IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v251y2019ic8.html
   My bibliography  Save this article

Effects of energetic heterogeneity on gas adsorption and gas storage in geologic shale systems

Author

Listed:
  • Li, Jing
  • Wu, Keliu
  • Chen, Zhangxin
  • Wang, Wenyang
  • Yang, Bin
  • Wang, Kun
  • Luo, Jia
  • Yu, Renjie

Abstract

Capturing heterogeneity in an adsorbate-adsorbent interaction is important to understand the underlying mechanisms controlling adsorption behavior; especially, for natural shale characterized by various mineral compositions and multi-scale pore sizes, its energetic heterogeneity is extremely complex. In this work, experimental investigations of methane adsorption on natural shale were conducted over a range of pressures (0.5–20 MPa) and temperatures (333–393 K), and a multi-site model was introduced to describe the measured adsorption isotherms. Specially, the adsorption energy distribution in our model is related to a pore-size and surface-property dependent function, rather than any traditionally assumed ones, such as Gaussian or exponential distributions. Besides, as an apparent indicator of adsorbent heterogeneity, isosteric heat was analyzed for our studied shales. Results showed that isosteric heat for an energetically homogeneous adsorbent is a constant, while the observed heat for our studied shales gradually decreases with an increase in surface coverage. This coverage-dependent heat is mainly controlled by the ordered occupation of gas molecules on heterogeneous adoption sites; in this respect, the most favorable sites with the highest energy are occupied first followed by secondary sites with lower energy. Furthermore, in application fields, our proposed model can be used to estimate total gas in place for a whole shale gas reservoir and gas resources contributed by individual pores. This work presents comprehensive knowledge about the effect of surface heterogeneity on methane adsorption on shale, and can thus be used as a solid foundation for accurately estimating gas storage and production in geologic systems.

Suggested Citation

  • Li, Jing & Wu, Keliu & Chen, Zhangxin & Wang, Wenyang & Yang, Bin & Wang, Kun & Luo, Jia & Yu, Renjie, 2019. "Effects of energetic heterogeneity on gas adsorption and gas storage in geologic shale systems," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    • Handle: RePEc:eee:appene:v:251:y:2019:i:c:8
    DOI: 10.1016/j.apenergy.2019.113368
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261919310426
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2019.113368?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Chen, Yuntian & Jiang, Su & Zhang, Dongxiao & Liu, Chaoyang, 2017. "An adsorbed gas estimation model for shale gas reservoirs via statistical learning," Applied Energy, Elsevier, vol. 197(C), pages 327-341.
    2. Wang, Ke & Li, Haitao & Wang, Junchao & Jiang, Beibei & Bu, Chengzhong & Zhang, Qing & Luo, Wei, 2017. "Predicting production and estimated ultimate recoveries for shale gas wells: A new methodology approach," Applied Energy, Elsevier, vol. 206(C), pages 1416-1431.
    3. Wang, Wenyang & Pang, Xiongqi & Chen, Zhangxin & Chen, Dongxia & Zheng, Tianyu & Luo, Bing & Li, Jing & Yu, Rui, 2019. "Quantitative prediction of oil and gas prospects of the Sinian-Lower Paleozoic in the Sichuan Basin in central China," Energy, Elsevier, vol. 174(C), pages 861-872.
    4. Middleton, Richard S. & Gupta, Rajan & Hyman, Jeffrey D. & Viswanathan, Hari S., 2017. "The shale gas revolution: Barriers, sustainability, and emerging opportunities," Applied Energy, Elsevier, vol. 199(C), pages 88-95.
    5. Crow, Daniel J.G. & Giarola, Sara & Hawkes, Adam D., 2018. "A dynamic model of global natural gas supply," Applied Energy, Elsevier, vol. 218(C), pages 452-469.
    6. Huang, Liang & Ning, Zhengfu & Wang, Qing & Zhang, Wentong & Cheng, Zhilin & Wu, Xiaojun & Qin, Huibo, 2018. "Effect of organic type and moisture on CO2/CH4 competitive adsorption in kerogen with implications for CO2 sequestration and enhanced CH4 recovery," Applied Energy, Elsevier, vol. 210(C), pages 28-43.
    7. Feijoo, Felipe & Iyer, Gokul C. & Avraam, Charalampos & Siddiqui, Sauleh A. & Clarke, Leon E. & Sankaranarayanan, Sriram & Binsted, Matthew T. & Patel, Pralit L. & Prates, Nathalia C. & Torres-Alfaro,, 2018. "The future of natural gas infrastructure development in the United states," Applied Energy, Elsevier, vol. 228(C), pages 149-166.
    8. Yuan, Jiehui & Luo, Dongkun & Feng, Lianyong, 2015. "A review of the technical and economic evaluation techniques for shale gas development," Applied Energy, Elsevier, vol. 148(C), pages 49-65.
    9. Luke Conibear & Edward W. Butt & Christoph Knote & Stephen R. Arnold & Dominick V. Spracklen, 2018. "Residential energy use emissions dominate health impacts from exposure to ambient particulate matter in India," Nature Communications, Nature, vol. 9(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhang, Tao & Zhang, Lei & Wang, Yongke & Qiao, Xiangyang & Feng, Dong & Zhao, Wen & Li, Xiangfang, 2020. "An integrated well-pattern optimization strategy to unlock continental tight gas reservoir in China," Energy, Elsevier, vol. 209(C).
    2. Hongyan Wang & Shangwen Zhou & Jiehui Zhang & Ziqi Feng & Pengfei Jiao & Leifu Zhang & Qin Zhang, 2021. "Clarifying the Effect of Clay Minerals on Methane Adsorption Capacity of Marine Shales in Sichuan Basin, China," Energies, MDPI, vol. 14(20), pages 1-15, October.
    3. Wu, Jian & Shen, Luming & Huang, Pengyu & Gan, Yixiang, 2023. "Selective adsorption and transport of CO2–CH4 mixture under nano-confinement," Energy, Elsevier, vol. 273(C).
    4. Wang, Hui & Chen, Li & Qu, Zhiguo & Yin, Ying & Kang, Qinjun & Yu, Bo & Tao, Wen-Quan, 2020. "Modeling of multi-scale transport phenomena in shale gas production — A critical review," Applied Energy, Elsevier, vol. 262(C).
    5. Song, Yilei & Song, Zhaojie & Chen, Zhangxin & Zhang, Lichao & Zhang, Yunfei & Feng, Dong & Wu, Zhengbin & Wu, Jiapeng, 2024. "Fluid phase behavior in multi-scale shale reservoirs with nano-confinement effect," Energy, Elsevier, vol. 289(C).
    6. Li, Dafang & Sun, Weifu & Chen, Yangchaoyue, 2024. "Enhancing overpressure and velocity of methane detonation by adding sodium chlorate with a view to fracturing shale," Applied Energy, Elsevier, vol. 355(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wang, Hui & Chen, Li & Qu, Zhiguo & Yin, Ying & Kang, Qinjun & Yu, Bo & Tao, Wen-Quan, 2020. "Modeling of multi-scale transport phenomena in shale gas production — A critical review," Applied Energy, Elsevier, vol. 262(C).
    2. Jin, Xu & Wang, Xiaoqi & Yan, Weipeng & Meng, Siwei & Liu, Xiaodan & Jiao, Hang & Su, Ling & Zhu, Rukai & Liu, He & Li, Jianming, 2019. "Exploration and casting of large scale microscopic pathways for shale using electrodeposition," Applied Energy, Elsevier, vol. 247(C), pages 32-39.
    3. Ahn, Yuchan & Kim, Junghwan & Kwon, Joseph Sang-Il, 2020. "Optimal design of supply chain network with carbon dioxide injection for enhanced shale gas recovery," Applied Energy, Elsevier, vol. 274(C).
    4. Gong, Jianming & Qiu, Zhen & Zou, Caineng & Wang, Hongyan & Shi, Zhensheng, 2020. "An integrated assessment system for shale gas resources associated with graptolites and its application," Applied Energy, Elsevier, vol. 262(C).
    5. Yang, Ruiyue & Hong, Chunyang & Huang, Zhongwei & Song, Xianzhi & Zhang, Shikun & Wen, Haitao, 2019. "Coal breakage using abrasive liquid nitrogen jet and its implications for coalbed methane recovery," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    6. Yang, Run & Liu, Xiangui & Yu, Rongze & Hu, Zhiming & Duan, Xianggang, 2022. "Long short-term memory suggests a model for predicting shale gas production," Applied Energy, Elsevier, vol. 322(C).
    7. Wang, Wenyang & Pang, Xiongqi & Chen, Zhangxin & Chen, Dongxia & Ma, Xinhua & Zhu, Weiping & Zheng, Tianyu & Wu, Keliu & Zhang, Kun & Ma, Kuiyou, 2020. "Improved methods for determining effective sandstone reservoirs and evaluating hydrocarbon enrichment in petroliferous basins," Applied Energy, Elsevier, vol. 261(C).
    8. Devine, Mel T. & Russo, Marianna, 2019. "Liquefied natural gas and gas storage valuation: Lessons from the integrated Irish and UK markets," Applied Energy, Elsevier, vol. 238(C), pages 1389-1406.
    9. Nguyen, Phong & Carey, J. William & Viswanathan, Hari S. & Porter, Mark, 2018. "Effectiveness of supercritical-CO2 and N2 huff-and-puff methods of enhanced oil recovery in shale fracture networks using microfluidic experiments," Applied Energy, Elsevier, vol. 230(C), pages 160-174.
    10. Brown, Maxwell & Siddiqui, Sauleh & Avraam, Charalampos & Bistline, John & Decarolis, Joseph & Eshraghi, Hadi & Giarola, Sara & Hansen, Matthew & Johnston, Peter & Khanal, Saroj & Molar-Cruz, Anahi, 2021. "North American energy system responses to natural gas price shocks," Energy Policy, Elsevier, vol. 149(C).
    11. Gillessen, B. & Heinrichs, H. & Hake, J.-F. & Allelein, H.-J., 2019. "Natural gas as a bridge to sustainability: Infrastructure expansion regarding energy security and system transition," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    12. Niu, Wente & Lu, Jialiang & Sun, Yuping & Zhang, Xiaowei & Li, Qiaojing & Cao, Xu & Liang, Pingping & Zhan, Hongming, 2024. "Techno-economic integration evaluation in shale gas development based on ensemble learning," Applied Energy, Elsevier, vol. 357(C).
    13. Wang, Yan & Zhong, Dong-Liang & Li, Zheng & Li, Jian-Bo, 2020. "Application of tetra-n-butyl ammonium bromide semi-clathrate hydrate for CO2 capture from unconventional natural gases," Energy, Elsevier, vol. 197(C).
    14. Wang, Tianyu & Tian, Shouceng & Li, Gensheng & Zhang, Liyuan & Sheng, Mao & Ren, Wenxi, 2021. "Molecular simulation of gas adsorption in shale nanopores: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    15. Andres Soage & Ruben Juanes & Ignasi Colominas & Luis Cueto-Felgueroso, 2021. "The Impact of the Geometry of the Effective Propped Volume on the Economic Performance of Shale Gas Well Production," Energies, MDPI, vol. 14(9), pages 1-22, April.
    16. Feng, Gan & Kang, Yong & Sun, Ze-dong & Wang, Xiao-chuan & Hu, Yao-qing, 2019. "Effects of supercritical CO2 adsorption on the mechanical characteristics and failure mechanisms of shale," Energy, Elsevier, vol. 173(C), pages 870-882.
    17. Wang, Ke & Li, Haitao & Wang, Junchao & Jiang, Beibei & Bu, Chengzhong & Zhang, Qing & Luo, Wei, 2017. "Predicting production and estimated ultimate recoveries for shale gas wells: A new methodology approach," Applied Energy, Elsevier, vol. 206(C), pages 1416-1431.
    18. Gao, Zheng & Li, Bobo & Li, Jianhua & Jia, Lidan & Wang, Zhonghui, 2023. "Adsorption characteristics and thermodynamic analysis of shale in northern Guizhou, China: Measurement, modeling and prediction," Energy, Elsevier, vol. 262(PA).
    19. Weige Han & Zhendong Cui & Zhengguo Zhu, 2021. "The Effect of Perforation Spacing on the Variation of Stress Shadow," Energies, MDPI, vol. 14(13), pages 1-16, July.
    20. Hong, Bingyuan & Li, Xiaoping & Song, Shangfei & Chen, Shilin & Zhao, Changlong & Gong, Jing, 2020. "Optimal planning and modular infrastructure dynamic allocation for shale gas production," Applied Energy, Elsevier, vol. 261(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:251:y:2019:i:c:8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.