IDEAS home Printed from https://ideas.repec.org/a/wly/greenh/v7y2017i2p383-394.html
   My bibliography  Save this article

Effect of Fe open metal site in metal‐organic frameworks on post‐combustion CO 2 capture performance

Author

Listed:
  • Suwimol Wongsakulphasatch
  • Worapon Kiatkittipong
  • Janenipa Saupsor
  • Jatuphol Chaiwiseshphol
  • Pakorn Piroonlerkgul
  • Vudhichai Parasuk
  • Suttichai Assabumrungrat

Abstract

Iron open metal site in metal‐organic frameworks, MIL‐88A and MIL‐127(Fe), was tested to investigate its performance on CO 2 separation from a binary mixture CO 2 /N 2 under simulated post‐combustion system. The sorption experiment tests were conducted via a fixed‐bed reactor with different temperatures ranging between 30°C and 60°C at atmospheric pressure. Maximum CO 2 sorption capacity was observed at low temperature of 30°C, where 5.24 mmol could be adsorbed by one gram of MIL‐127(Fe) and 4.95 mmol CO 2 could be adsorbed by one gram of MIL‐88A. The presence of moisture in the gas mixture affected CO 2 sorption capacity by reducing CO 2 capacity as high as 0.5 mmol CO 2 per one gram sorbent. In this work, a dynamic breakthrough model was applied to investigate adsorption behavior of the metal‐organic frameworks (MOFs) and of the system. The predicted model showed good agreement with experimental results; the Langmuir isotherm model fitted well with our sorption system, suggesting one molecule of CO 2 is held at localized sites of the MOFs, which plausibly be at unsaturated Fe-super-2+ metal ion site. Rate of sorption was found to increase with increasing sorption temperature for either intra‐particle diffusivity or external mass transfer. Our study suggests that the MOFs containing Fe open metal sites offer an outstanding prospective for CO 2 sorption and both MIL‐88A and MIL‐127(Fe) are good representatives applied for post‐combustion CO 2 capture. © 2016 Society of Chemical Industry and John Wiley & Sons, Ltd.

Suggested Citation

  • Suwimol Wongsakulphasatch & Worapon Kiatkittipong & Janenipa Saupsor & Jatuphol Chaiwiseshphol & Pakorn Piroonlerkgul & Vudhichai Parasuk & Suttichai Assabumrungrat, 2017. "Effect of Fe open metal site in metal‐organic frameworks on post‐combustion CO 2 capture performance," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(2), pages 383-394, April.
    • Handle: RePEc:wly:greenh:v:7:y:2017:i:2:p:383-394
    as

    Download full text from publisher

    File URL: http://hdl.handle.net/10.1002/ghg.1662
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Yangyang Liu & Zhiyong U. Wang & Hong‐Cai Zhou, 2012. "Recent advances in carbon dioxide capture with metal‐organic frameworks," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 2(4), pages 239-259, August.
    2. Sreenivasulu, B. & Gayatri, D.V. & Sreedhar, I. & Raghavan, K.V., 2015. "A journey into the process and engineering aspects of carbon capture technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1324-1350.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jia Yen Lai & Lock Hei Ngu & Siti Salwa Hashim, 2021. "A review of CO2 adsorbents performance for different carbon capture technology processes conditions," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(5), pages 1076-1117, October.
    2. Slyvester Yew Wang Chai & Lock Hei Ngu & Bing Shen How, 2022. "Review of carbon capture absorbents for CO2 utilization," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 12(3), pages 394-427, June.
    3. Amin Mojarad Garehbagh & Saeid Rajabzadeh & Mahmoud A. Shouman & Mohamed R. Elmarghany & Mohamed S. Salem & Nasrul Arahman & Toraj Mohammadi & Hideto Matsuyama, 2022. "Simulation Assessment of Inlet Parameters and Membrane-Surface-Structure Effects on CO 2 Absorption Flux in Membrane Contactors," Sustainability, MDPI, vol. 14(21), pages 1-15, November.
    4. Ovaid Mehmood & Sarah Farrukh & Arshad Hussain & Mohammad Younas & Zarrar Salahuddin & Erum Pervaiz & Muhammad Ayoub, 2021. "Investigation of cellulose acetate/gamma‐cyclodextrin MOF based mixed matrix membranes for CO2/CH4 gas separation," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(2), pages 313-330, April.
    5. Nicholas S. Siefert & Sarah Narburgh & Yang Chen, 2016. "Comprehensive Exergy Analysis of Three IGCC Power Plant Configurations with CO 2 Capture," Energies, MDPI, vol. 9(9), pages 1-19, August.
    6. Mansir, Ibrahim B. & Nemitallah, Medhat A. & Habib, Mohamed A. & Khalifa, Atia E., 2018. "Experimental and numerical investigation of flow field and oxy-methane combustion characteristics in a low-power porous-plate reactor," Energy, Elsevier, vol. 160(C), pages 783-795.
    7. Powell, Kody M. & Rashid, Khalid & Ellingwood, Kevin & Tuttle, Jake & Iverson, Brian D., 2017. "Hybrid concentrated solar thermal power systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 215-237.
    8. Vahid Barahimi & Monica Ho & Eric Croiset, 2023. "From Lab to Fab: Development and Deployment of Direct Air Capture of CO 2," Energies, MDPI, vol. 16(17), pages 1-33, September.
    9. von Bohnstein, Maximilian & Richter, Marcel & Graeser, Phillip & Schiemann, Martin & Ströhle, Jochen & Epple, Bernd, 2021. "3D CFD simulation of a 250 MWel oxy-fuel boiler with evaluation of heat radiation calculation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    10. Li, Hongwei & Tang, Zhigang & Li, Na & Cui, Longpeng & Mao, Xian-zhong, 2020. "Mechanism and process study on steel slag enhancement for CO2 capture by seawater," Applied Energy, Elsevier, vol. 276(C).
    11. Taheri Najafabadi, Amin, 2015. "Emerging applications of graphene and its derivatives in carbon capture and conversion: Current status and future prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1515-1545.
    12. Mohd Mu’Izzuddin Mohd Pauzi & Nurulhuda Azmi & Kok Keong Lau, 2022. "Emerging Solvent Regeneration Technologies for CO 2 Capture through Offshore Natural Gas Purification Processes," Sustainability, MDPI, vol. 14(7), pages 1-18, April.
    13. Sreedhar, I. & Vaidhiswaran, R. & Kamani, Bansi. M. & Venugopal, A., 2017. "Process and engineering trends in membrane based carbon capture," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 659-684.
    14. Abdelkareem, Mohammad Ali & Abbas, Qaisar & Sayed, Enas Taha & Shehata, N. & Parambath, J.B.M. & Alami, Abdul Hai & Olabi, A.G., 2024. "Recent advances on metal-organic frameworks (MOFs) and their applications in energy conversion devices: Comprehensive review," Energy, Elsevier, vol. 299(C).
    15. Janusz Zdeb & Natalia Howaniec, 2022. "Energy Sector Derived Combustion Products Utilization—Current Advances in Carbon Dioxide Mineralization," Energies, MDPI, vol. 15(23), pages 1-28, November.
    16. Bonalumi, Davide & Giuffrida, Antonio, 2016. "Investigations of an air-blown integrated gasification combined cycle fired with high-sulphur coal with post-combustion carbon capture by aqueous ammonia," Energy, Elsevier, vol. 117(P2), pages 439-449.
    17. Sittichain Pramchu & Atchara P. Jaroenjittichai & Yongyut Laosiritaworn, 2018. "Tuning carbon dioxide capture capability with structural and compositional design in mmen‐(Mg,Zn) (dobpdc) metal‐organic framework: density functional theory investigation," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(3), pages 580-586, June.
    18. Alfe, M. & Policicchio, A. & Lisi, L. & Gargiulo, V., 2021. "Solid sorbents for CO2 and CH4 adsorption: The effect of metal organic framework hybridization with graphene-like layers on the gas sorption capacities at high pressure," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    19. Nejati, Kaveh & Aghel, Babak, 2023. "Utilizing fly ash from a power plant company for CO2 capture in a microchannel," Energy, Elsevier, vol. 278(PB).
    20. Jin, S.W. & Li, Y.P. & Nie, S. & Sun, J., 2017. "The potential role of carbon capture and storage technology in sustainable electric-power systems under multiple uncertainties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 467-480.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:wly:greenh:v:7:y:2017:i:2:p:383-394. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Wiley Content Delivery (email available below). General contact details of provider: https://doi.org/10.1002/(ISSN)2152-3878 .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.