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Methanol based Solid Oxide Reversible energy storage system – Does it make sense thermodynamically?

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  • Giannoulidis, Sotiris
  • Venkataraman, Vikrant
  • Woudstra, Theo
  • Aravind, P.V.

Abstract

Hydrogen is yet to be widely accepted as a fuel for everyday operation due to stringent safety regulations involved around it. In the meanwhile, methanol could be a potential fuel of the future. In this work, an extensive thermodynamic investigation on an energy storage system with a reversible solid oxide stack at its core is presented. The current investigated system can operate either as an electrolyzer or as a fuel cell. It uses steam for electrolysis (charging mode) and methanol for fuel cell operation (discharging mode). A process model of the entire system is formulated by using Aspen Plus™. Energy and exergy efficiency have been reported for both modes of operation, along with maximum roundtrip efficiency that can be achieved for the entire system operation. Results indicate that during electrolysis mode, a maximum energy and exergy efficiency of 67.94% and 72.30% can be achieved and for fuel cell mode operation, the numbers are 74.14% and 62.61% respectively. The maximum reported value of RT efficiency is 64.32% which is quite high considering the infancy of reversible solid oxide technology and the fact that methanol is used as the fuel.

Suggested Citation

  • Giannoulidis, Sotiris & Venkataraman, Vikrant & Woudstra, Theo & Aravind, P.V., 2020. "Methanol based Solid Oxide Reversible energy storage system – Does it make sense thermodynamically?," Applied Energy, Elsevier, vol. 278(C).
    • Handle: RePEc:eee:appene:v:278:y:2020:i:c:s0306261920311272
    DOI: 10.1016/j.apenergy.2020.115623
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    References listed on IDEAS

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    1. Barelli, L. & Bidini, G. & Ottaviano, A., 2015. "Hydromethane generation through SOE (solid oxide electrolyser): Advantages of H2O–CO2 co-electrolysis," Energy, Elsevier, vol. 90(P1), pages 1180-1191.
    2. Al-musleh, Easa I. & Mallapragada, Dharik S. & Agrawal, Rakesh, 2014. "Continuous power supply from a baseload renewable power plant," Applied Energy, Elsevier, vol. 122(C), pages 83-93.
    3. Wendel, Christopher H. & Braun, Robert J., 2016. "Design and techno-economic analysis of high efficiency reversible solid oxide cell systems for distributed energy storage," Applied Energy, Elsevier, vol. 172(C), pages 118-131.
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    Cited by:

    1. Kontou, V. & Grimekis, D. & Braimakis, K. & Karellas, S., 2022. "Techno-economic assessment of dimethyl carbonate production based on carbon capture and utilization and power-to-fuel technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    2. Sun, Yi & Qian, Tang & Zhu, Jingdong & Zheng, Nan & Han, Yu & Xiao, Gang & Ni, Meng & Xu, Haoran, 2023. "Dynamic simulation of a reversible solid oxide cell system for efficient H2 production and power generation," Energy, Elsevier, vol. 263(PA).
    3. Amladi, Amogh & Venkataraman, Vikrant & Woudstra, Theo & Aravind, P.V., 2024. "Hot air recirculation enlarges efficient operating window of reversible solid oxide cell systems: A thermodynamic study of energy storage using ammonia," Applied Energy, Elsevier, vol. 355(C).

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