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Visualization and suppression of interfacial recombination for high-efficiency large-area pin perovskite solar cells

Author

Listed:
  • Martin Stolterfoht

    (University of Potsdam)

  • Christian M. Wolff

    (University of Potsdam)

  • José A. Márquez

    (Helmholtz-Zentrum-Berlin)

  • Shanshan Zhang

    (University of Potsdam
    The University of Queensland)

  • Charles J. Hages

    (Helmholtz-Zentrum-Berlin)

  • Daniel Rothhardt

    (University of Potsdam)

  • Steve Albrecht

    (Young Investigator Group Perovskite Tandem Solar Cells, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH)

  • Paul L. Burn

    (The University of Queensland)

  • Paul Meredith

    (Swansea University)

  • Thomas Unold

    (Helmholtz-Zentrum-Berlin)

  • Dieter Neher

    (University of Potsdam)

Abstract

The performance of perovskite solar cells is predominantly limited by non-radiative recombination, either through trap-assisted recombination in the absorber layer or via minority carrier recombination at the perovskite/transport layer interfaces. Here, we use transient and absolute photoluminescence imaging to visualize all non-radiative recombination pathways in planar pin-type perovskite solar cells with undoped organic charge transport layers. We find significant quasi-Fermi-level splitting losses (135 meV) in the perovskite bulk, whereas interfacial recombination results in an additional free energy loss of 80 meV at each individual interface, which limits the open-circuit voltage (VOC) of the complete cell to ~1.12 V. Inserting ultrathin interlayers between the perovskite and transport layers leads to a substantial reduction of these interfacial losses at both the p and n contacts. Using this knowledge and approach, we demonstrate reproducible dopant-free 1 cm2 perovskite solar cells surpassing 20% efficiency (19.83% certified) with stabilized power output, a high VOC (1.17 V) and record fill factor (>81%).

Suggested Citation

  • Martin Stolterfoht & Christian M. Wolff & José A. Márquez & Shanshan Zhang & Charles J. Hages & Daniel Rothhardt & Steve Albrecht & Paul L. Burn & Paul Meredith & Thomas Unold & Dieter Neher, 2018. "Visualization and suppression of interfacial recombination for high-efficiency large-area pin perovskite solar cells," Nature Energy, Nature, vol. 3(10), pages 847-854, October.
  • Handle: RePEc:nat:natene:v:3:y:2018:i:10:d:10.1038_s41560-018-0219-8
    DOI: 10.1038/s41560-018-0219-8
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    Cited by:

    1. Stefania Cacovich & Guillaume Vidon & Matteo Degani & Marie Legrand & Laxman Gouda & Jean-Baptiste Puel & Yana Vaynzof & Jean-François Guillemoles & Daniel Ory & Giulia Grancini, 2022. "Imaging and quantifying non-radiative losses at 23% efficient inverted perovskite solar cells interfaces," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Giovanni Pica & Lorenzo Pancini & Christopher E. Petoukhoff & Badri Vishal & Francesco Toniolo & Changzeng Ding & Young-Kwang Jung & Mirko Prato & Nada Mrkyvkova & Peter Siffalovic & Stefaan De Wolf &, 2024. "Photo-ferroelectric perovskite interfaces for boosting VOC in efficient perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Wei Qin & Wajid Ali & Jianfeng Wang & Yong Liu & Xiaolan Yan & Pengfei Zhang & Zhaochi Feng & Hao Tian & Yanfeng Yin & Wenming Tian & Can Li, 2023. "Suppressing non-radiative recombination in metal halide perovskite solar cells by synergistic effect of ferroelasticity," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    4. Chee, A. Kuan-Way, 2023. "On current technology for light absorber materials used in highly efficient industrial solar cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    5. Thibault Lemercier & Lara Perrin & Emilie Planès & Solenn Berson & Lionel Flandin, 2020. "A Comparison of the Structure and Properties of Opaque and Semi-Transparent NIP/PIN-Type Scalable Perovskite Solar Cells," Energies, MDPI, vol. 13(15), pages 1-18, July.
    6. Jarla Thiesbrummel & Sahil Shah & Emilio Gutierrez-Partida & Fengshuo Zu & Francisco Peña-Camargo & Stefan Zeiske & Jonas Diekmann & Fangyuan Ye & Karol P. Peters & Kai O. Brinkmann & Pietro Capriogli, 2024. "Ion-induced field screening as a dominant factor in perovskite solar cell operational stability," Nature Energy, Nature, vol. 9(6), pages 664-676, June.
    7. Fangyuan Ye & Shuo Zhang & Jonathan Warby & Jiawei Wu & Emilio Gutierrez-Partida & Felix Lang & Sahil Shah & Elifnaz Saglamkaya & Bowen Sun & Fengshuo Zu & Safa Shoaee & Haifeng Wang & Burkhard Stille, 2022. "Overcoming C60-induced interfacial recombination in inverted perovskite solar cells by electron-transporting carborane," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    8. Jing Zhang & Xian-Gang Hu & Kangyu Ji & Songru Zhao & Dongtao Liu & Bowei Li & Peng-Xiang Hou & Chang Liu & Lirong Liu & Samuel D. Stranks & Hui-Ming Cheng & S. Ravi P. Silva & Wei Zhang, 2024. "High-performance bifacial perovskite solar cells enabled by single-walled carbon nanotubes," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    9. Nour El Islam Boukortt & Claudia Triolo & Saveria Santangelo & Salvatore Patanè, 2023. "All-Perovskite Tandem Solar Cells: From Certified 25% and Beyond," Energies, MDPI, vol. 16(8), pages 1-24, April.

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