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Investigation of co-combustion characteristics of distillery sludge and sugar mill waste: kinetics, synergy, and ash characterization

Author

Listed:
  • Vikash Singh

    (INHA University)

  • Seon Yeong Park

    (INHA University)

  • Eun Seo Lee

    (INHA University)

  • Jun Ho Choi

    (INHA University)

  • Chang Gyun Kim

    (INHA University
    INHA University)

  • Vimal Chandra Srivastava

    (Indian Institute of Technology Roorkee)

Abstract

The co-combustion characteristics and synergy of distillery effluent sludge (DES) and sugar mill waste (SMW) were studied by thermogravimetric (TG) analysis. TG data were used to evaluate the combustion indices, synergy, kinetic parameters, and heterogeneous reaction mechanisms. The blend D1S3 (25% DES and 75% SMW) exhibited optimal combustion parameters (Ci = 2.69 × 10−4% min−3, Cb = 1.34 × 10−6% min−4, and CCI = 13.02 × 10−7%2 °C−3 min−2). Mixing DES with SMW resulted in a positive synergy that facilitated effective combustion owing to the presence of Fe, Ca, and Mg in DES, which served as catalysts during combustion. For D1S3, the apparent activation energy (*Ea) calculated using FWO, KAS, and ST iso-conversional methods were 173.3, 172.4, and 172.7 kJ mol−1, respectively. The master plots revealed that the combustion process was governed by the D1, D3, F2, and F3 solid-state kinetic models in different conversion (α) ranges for the wastes and their blends. Finally, the presence of alkaline and alkaline-earth elements (Na, K, Mg, and Ca) was confirmed through ash characterization. Thus, the ash can be considered a possible supplementary cementing material for end-use applications.

Suggested Citation

  • Vikash Singh & Seon Yeong Park & Eun Seo Lee & Jun Ho Choi & Chang Gyun Kim & Vimal Chandra Srivastava, 2024. "Investigation of co-combustion characteristics of distillery sludge and sugar mill waste: kinetics, synergy, and ash characterization," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 26(8), pages 21217-21236, August.
  • Handle: RePEc:spr:endesu:v:26:y:2024:i:8:d:10.1007_s10668-023-03525-1
    DOI: 10.1007/s10668-023-03525-1
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    References listed on IDEAS

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