IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v111y2013icp267-276.html
   My bibliography  Save this article

CO-hydrogenation over silica supported iron based catalysts: Influence of potassium loading

Author

Listed:
  • Das, Satyen Kumar
  • Mohanty, Pravakar
  • Majhi, Sachchit
  • Pant, Kamal Kishore

Abstract

Five different Fe–Cu/SiO2 catalysts were prepared by a combination of co-precipitation and wet impregnation technique at different K-loading ranging from 0 to 5wt.% for the conversion of syngas to liquid fuel. The physiochemical characterization of these catalysts was performed by using N2 adsorption, X-ray diffraction (XRD), H2-TPR, NH3-TPD, TEM, Inductive Couple Plasma Mass Spectroscopy (ICP-MS), and SEM–EDX to study the effect of potassium on the textural properties, structural change, reduction behavior, acidity and morphological change to the above K-loading catalysts. The effect of addition of potassium promoter was studied for CO-Hydrogenation in a fixed bed reactor simultaneously with the effect of promoter on the CO-conversion, selectivity and deactivation. The maximum catalytic activity was obtained from 1% K-loading and the catalytic activity decreased thereafter. The activity for water–gas shift (WGS) also enhanced with increasing K loading. The results revealed that increasing K loading decreases gaseous hydrocarbon formation and shifts selectivity to higher molecular weight hydrocarbons. Incorporation of potassium suppresses the hydrogenation activity of the Fe–Cu/SiO2 catalyst, leading to higher olefin yield in the products.

Suggested Citation

  • Das, Satyen Kumar & Mohanty, Pravakar & Majhi, Sachchit & Pant, Kamal Kishore, 2013. "CO-hydrogenation over silica supported iron based catalysts: Influence of potassium loading," Applied Energy, Elsevier, vol. 111(C), pages 267-276.
    • Handle: RePEc:eee:appene:v:111:y:2013:i:c:p:267-276
    DOI: 10.1016/j.apenergy.2013.04.070
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261913003668
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2013.04.070?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Squires, Arthur M., 1978. "Reaction paths in donor solvent coal liquefaction," Applied Energy, Elsevier, vol. 4(3), pages 161-185, July.
    2. Choudhary, Vasant R. & Mondal, Kartick C., 2006. "CO2 reforming of methane combined with steam reforming or partial oxidation of methane to syngas over NdCoO3 perovskite-type mixed metal-oxide catalyst," Applied Energy, Elsevier, vol. 83(9), pages 1024-1032, September.
    3. Hu, Shengyang & Guan, Yanping & Wang, Yun & Han, Heyou, 2011. "Nano-magnetic catalyst KF/CaO-Fe3O4 for biodiesel production," Applied Energy, Elsevier, vol. 88(8), pages 2685-2690, August.
    4. Khobragade, Murnal & Majhi, Sachchit & Pant, K.K., 2012. "Effect of K and CeO2 promoters on the activity of Co/SiO2 catalyst for liquid fuel production from syngas," Applied Energy, Elsevier, vol. 94(C), pages 385-394.
    5. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    6. Antolini, Ermete, 2011. "The stability of molten carbonate fuel cell electrodes: A review of recent improvements," Applied Energy, Elsevier, vol. 88(12), pages 4274-4293.
    7. Raspolli Galletti, Anna Maria & Antonetti, Claudia & Ribechini, Erika & Colombini, Maria Perla & Nassi o Di Nasso, Nicoletta & Bonari, Enrico, 2013. "From giant reed to levulinic acid and gamma-valerolactone: A high yield catalytic route to valeric biofuels," Applied Energy, Elsevier, vol. 102(C), pages 157-162.
    8. Haro, P. & Ollero, P. & Villanueva Perales, A.L. & Gómez-Barea, A., 2013. "Thermochemical biorefinery based on dimethyl ether as intermediate: Technoeconomic assessment," Applied Energy, Elsevier, vol. 102(C), pages 950-961.
    9. Ahmed, I.I. & Nipattummakul, N. & Gupta, A.K., 2011. "Characteristics of syngas from co-gasification of polyethylene and woodchips," Applied Energy, Elsevier, vol. 88(1), pages 165-174, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ding, Mingyue & Tu, Junling & Qiu, Minghuang & Wang, Tiejun & Ma, Longlong & Li, Yuping, 2015. "Impact of potassium promoter on Cu–Fe based mixed alcohols synthesis catalyst," Applied Energy, Elsevier, vol. 138(C), pages 584-589.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Kuo, Yen-Ting & Almansa, G. Aranda & Vreugdenhil, B.J., 2018. "Catalytic aromatization of ethylene in syngas from biomass to enhance economic sustainability of gas production," Applied Energy, Elsevier, vol. 215(C), pages 21-30.
    2. Arab Aboosadi, Z. & Jahanmiri, A.H. & Rahimpour, M.R., 2011. "Optimization of tri-reformer reactor to produce synthesis gas for methanol production using differential evolution (DE) method," Applied Energy, Elsevier, vol. 88(8), pages 2691-2701, August.
    3. Gupta, Anilkumar R. & Rathod, Virendra K., 2018. "Calcium diglyceroxide catalyzed biodiesel production from waste cooking oil in the presence of microwave: Optimization and kinetic studies," Renewable Energy, Elsevier, vol. 121(C), pages 757-767.
    4. Zhang, Xiaolei & Yan, Song & Tyagi, Rajeshwar D. & Surampalli, RaoY. & Valéro, Jose R., 2014. "Wastewater sludge as raw material for microbial oils production," Applied Energy, Elsevier, vol. 135(C), pages 192-201.
    5. Huang, Jijiang & Veksha, Andrei & Chan, Wei Ping & Giannis, Apostolos & Lisak, Grzegorz, 2022. "Chemical recycling of plastic waste for sustainable material management: A prospective review on catalysts and processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    6. Fiore, M. & Magi, V. & Viggiano, A., 2020. "Internal combustion engines powered by syngas: A review," Applied Energy, Elsevier, vol. 276(C).
    7. Buentello-Montoya, D.A. & Duarte-Ruiz, C.A. & Maldonado-Escalante, J.F., 2023. "Co-gasification of waste PET, PP and biomass for energy recovery: A thermodynamic model to assess the produced syngas quality," Energy, Elsevier, vol. 266(C).
    8. Singh, Paramvir & Varun, & Chauhan, S.R., 2016. "Carbonyl and aromatic hydrocarbon emissions from diesel engine exhaust using different feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 269-291.
    9. Walluk, Mark R. & Lin, Jiefeng & Waller, Michael G. & Smith, Daniel F. & Trabold, Thomas A., 2014. "Diesel auto-thermal reforming for solid oxide fuel cell systems: Anode off-gas recycle simulation," Applied Energy, Elsevier, vol. 130(C), pages 94-102.
    10. Ambat, Indu & Srivastava, Varsha & Sillanpää, Mika, 2018. "Recent advancement in biodiesel production methodologies using various feedstock: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 356-369.
    11. Zaini, Ilman Nuran & Gomez-Rueda, Yamid & García López, Cristina & Ratnasari, Devy Kartika & Helsen, Lieve & Pretz, Thomas & Jönsson, Pär Göran & Yang, Weihong, 2020. "Production of H2-rich syngas from excavated landfill waste through steam co-gasification with biochar," Energy, Elsevier, vol. 207(C).
    12. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    13. Zhang, X.L. & Yan, S. & Tyagi, R.D. & Surampalli, R.Y., 2013. "Biodiesel production from heterotrophic microalgae through transesterification and nanotechnology application in the production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 216-223.
    14. Santagata, R. & Ripa, M. & Ulgiati, S., 2017. "An environmental assessment of electricity production from slaughterhouse residues. Linking urban, industrial and waste management systems," Applied Energy, Elsevier, vol. 186(P2), pages 175-188.
    15. Chung, Wei-Chieh & Chang, Moo-Been, 2016. "Review of catalysis and plasma performance on dry reforming of CH4 and possible synergistic effects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 13-31.
    16. Chiatti, Giancarlo & Chiavola, Ornella & Palmieri, Fulvio, 2017. "Vibration and acoustic characteristics of a city-car engine fueled with biodiesel blends," Applied Energy, Elsevier, vol. 185(P1), pages 664-670.
    17. Manzone, Marco & Calvo, Angela, 2016. "Energy and CO2 analysis of poplar and maize crops for biomass production in north Italy," Renewable Energy, Elsevier, vol. 86(C), pages 675-681.
    18. Zhang, Huiming & Zheng, Yu & Cao, Jie & Qiu, Yueming, 2017. "Has government intervention effectively encouraged the use of waste cooking oil as an energy source? Comparison of two Chinese biofuel companies," Energy, Elsevier, vol. 140(P1), pages 708-715.
    19. Patel, Vimal R. & Patel, Darshil & Varia, Nandan S. & Patel, Rajesh N., 2017. "Co-gasification of lignite and waste wood in a pilot-scale (10 kWe) downdraft gasifier," Energy, Elsevier, vol. 119(C), pages 834-844.
    20. Wang, Yi-Tong & Yang, Xing-Xia & Xu, Jie & Wang, Hong-Li & Wang, Zi-Bing & Zhang, Lei & Wang, Shao-Long & Liang, Jing-Long, 2019. "Biodiesel production from esterification of oleic acid by a sulfonated magnetic solid acid catalyst," Renewable Energy, Elsevier, vol. 139(C), pages 688-695.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:111:y:2013:i:c:p:267-276. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.