, China)

  • Yiming Zhu

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, Dalian University of Technology, Dalian 116024, China)

  • Xichong Yu

    (CNOOC Research Center, Beijing 100027, China)

  • Qingping Li

    (CNOOC Research Center, Beijing 100027, China)

Abstract

This paper introduces the research advances on replacement of CH 4 in Natural Gas Hydrates (NGHs) by use of CO 2 and discusses the advantages and disadvantages of the method on the natural gas production from such hydrates. Firstly, the feasibility of replacement is proven from the points of view of kinetics and thermodynamics, and confirmed by experiments. Then, the latest progress in CH 4 replacement experiments with gaseous CO 2 , liquid CO 2 and CO 2 emulsion are presented Moreover, the superiority of CO 2 emulsion for replacement of CH 4 is emphasized. The latest experiment progress on preparation of CO 2 emulsions are introduced. Finally, the advancements in simulation research on replacement is introduced, and the deficiencies of the simulations are pointed. The factors influencing on the replacement with different forms of CO 2 are analyzed and the optimum conditions for the replacement of CH 4 in hydrated with different forms of CO 2 is suggested.

Suggested Citation

  • Jiafei Zhao & Kun Xu & Yongchen Song & Weiguo Liu & Weihaur Lam & Yu Liu & Kaihua Xue & Yiming Zhu & Xichong Yu & Qingping Li, 2012. "A Review on Research on Replacement of CH 4 in Natural Gas Hydrates by Use of CO 2," Energies, MDPI, vol. 5(2), pages 1-21, February.
  • Handle: RePEc:gam:jeners:v:5:y:2012:i:2:p:399-419:d:16264
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    Citations

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    Cited by:

    1. Chen, Xuyue & Yang, Jin & Gao, Deli & Hong, Yuqun & Zou, Yiqi & Du, Xu, 2020. "Unlocking the deepwater natural gas hydrate's commercial potential with extended reach wells from shallow water: Review and an innovative method," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    2. Feng, Jing-Chun & Wang, Yi & Li, Xiao-Sen, 2016. "Energy and entropy analyses of hydrate dissociation in different scales of hydrate simulator," Energy, Elsevier, vol. 102(C), pages 176-186.
    3. Koh, Dong-Yeun & Kang, Hyery & Lee, Jong-Won & Park, Youngjune & Kim, Se-Joon & Lee, Jaehyoung & Lee, Joo Yong & Lee, Huen, 2016. "Energy-efficient natural gas hydrate production using gas exchange," Applied Energy, Elsevier, vol. 162(C), pages 114-130.
    4. Cai, Jing & Lv, Tao & Zhang, Yu & von Solms, Nicolas & Xu, Chun-Gang & Chen, Zhao-Yang & Li, Xiao-Sen, 2020. "Studies on temperature characteristics and initial formation interface during cyclopentane-methane hydrate formation in large-scale equipment with bubbling," Applied Energy, Elsevier, vol. 258(C).
    5. Pandey, Gaurav & Poothia, Tejaswa & Kumar, Asheesh, 2022. "Hydrate based carbon capture and sequestration (HBCCS): An innovative approach towards decarbonization," Applied Energy, Elsevier, vol. 326(C).
    6. Zhouhua Wang & Yun Li & Huang Liu & Fanhua Zeng & Ping Guo & Wei Jiang, 2017. "Study on the Adsorption, Diffusion and Permeation Selectivity of Shale Gas in Organics," Energies, MDPI, vol. 10(1), pages 1-15, January.
    7. Chen, Ye & Gao, Yonghai & Zhao, Yipeng & Chen, Litao & Dong, Changyin & Sun, Baojiang, 2018. "Experimental investigation of different factors influencing the replacement efficiency of CO2 for methane hydrate," Applied Energy, Elsevier, vol. 228(C), pages 309-316.
    8. Zhang, Xuemin & Yang, Huijie & Huang, Tingting & Li, Jinping & Li, Pengyu & Wu, Qingbai & Wang, Yingmei & Zhang, Peng, 2022. "Research progress of molecular dynamics simulation on the formation-decomposition mechanism and stability of CO2 hydrate in porous media: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    9. Jyoti Shanker Pandey & Charilaos Karantonidis & Adam Paul Karcz & Nicolas von Solms, 2020. "Enhanced CH 4 -CO 2 Hydrate Swapping in the Presence of Low Dosage Methanol," Energies, MDPI, vol. 13(20), pages 1-30, October.
    10. Wang, Xiao-Hui & Sun, Yi-Fei & Wang, Yun-Fei & Li, Nan & Sun, Chang-Yu & Chen, Guang-Jin & Liu, Bei & Yang, Lan-Ying, 2017. "Gas production from hydrates by CH4-CO2/H2 replacement," Applied Energy, Elsevier, vol. 188(C), pages 305-314.
    11. Zhou, Xuebing & Li, Dongliang & Zhang, Shaohong & Liang, Deqing, 2017. "Swapping methane with carbon dioxide in spherical hydrate pellets," Energy, Elsevier, vol. 140(P1), pages 136-143.

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