IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v224y2018icp300-308.html
   My bibliography  Save this article

Effects of water content and diluent pressure on the ignition of aqueous ammonia/ammonium nitrate and urea/ammonium nitrate fuels

Author

Listed:
  • Mosevitzky, Bar
  • Azoulay, Rotem
  • Naamat, Lilach
  • Shter, Gennady E.
  • Grader, Gideon S.

Abstract

Two aqueous monofuels composed of aqueous solutions of ammonia/ammonium nitrate and urea/ammonium nitrate have been suggested as feasible nitrogen-based hydrogen carriers. Such synthetic fuels can serve as long-term energy storage media, providing back-up power generation for intermittent renewable energy sources. The effects of diluents such as helium and water on the thermal behavior of these fuels are mostly unexplored. Experimental results indicated the fuels' autoignition temperature increases with diluent content due to the heat sink effect of the inert water and helium. Simulations were performed using an updated mechanism to study the reaction pathways leading to thermal autoignition. Isocyanic acid underwent hydrolysis generating NH3 and most of the CO2. Ammonia was oxidized by either NO3 or NO2 to form NH2 and either HNO3 or HONO. Nitric acid reacted with HONO producing N2O4 and most of the H2O. Molecular nitrogen was mostly produced by the termination reaction between NH2 and NO. Sensitivity analyses indicated the ignition of these fuels is promoted by the generation of NH2 from NH3 by high oxidation NOx, and inhibited by the reduction of NO3 and NO2 to NO2 and NO, respectively. This work demonstrates for the first time the effect of aqueous ammonia/ammonium nitrate water content on its auto-ignition temperature and the crucial role of isocyanic acid hydrolysis in aqueous urea/ammonium nitrate pre-ignition pathways.

Suggested Citation

  • Mosevitzky, Bar & Azoulay, Rotem & Naamat, Lilach & Shter, Gennady E. & Grader, Gideon S., 2018. "Effects of water content and diluent pressure on the ignition of aqueous ammonia/ammonium nitrate and urea/ammonium nitrate fuels," Applied Energy, Elsevier, vol. 224(C), pages 300-308.
    • Handle: RePEc:eee:appene:v:224:y:2018:i:c:p:300-308
    DOI: 10.1016/j.apenergy.2018.04.107
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261918306731
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.04.107?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Luo, Xing & Wang, Jihong & Dooner, Mark & Clarke, Jonathan, 2015. "Overview of current development in electrical energy storage technologies and the application potential in power system operation," Applied Energy, Elsevier, vol. 137(C), pages 511-536.
    2. Ryu, Kyunghyun & Zacharakis-Jutz, George E. & Kong, Song-Charng, 2014. "Effects of gaseous ammonia direct injection on performance characteristics of a spark-ignition engine," Applied Energy, Elsevier, vol. 116(C), pages 206-215.
    3. Ibrahim, H. & Ilinca, A. & Perron, J., 2008. "Energy storage systems--Characteristics and comparisons," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(5), pages 1221-1250, June.
    4. Brouwer, Anne Sjoerd & van den Broek, Machteld & Zappa, William & Turkenburg, Wim C. & Faaij, André, 2016. "Least-cost options for integrating intermittent renewables in low-carbon power systems," Applied Energy, Elsevier, vol. 161(C), pages 48-74.
    5. Valera-Medina, Agustin & Marsh, Richard & Runyon, Jon & Pugh, Daniel & Beasley, Paul & Hughes, Timothy & Bowen, Phil, 2017. "Ammonia–methane combustion in tangential swirl burners for gas turbine power generation," Applied Energy, Elsevier, vol. 185(P2), pages 1362-1371.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Rafael Estevez & Francisco J. López-Tenllado & Laura Aguado-Deblas & Felipa M. Bautista & Antonio A. Romero & Diego Luna, 2023. "Current Research on Green Ammonia (NH 3 ) as a Potential Vector Energy for Power Storage and Engine Fuels: A Review," Energies, MDPI, vol. 16(14), pages 1-33, July.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Meng, Hui & Wang, Meihong & Olumayegun, Olumide & Luo, Xiaobo & Liu, Xiaoyan, 2019. "Process design, operation and economic evaluation of compressed air energy storage (CAES) for wind power through modelling and simulation," Renewable Energy, Elsevier, vol. 136(C), pages 923-936.
    2. Muhammad Aziz & Agung Tri Wijayanta & Asep Bayu Dani Nandiyanto, 2020. "Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization," Energies, MDPI, vol. 13(12), pages 1-25, June.
    3. Martin, Nigel & Rice, John, 2021. "Power outages, climate events and renewable energy: Reviewing energy storage policy and regulatory options for Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    4. Emmanouil, Stergios & Nikolopoulos, Efthymios I. & François, Baptiste & Brown, Casey & Anagnostou, Emmanouil N., 2021. "Evaluating existing water supply reservoirs as small-scale pumped hydroelectric storage options – A case study in Connecticut," Energy, Elsevier, vol. 226(C).
    5. Kapila, Sahil & Oni, Abayomi Olufemi & Kumar, Amit, 2017. "The development of techno-economic models for large-scale energy storage systems," Energy, Elsevier, vol. 140(P1), pages 656-672.
    6. Nimat Shamim & Vilayanur V. Viswanathan & Edwin C. Thomsen & Guosheng Li & David M. Reed & Vincent L. Sprenkle, 2022. "Valve Regulated Lead Acid Battery Evaluation under Peak Shaving and Frequency Regulation Duty Cycles," Energies, MDPI, vol. 15(9), pages 1-19, May.
    7. Fan, Xiaoyu & Guo, Luna & Ji, Wei & Chen, Liubiao & Wang, Junjie, 2023. "Liquid air energy storage system based on fluidized bed heat transfer," Renewable Energy, Elsevier, vol. 215(C).
    8. Chen, Feng & Taylor, Nathaniel & Kringos, Nicole, 2015. "Electrification of roads: Opportunities and challenges," Applied Energy, Elsevier, vol. 150(C), pages 109-119.
    9. Parra, David & Swierczynski, Maciej & Stroe, Daniel I. & Norman, Stuart.A. & Abdon, Andreas & Worlitschek, Jörg & O’Doherty, Travis & Rodrigues, Lucelia & Gillott, Mark & Zhang, Xiaojin & Bauer, Chris, 2017. "An interdisciplinary review of energy storage for communities: Challenges and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 730-749.
    10. Sanghyun Hong & Barry W. Brook, 2018. "At the crossroads: An uncertain future facing the electricity‐generation sector in South Korea," Asia and the Pacific Policy Studies, Wiley Blackwell, vol. 5(3), pages 522-532, September.
    11. Chen Yang & Li Sun & Hao Chen, 2023. "Thermodynamics Analysis of a Novel Compressed Air Energy Storage System Combined with Solid Oxide Fuel Cell–Micro Gas Turbine and Using Low-Grade Waste Heat as Heat Source," Energies, MDPI, vol. 16(19), pages 1-28, October.
    12. Yang, Yuqing & Bremner, Stephen & Menictas, Chris & Kay, Merlinde, 2018. "Battery energy storage system size determination in renewable energy systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 109-125.
    13. Cruz, Marco R.M. & Fitiwi, Desta Z. & Santos, Sérgio F. & Catalão, João P.S., 2018. "A comprehensive survey of flexibility options for supporting the low-carbon energy future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 97(C), pages 338-353.
    14. Arani, A.A. Khodadoost & Karami, H. & Gharehpetian, G.B. & Hejazi, M.S.A., 2017. "Review of Flywheel Energy Storage Systems structures and applications in power systems and microgrids," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 9-18.
    15. Mejia, Cristian & Kajikawa, Yuya, 2020. "Emerging topics in energy storage based on a large-scale analysis of academic articles and patents," Applied Energy, Elsevier, vol. 263(C).
    16. Inal, Omer Berkehan & Charpentier, Jean-Frédéric & Deniz, Cengiz, 2022. "Hybrid power and propulsion systems for ships: Current status and future challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
    17. Guerra, Omar J. & Tejada, Diego A. & Reklaitis, Gintaras V., 2016. "An optimization framework for the integrated planning of generation and transmission expansion in interconnected power systems," Applied Energy, Elsevier, vol. 170(C), pages 1-21.
    18. Sciacovelli, Adriano & Li, Yongliang & Chen, Haisheng & Wu, Yuting & Wang, Jihong & Garvey, Seamus & Ding, Yulong, 2017. "Dynamic simulation of Adiabatic Compressed Air Energy Storage (A-CAES) plant with integrated thermal storage – Link between components performance and plant performance," Applied Energy, Elsevier, vol. 185(P1), pages 16-28.
    19. Rodrigues, E.M.G. & Godina, R. & Catalão, J.P.S., 2017. "Modelling electrochemical energy storage devices in insular power network applications supported on real data," Applied Energy, Elsevier, vol. 188(C), pages 315-329.
    20. Olabi, A.G. & Onumaegbu, C. & Wilberforce, Tabbi & Ramadan, Mohamad & Abdelkareem, Mohammad Ali & Al – Alami, Abdul Hai, 2021. "Critical review of energy storage systems," Energy, Elsevier, vol. 214(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:224:y:2018:i:c:p:300-308. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.