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Local degradation effects in automotive size membrane electrode assemblies under realistic operating conditions

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  • Lochner, Tim
  • Hallitzky, Laurens
  • Perchthaler, Markus
  • Obermaier, Michael
  • Sabawa, Jarek
  • Enz, Simon
  • Bandarenka, Aliaksandr S.

Abstract

In automotive applications, the operational parameters for fuel cell (FC) systems can vary over a wide range. To analyze their impact on fuel cell degradation, an automotive size single cell was operated under realistic working conditions. The parameter sets were extracted from the FC system modeling based on on-road customer data. The parameter variation included simultaneous variation of the FC load, gas pressures, cell temperature, stoichiometries and relative humidity. Current density distributions and the overall cell voltage were recorded in real time during the tests. The current densities were low at the geometric anode gas outlet and high at the anode gas inlet. After electrochemical tests, post mortem analysis was conducted on the membrane electrode assemblies using scanning electron microscopy. The ex-situ analysis showed significant cathode carbon corrosion in areas associated with low current densities. This suggests that fuel starvation close to the anode outlet is the origin of the cathode electrode degradation. The results of the numerical simulations reveal high relative humidity at that region and, therefore, water flooding is assumed to cause local anode fuel starvation. Even though the hydrogen oxidation reaction has low kinetic overpotentials, “local availability” of H2 plays a significant role in maintaining a homogeneous current density distribution and thereby in local degradation of the cathode catalyst layer. The described phenomena occurred while the overall cell voltage remained above 0.3 V. This indicates that only voltage monitoring of fuel cell systems does not contain straightforward information about this type of degradation.

Suggested Citation

  • Lochner, Tim & Hallitzky, Laurens & Perchthaler, Markus & Obermaier, Michael & Sabawa, Jarek & Enz, Simon & Bandarenka, Aliaksandr S., 2020. "Local degradation effects in automotive size membrane electrode assemblies under realistic operating conditions," Applied Energy, Elsevier, vol. 260(C).
    • Handle: RePEc:eee:appene:v:260:y:2020:i:c:s0306261919319786
    DOI: 10.1016/j.apenergy.2019.114291
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    References listed on IDEAS

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    1. Mark K. Debe, 2012. "Electrocatalyst approaches and challenges for automotive fuel cells," Nature, Nature, vol. 486(7401), pages 43-51, June.
    2. Pei, Pucheng & Chen, Huicui, 2014. "Main factors affecting the lifetime of Proton Exchange Membrane fuel cells in vehicle applications: A review," Applied Energy, Elsevier, vol. 125(C), pages 60-75.
    3. Mehmood, Asad & An, Myung-Gi & Ha, Heung Yong, 2014. "Physical degradation of cathode catalyst layer: A major contributor to accelerated water flooding in long-term operation of DMFCs," Applied Energy, Elsevier, vol. 129(C), pages 346-353.
    4. Chen, Huicui & Song, Zhen & Zhao, Xin & Zhang, Tong & Pei, Pucheng & Liang, Chen, 2018. "A review of durability test protocols of the proton exchange membrane fuel cells for vehicle," Applied Energy, Elsevier, vol. 224(C), pages 289-299.
    5. Du, Jiuyu & Ouyang, Minggao & Chen, Jingfu, 2017. "Prospects for Chinese electric vehicle technologies in 2016–2020: Ambition and rationality," Energy, Elsevier, vol. 120(C), pages 584-596.
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    3. Nicu Bizon & Mircea Raceanu & Emmanouel Koudoumas & Adriana Marinoiu & Emmanuel Karapidakis & Elena Carcadea, 2020. "Renewable/Fuel Cell Hybrid Power System Operation Using Two Search Controllers of the Optimal Power Needed on the DC Bus," Energies, MDPI, vol. 13(22), pages 1-26, November.
    4. Wang, Yulin & Wang, Xiaoai & Fan, Yuanzhi & He, Wei & Guan, Jinglei & Wang, Xiaodong, 2022. "Numerical Investigation of Tapered Flow Field Configurations for Enhanced Polymer Electrolyte Membrane Fuel Cell Performance," Applied Energy, Elsevier, vol. 306(PA).

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