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Non-catalytic upgrading of fast pyrolysis bio-oil in supercritical ethanol and combustion behavior of the upgraded oil

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  • Prajitno, Hermawan
  • Insyani, Rizki
  • Park, Jongkeun
  • Ryu, Changkook
  • Kim, Jaehoon

Abstract

Fast pyrolysis bio-oil derived from empty palm fruit bunch was upgraded in supercritical ethanol (scEtOH) without using external catalysts and molecular hydrogen. The effects of the reaction temperature and time on the product yield and the quality of the upgraded oil based on parameters like the elemental content, total acid number (TAN), water content, high heating value (HHV), and viscosity were examined. At 400°C, almost all of the organic species in the fast pyrolysis bio-oil were converted to the liquid and gas phase in 30min, resulting in a high yield of the upgraded oil (83.0wt%) with an enhanced HHV of 34.1MJkg−1 and very low values of TAN (4.8mgKOHg−1) and water (1.6wt%) when compared to the fast pyrolysis bio-oil (HHV, 24.3MJkg−1; TAN, 69.4mgKOHg−1; water, 14.0wt%). The major chemical species in the upgraded oil were alcohols, esters, phenols, hydrocarbons, and aromatics. After aging at 80°C for one week, a marginal increase in the viscosity of the upgraded bio-oil was observed, indicating a significant improvement in the stability of the bio-oil. Computational fluid dynamics (CFD) analysis of the process performed in a commercial boiler demonstrated that the upgraded oil firing exhibited high gas temperature profiles, a high firing peak of 1599°C, and a high total heat transfer rate of 121.81MWth. These results are comparable to the performance parameters of conventional heavy oil-firing processes.

Suggested Citation

  • Prajitno, Hermawan & Insyani, Rizki & Park, Jongkeun & Ryu, Changkook & Kim, Jaehoon, 2016. "Non-catalytic upgrading of fast pyrolysis bio-oil in supercritical ethanol and combustion behavior of the upgraded oil," Applied Energy, Elsevier, vol. 172(C), pages 12-22.
    • Handle: RePEc:eee:appene:v:172:y:2016:i:c:p:12-22
    DOI: 10.1016/j.apenergy.2016.03.093
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    1. Zhang, Qing & Xu, Ying & Li, Yuping & Wang, Tiejun & Zhang, Qi & Ma, Longlong & He, Minghong & Li, Kai, 2015. "Investigation on the esterification by using supercritical ethanol for bio-oil upgrading," Applied Energy, Elsevier, vol. 160(C), pages 633-640.
    2. Kim, Tae-Seung & Oh, Shinyoung & Kim, Jae-Young & Choi, In-Gyu & Choi, Joon Weon, 2014. "Study on the hydrodeoxygenative upgrading of crude bio-oil produced from woody biomass by fast pyrolysis," Energy, Elsevier, vol. 68(C), pages 437-443.
    3. Brand, Steffen & Susanti, Ratna Frida & Kim, Seok Ki & Lee, Hong-shik & Kim, Jaehoon & Sang, Byung-In, 2013. "Supercritical ethanol as an enhanced medium for lignocellulosic biomass liquefaction: Influence of physical process parameters," Energy, Elsevier, vol. 59(C), pages 173-182.
    4. Zhang, Xinghua & Chen, Lungang & Kong, Wei & Wang, Tiejun & Zhang, Qi & Long, Jinxing & Xu, Ying & Ma, Longlong, 2015. "Upgrading of bio-oil to boiler fuel by catalytic hydrotreatment and esterification in an efficient process," Energy, Elsevier, vol. 84(C), pages 83-90.
    5. Xiu, Shuangning & Shahbazi, Abolghasem, 2012. "Bio-oil production and upgrading research: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4406-4414.
    6. Brand, Steffen & Kim, Jaehoon, 2015. "Liquefaction of major lignocellulosic biomass constituents in supercritical ethanol," Energy, Elsevier, vol. 80(C), pages 64-74.
    7. Zhu, Yunhua & Biddy, Mary J. & Jones, Susanne B. & Elliott, Douglas C. & Schmidt, Andrew J., 2014. "Techno-economic analysis of liquid fuel production from woody biomass via hydrothermal liquefaction (HTL) and upgrading," Applied Energy, Elsevier, vol. 129(C), pages 384-394.
    8. Zhang, Le & Liu, Ronghou & Yin, Renzhan & Mei, Yuanfei, 2013. "Upgrading of bio-oil from biomass fast pyrolysis in China: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 66-72.
    9. Xu, Ying & Wang, Tiejun & Ma, Longlong & Zhang, Qi & Liang, Wei, 2010. "Upgrading of the liquid fuel from fast pyrolysis of biomass over MoNi/[gamma]-Al2O3 catalysts," Applied Energy, Elsevier, vol. 87(9), pages 2886-2891, September.
    10. Fatih Demirbas, M., 2009. "Biorefineries for biofuel upgrading: A critical review," Applied Energy, Elsevier, vol. 86(Supplemen), pages 151-161, November.
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    6. Muley, P.D. & Henkel, C.E. & Aguilar, G. & Klasson, K.T. & Boldor, D., 2016. "Ex situ thermo-catalytic upgrading of biomass pyrolysis vapors using a traveling wave microwave reactor," Applied Energy, Elsevier, vol. 183(C), pages 995-1004.
    7. Li, Haowei & Ma, Hongwei & Zhao, Weijie & Li, Xuehui & Long, Jinxing, 2019. "Upgrading lignin bio-oil for oxygen-containing fuel production using Ni/MgO: Effect of the catalyst calcination temperature," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    8. Remón, J. & Arcelus-Arrillaga, P. & García, L. & Arauzo, J., 2018. "Simultaneous production of gaseous and liquid biofuels from the synergetic co-valorisation of bio-oil and crude glycerol in supercritical water," Applied Energy, Elsevier, vol. 228(C), pages 2275-2287.
    9. Wan Mahari, Wan Adibah & Chong, Cheng Tung & Cheng, Chin Kui & Lee, Chern Leing & Hendrata, Kristian & Yuh Yek, Peter Nai & Ma, Nyuk Ling & Lam, Su Shiung, 2018. "Production of value-added liquid fuel via microwave co-pyrolysis of used frying oil and plastic waste," Energy, Elsevier, vol. 162(C), pages 309-317.
    10. Do, Truong Xuan & Mujahid, Rana & Lim, Hyun Soo & Kim, Jae-Kon & Lim, Young-Il & Kim, Jaehoon, 2020. "Techno-economic analysis of bio heavy-oil production from sewage sludge using supercritical and subcritical water," Renewable Energy, Elsevier, vol. 151(C), pages 30-42.
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