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Latent heat storage using renewable saturated diesters as phase change materials

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  • Floros, Michael C.
  • Narine, Suresh S.

Abstract

A series of phase change materials produced primarily from non-toxic renewable vegetable oil derivatives are described. It is shown that the synthesis of the materials from commercially available fatty acid methyl esters and short-chain dialcohols is rapid and effective. The phase change temperatures of these materials can be predictively varied, while maintaining similar latent heat values, as a function of the length of the fatty acid methyl esters and/or short chain dialcohols. This facilitates the synthesis of phase change materials which function over a wide range of working temperatures, whilst maintaining the amount of heat absorbed or released within a predictable range. The PCMs described compare favorably to other commercial PCMs, with similar or higher latent heat values. One diester which melts within a normal hot beverage consumption range was used to test diester thermoregulation. An insulated beverage container was modified with a PCM liner and filled with water initially at 85 °C. The PCM modified container brought the water to a drinkable temperature range (60 °C ± 10 °C) in less than 1 min and held the temperature of the water within the desired range for a longer duration than a control without added PCM.

Suggested Citation

  • Floros, Michael C. & Narine, Suresh S., 2016. "Latent heat storage using renewable saturated diesters as phase change materials," Energy, Elsevier, vol. 115(P1), pages 924-930.
    • Handle: RePEc:eee:energy:v:115:y:2016:i:p1:p:924-930
    DOI: 10.1016/j.energy.2016.09.085
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    References listed on IDEAS

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    1. Zhou, D. & Zhao, C.Y. & Tian, Y., 2012. "Review on thermal energy storage with phase change materials (PCMs) in building applications," Applied Energy, Elsevier, vol. 92(C), pages 593-605.
    2. Anisur, M.R. & Mahfuz, M.H. & Kibria, M.A. & Saidur, R. & Metselaar, I.H.S.C. & Mahlia, T.M.I., 2013. "Curbing global warming with phase change materials for energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 23-30.
    3. Tessier, Michael J. & Floros, Michael C. & Bouzidi, Laziz & Narine, Suresh S., 2016. "Exergy analysis of an adiabatic compressed air energy storage system using a cascade of phase change materials," Energy, Elsevier, vol. 106(C), pages 528-534.
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    Cited by:

    1. Chao, Weixiang & Yang, Haiyue & Cao, Guoliang & Sun, Xiaohan & Wang, Xin & Wang, Chengyu, 2020. "Carbonized wood flour matrix with functional phase change material composite for magnetocaloric-assisted photothermal conversion and storage," Energy, Elsevier, vol. 202(C).
    2. Simonsen, Galina & Ravotti, Rebecca & O'Neill, Poppy & Stamatiou, Anastasia, 2023. "Biobased phase change materials in energy storage and thermal management technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
    3. Pizzolato, Alberto & Sharma, Ashesh & Maute, Kurt & Sciacovelli, Adriano & Verda, Vittorio, 2017. "Design of effective fins for fast PCM melting and solidification in shell-and-tube latent heat thermal energy storage through topology optimization," Applied Energy, Elsevier, vol. 208(C), pages 210-227.

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