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Reactive absorption of CO2 into enzyme accelerated solvents: From laboratory to pilot scale

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  • Kunze, Anna-Katharina
  • Dojchinov, Greg
  • Haritos, Victoria S.
  • Lutze, Philip

Abstract

CO2 capture could contribute to a reduction of CO2 emissions by decreasing CO2 concentrations in flue gas streams of fossil fuelled power plants. State of the art technology for CO2 capture is reactive absorption using monoethanolamine (MEA) as a solvent, which requires a high energy demand for solvent regeneration in a continuous process. This study investigated the ability of the biocatalyst carbonic anhydrase, to significantly increase the absorption rate when combined with reactive solvents. Based on laboratory scale experiments the proof of chemical capability was evaluated for different solvents. CO2 absorption rates of 30wt.% MEA, 30wt.% N-methyldiethanolamine (MDEA), 30wt.% diethylethanolamine (DEEA) and 10wt.% potassium carbonate (K2CO3) were measured with the addition of carbonic anhydrase (0.2wt.%). Aqueous solutions of 30wt.% MDEA as well as 30wt.% K2CO3 were identified as promising solvents whose CO2 absorption rate was accelerated by the enzyme, as the addition of 0.2wt.% carbonic anhydrase led to an increase of the absorbed mole flow by a factor>4. Next, the technical feasibility of the enzyme-solvent concept was tested in packed columns to check for transferability of laboratory scale performance to pilot scale (diameter: 56mm, height: 2.3m, Sulzer BX gauze packing). The increase of the absorbed mole flow in pilot scale in the presence of biocatalyst was in good accordance with the laboratory scale experiments. No undesired effects such as foaming or aggregation were observed. Subsequently, mass transfer parameter determination was performed for enzyme-solvent combinations in a wetted wall column. Together, the data presented in this study enables for the first time, the application of rigorous models for conceptual process design for biocatalyst-accelerated CO2 capture.

Suggested Citation

  • Kunze, Anna-Katharina & Dojchinov, Greg & Haritos, Victoria S. & Lutze, Philip, 2015. "Reactive absorption of CO2 into enzyme accelerated solvents: From laboratory to pilot scale," Applied Energy, Elsevier, vol. 156(C), pages 676-685.
    • Handle: RePEc:eee:appene:v:156:y:2015:i:c:p:676-685
    DOI: 10.1016/j.apenergy.2015.07.033
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    References listed on IDEAS

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    1. Li, Bingyun & Duan, Yuhua & Luebke, David & Morreale, Bryan, 2013. "Advances in CO2 capture technology: A patent review," Applied Energy, Elsevier, vol. 102(C), pages 1439-1447.
    2. Rubin, Edward S. & Chen, Chao & Rao, Anand B., 2007. "Cost and performance of fossil fuel power plants with CO2 capture and storage," Energy Policy, Elsevier, vol. 35(9), pages 4444-4454, September.
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    1. Sara Peirce & Rosa Perfetto & Maria Elena Russo & Clemente Capasso & Mosè Rossi & Piero Salatino & Antonio Marzocchella, 2018. "Characterization of technical grade carbonic anhydrase as biocatalyst for CO2 capture in potassium carbonate solutions," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(2), pages 279-291, April.
    2. Leimbrink, Mathias & Sandkämper, Stephanie & Wardhaugh, Leigh & Maher, Dan & Green, Phil & Puxty, Graeme & Conway, Will & Bennett, Robert & Botma, Henk & Feron, Paul & Górak, Andrzej & Skiborowski, Mi, 2017. "Energy-efficient solvent regeneration in enzymatic reactive absorption for carbon dioxide capture," Applied Energy, Elsevier, vol. 208(C), pages 263-276.
    3. Putta, Koteswara Rao & Tobiesen, Finn Andrew & Svendsen, Hallvard F. & Knuutila, Hanna K., 2017. "Applicability of enhancement factor models for CO2 absorption into aqueous MEA solutions," Applied Energy, Elsevier, vol. 206(C), pages 765-783.
    4. Wang, Fu & Zhao, Jun & Li, Hailong & Deng, Shuai & Yan, Jinyue, 2017. "Preliminary experimental study of post-combustion carbon capture integrated with solar thermal collectors," Applied Energy, Elsevier, vol. 185(P2), pages 1471-1480.
    5. Rongrong Zhai & Hongtao Liu & Hao Wu & Hai Yu & Yongping Yang, 2018. "Analysis of Integration of MEA-Based CO 2 Capture and Solar Energy System for Coal-Based Power Plants Based on Thermo-Economic Structural Theory," Energies, MDPI, vol. 11(5), pages 1-30, May.
    6. Qi, Guojie & Liu, Kun & House, Alan & Salmon, Sonja & Ambedkar, Balraj & Frimpong, Reynolds A. & Remias, Joseph E. & Liu, Kunlei, 2018. "Laboratory to bench-scale evaluation of an integrated CO2 capture system using a thermostable carbonic anhydrase promoted K2CO3 solvent with low temperature vacuum stripping," Applied Energy, Elsevier, vol. 209(C), pages 180-189.

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