IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v5y2014i1d10.1038_ncomms6723.html
   My bibliography  Save this article

Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks

Author

Listed:
  • Dawei Feng

    (Texas A&M University)

  • Kecheng Wang

    (Texas A&M University)

  • Zhangwen Wei

    (Texas A&M University)

  • Ying-Pin Chen

    (Texas A&M University
    Texas A&M University)

  • Cory M. Simon

    (University of California at Berkeley)

  • Ravi K. Arvapally

    (University of North Texas)

  • Richard L. Martin

    (Lawrence Berkeley National Laboratory)

  • Mathieu Bosch

    (Texas A&M University)

  • Tian-Fu Liu

    (Texas A&M University)

  • Stephen Fordham

    (Texas A&M University)

  • Daqiang Yuan

    (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

  • Mohammad A. Omary

    (University of North Texas)

  • Maciej Haranczyk

    (Lawrence Berkeley National Laboratory)

  • Berend Smit

    (University of California at Berkeley
    Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL))

  • Hong-Cai Zhou

    (Texas A&M University
    Texas A&M University)

Abstract

Metal–organic frameworks with high stability have been pursued for many years due to the sustainability requirement for practical applications. However, researchers have had great difficulty synthesizing chemically ultra-stable, highly porous metal–organic frameworks in the form of crystalline solids, especially as single crystals. Here we present a kinetically tuned dimensional augmentation synthetic route for the preparation of highly crystalline and extremely robust metal–organic frameworks with a preserved metal cluster core. Through this versatile synthetic route, we obtain large single crystals of 34 different iron-containing metal–organic frameworks. Among them, PCN-250(Fe2Co) exhibits high volumetric uptake of hydrogen and methane, and is also stable in water and aqueous solutions with a wide range of pH values.

Suggested Citation

  • Dawei Feng & Kecheng Wang & Zhangwen Wei & Ying-Pin Chen & Cory M. Simon & Ravi K. Arvapally & Richard L. Martin & Mathieu Bosch & Tian-Fu Liu & Stephen Fordham & Daqiang Yuan & Mohammad A. Omary & Ma, 2014. "Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks," Nature Communications, Nature, vol. 5(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms6723
    DOI: 10.1038/ncomms6723
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/ncomms6723
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/ncomms6723?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chen Dong & Jia-Jia Yang & Lin-Hua Xie & Ganglong Cui & Wei-Hai Fang & Jian-Rong Li, 2022. "Catalytic ozone decomposition and adsorptive VOCs removal in bimetallic metal-organic frameworks," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Sujing Wang & Hong Giang T. Ly & Mohammad Wahiduzzaman & Charlotte Simms & Iurii Dovgaliuk & Antoine Tissot & Guillaume Maurin & Tatjana N. Parac-Vogt & Christian Serre, 2022. "A zirconium metal-organic framework with SOC topological net for catalytic peptide bond hydrolysis," Nature Communications, Nature, vol. 13(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms6723. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.