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Experimental and simulation studies for reaction enhancement of catalytic CF4 hydrolysis by consecutive HF removal using a multi†stage catalyst†adsorbent reactor

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  • Jae†Yun Han
  • Chang†Hyun Kim
  • Boreum Lee
  • Seonju Jeong
  • Hankwon Lim
  • Kwan†Young Lee
  • Shin†Kun Ryi

Abstract

In this paper, a multi†stage catalyst†adsorbent reactor consisting of a series of catalyst and adsorbent beds is proposed for an effective tetrafluoromethane (CF4) abatement and conversion of corrosive hydrogen fluoride (HF) to CaF2, a useful chemical. Experimentally, enhanced CF4 conversions were observed in multi†stage catalyst†adsorbent reactors compared to a zero†stage reactor (catalyst bed only) confirming sorption†enhanced CF4 hydrolysis due to selective removal of HF during reaction. In addition, some useful design guidelines to select the number of stages and a proper time to replace adsorbents are presented. To develop a process simulation model to represent experimental data, Aspen HYSYS®, a commercial process simulator, was used providing a proper model to match experimental data quite reasonably. Based on experimental and simulative studies, a three†or four†stage catalyst†adsorbent reactor is recommended for CF4 abatement considering both reactor performance and capital/operating expenditures. © 2017 Society of Chemical Industry and John Wiley & Sons, Ltd.

Suggested Citation

  • Jae†Yun Han & Chang†Hyun Kim & Boreum Lee & Seonju Jeong & Hankwon Lim & Kwan†Young Lee & Shin†Kun Ryi, 2017. "Experimental and simulation studies for reaction enhancement of catalytic CF4 hydrolysis by consecutive HF removal using a multi†stage catalyst†adsorbent reactor," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(6), pages 1141-1149, December.
  • Handle: RePEc:wly:greenh:v:7:y:2017:i:6:p:1141-1149
    DOI: 10.1002/ghg.1742
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    References listed on IDEAS

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    1. Boreum Lee & Seonju Jeong & Sunggeun Lee & Ho‐Young Jung & Shin‐Kun Ryi & Hankwon Lim, 2017. "Preliminary techno‐economic analysis of a multi‐bed series reactor as a simultaneous CF 4 abatement and utilization process," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(3), pages 542-549, June.
    2. Somers, C. & Mortazavi, A. & Hwang, Y. & Radermacher, R. & Rodgers, P. & Al-Hashimi, S., 2011. "Modeling water/lithium bromide absorption chillers in ASPEN Plus," Applied Energy, Elsevier, vol. 88(11), pages 4197-4205.
    3. Wenfeng Han & Yuliang Chen & Bibo Jin & Huazhang Liu & Hai Yu, 2014. "Catalytic hydrolysis of trifluoromethane over alumina," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 4(1), pages 121-130, February.
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