IDEAS home Printed from https://ideas.repec.org/a/nat/nature/v515y2014i7526d10.1038_nature13867.html
   My bibliography  Save this article

Formic-acid-induced depolymerization of oxidized lignin to aromatics

Author

Listed:
  • Alireza Rahimi

    (University of Wisconsin–Madison, 1101 University Avenue)

  • Arne Ulbrich

    (University of Wisconsin–Madison, 1101 University Avenue)

  • Joshua J. Coon

    (University of Wisconsin–Madison, 1101 University Avenue
    University of Wisconsin–Madison)

  • Shannon S. Stahl

    (University of Wisconsin–Madison, 1101 University Avenue)

Abstract

A method for the depolymerization of oxidized lignin under mild conditions in aqueous formic acid is described that results in more than 60 wt% yield of low-molecular-mass aromatics.

Suggested Citation

  • Alireza Rahimi & Arne Ulbrich & Joshua J. Coon & Shannon S. Stahl, 2014. "Formic-acid-induced depolymerization of oxidized lignin to aromatics," Nature, Nature, vol. 515(7526), pages 249-252, November.
    • Handle: RePEc:nat:nature:v:515:y:2014:i:7526:d:10.1038_nature13867
    DOI: 10.1038/nature13867
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/nature13867
    File Function: Abstract
    Download Restriction: Access to the full text of the articles in this series is restricted.
    File URL: https://libkey.io/10.1038/nature13867?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Leiming Hu & Jacob A. Wrubel & Carlos M. Baez-Cotto & Fry Intia & Jae Hyung Park & Arthur Jeremy Kropf & Nancy Kariuki & Zhe Huang & Ahmed Farghaly & Lynda Amichi & Prantik Saha & Ling Tao & David A. , 2023. "A scalable membrane electrode assembly architecture for efficient electrochemical conversion of CO2 to formic acid," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    2. Chio, Chonlong & Sain, Mohini & Qin, Wensheng, 2019. "Lignin utilization: A review of lignin depolymerization from various aspects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 232-249.
    3. Long, Jinxing & Shu, Riyang & Yuan, Zhengqiu & Wang, Tiejun & Xu, Ying & Zhang, Xinghua & Zhang, Qi & Ma, Longlong, 2015. "Efficient valorization of lignin depolymerization products in the present of NixMg1−xO," Applied Energy, Elsevier, vol. 157(C), pages 540-545.
    4. Li Xu & Meifang Cao & Jiefeng Zhou & Yuxia Pang & Zhixian Li & Dongjie Yang & Shao-Yuan Leu & Hongming Lou & Xuejun Pan & Xueqing Qiu, 2024. "Aqueous amine enables sustainable monosaccharide, monophenol, and pyridine base coproduction in lignocellulosic biorefineries," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    5. Haoyu Wang & Yipei Jiang & Evan Park & Xue Han & Yimin Zeng & Chunbao Xu, 2023. "Hydrothermal Liquefaction of Pinewood Sawdust: Influence of Reaction Atmosphere," Sustainability, MDPI, vol. 15(8), pages 1-18, April.
    6. Zhang, Yan & Song, Kuiyan, 2018. "Thermal and chemical characteristics of torrefied biomass derived from a generated volatile atmosphere," Energy, Elsevier, vol. 165(PB), pages 235-245.
    7. Cao, Yang & He, Mingjing & Dutta, Shanta & Luo, Gang & Zhang, Shicheng & Tsang, Daniel C.W., 2021. "Hydrothermal carbonization and liquefaction for sustainable production of hydrochar and aromatics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    8. Yuting Zhou & Grace E. Klinger & Eric L. Hegg & Christopher M. Saffron & James E. Jackson, 2022. "Skeletal Ni electrode-catalyzed C-O cleavage of diaryl ethers entails direct elimination via benzyne intermediates," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    9. Md Sumon Reza & Zhanar Baktybaevna Iskakova & Shammya Afroze & Kairat Kuterbekov & Asset Kabyshev & Kenzhebatyr Zh. Bekmyrza & Marzhan M. Kubenova & Muhammad Saifullah Abu Bakar & Abul K. Azad & Hrido, 2023. "Influence of Catalyst on the Yield and Quality of Bio-Oil for the Catalytic Pyrolysis of Biomass: A Comprehensive Review," Energies, MDPI, vol. 16(14), pages 1-39, July.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:nature:v:515:y:2014:i:7526:d:10.1038_nature13867. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.