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Local impact of load cycling on degradation in polymer electrolyte fuel cells

Author

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  • Garcia-Sanchez, D.
  • Morawietz, T.
  • da Rocha, P. Gama
  • Hiesgen, R.
  • Gazdzicki, P.
  • Friedrich, K.A.

Abstract

Degradation mechanisms occurring during proton exchange membrane fuel cells (PEMFC) operation critically depend on the applied electrical load profile. In this work, durability tests were performed using different load cycling ranges. The tests include refresh procedures in order to recover temporary performance losses. Operando current density distribution measurements as well as electrochemical characterization techniques were applied to obtain essential data for understanding degradation behavior of the components of the membrane electrode assembly (MEA). The analysis is supported by scanning electron microscopy (SEM) and energy dispersive x-ray diffraction (EDX) analysis of MEA components. Dynamic load cycling has proven to lead to lower performance losses as compared to constant load operation. Moreover, reversible performance losses were associated with an increased heterogeneity of the current density distribution along the flow field. Thereby, areas with high local current density exhibit particularly strong Pt band formation in the membrane linked with a thinning of the cathode catalyst layer.

Suggested Citation

  • Garcia-Sanchez, D. & Morawietz, T. & da Rocha, P. Gama & Hiesgen, R. & Gazdzicki, P. & Friedrich, K.A., 2020. "Local impact of load cycling on degradation in polymer electrolyte fuel cells," Applied Energy, Elsevier, vol. 259(C).
    • Handle: RePEc:eee:appene:v:259:y:2020:i:c:s0306261919318975
    DOI: 10.1016/j.apenergy.2019.114210
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    References listed on IDEAS

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    1. Pérez, Luis C. & Brandão, Lúcia & Sousa, José M. & Mendes, Adélio, 2011. "Segmented polymer electrolyte membrane fuel cells--A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 169-185, January.
    2. Kurnia, Jundika C. & Sasmito, Agus P. & Shamim, Tariq, 2017. "Performance evaluation of a PEM fuel cell stack with variable inlet flows under simulated driving cycle conditions," Applied Energy, Elsevier, vol. 206(C), pages 751-764.
    3. Panha, Karachakorn & Fowler, Michael & Yuan, Xiao-Zi & Wang, Haijiang, 2012. "Accelerated durability testing via reactants relative humidity cycling on PEM fuel cells," Applied Energy, Elsevier, vol. 93(C), pages 90-97.
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    Cited by:

    1. Indro Biswas & Daniel G. Sánchez & Mathias Schulze & Jens Mitzel & Benjamin Kimmel & Aldo Saul Gago & Pawel Gazdzicki & K. Andreas Friedrich, 2020. "Advancement of Segmented Cell Technology in Low Temperature Hydrogen Technologies," Energies, MDPI, vol. 13(9), pages 1-22, May.
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    4. Ding, Feng & Zou, Tingting & Wei, Tao & Chen, Lei & Qin, Xiaoping & Shao, Zhigang & Yang, Jianjun, 2023. "The pinhole effect on proton exchange membrane fuel cell (PEMFC) current density distribution and temperature distribution," Applied Energy, Elsevier, vol. 342(C).
    5. Meng, Kai & Chen, Ben & Zhou, Haoran & Shen, Jun & Shen, Zuguo & Tu, Zhengkai, 2022. "Investigation on degradation mechanism of hydrogen–oxygen proton exchange membrane fuel cell under current cyclic loading," Energy, Elsevier, vol. 242(C).
    6. Zuo, Jian & Lv, Hong & Zhou, Daming & Xue, Qiong & Jin, Liming & Zhou, Wei & Yang, Daijun & Zhang, Cunman, 2021. "Deep learning based prognostic framework towards proton exchange membrane fuel cell for automotive application," Applied Energy, Elsevier, vol. 281(C).
    7. Chu, Tiankuo & Xie, Meng & Yu, Yue & Wang, Baoyun & Yang, Daijun & Li, Bing & Ming, Pingwen & Zhang, Cunman, 2022. "Experimental study of the influence of dynamic load cycle and operating parameters on the durability of PEMFC," Energy, Elsevier, vol. 239(PD).
    8. Fan, Ruijia & Chang, Guofeng & Xu, Yiming & Zhang, Yuanzhi, 2024. "Investigating the transient electrical behaviors in PEM fuel cells under various platinum distributions within cathode catalyst layers," Applied Energy, Elsevier, vol. 359(C).
    9. Zhang, Qian & Schulze, Mathias & Gazdzicki, Pawel & Friedrich, K. Andreas, 2021. "Comparison of different performance recovery procedures for polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 302(C).

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