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Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks

Author

Listed:
  • Dawei Feng

    (Texas A&M University)

  • Kecheng Wang

    (Texas A&M University)

  • Zhangwen Wei

    (Texas A&M University)

  • Ying-Pin Chen

    (Texas A&M University
    Texas A&M University)

  • Cory M. Simon

    (University of California at Berkeley)

  • Ravi K. Arvapally

    (University of North Texas)

  • Richard L. Martin

    (Lawrence Berkeley National Laboratory)

  • Mathieu Bosch

    (Texas A&M University)

  • Tian-Fu Liu

    (Texas A&M University)

  • Stephen Fordham

    (Texas A&M University)

  • Daqiang Yuan

    (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences)

  • Mohammad A. Omary

    (University of North Texas)

  • Maciej Haranczyk

    (Lawrence Berkeley National Laboratory)

  • Berend Smit

    (University of California at Berkeley
    Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL))

  • Hong-Cai Zhou

    (Texas A&M University
    Texas A&M University)

Abstract

Metal–organic frameworks with high stability have been pursued for many years due to the sustainability requirement for practical applications. However, researchers have had great difficulty synthesizing chemically ultra-stable, highly porous metal–organic frameworks in the form of crystalline solids, especially as single crystals. Here we present a kinetically tuned dimensional augmentation synthetic route for the preparation of highly crystalline and extremely robust metal–organic frameworks with a preserved metal cluster core. Through this versatile synthetic route, we obtain large single crystals of 34 different iron-containing metal–organic frameworks. Among them, PCN-250(Fe2Co) exhibits high volumetric uptake of hydrogen and methane, and is also stable in water and aqueous solutions with a wide range of pH values.

Suggested Citation

  • Dawei Feng & Kecheng Wang & Zhangwen Wei & Ying-Pin Chen & Cory M. Simon & Ravi K. Arvapally & Richard L. Martin & Mathieu Bosch & Tian-Fu Liu & Stephen Fordham & Daqiang Yuan & Mohammad A. Omary & Ma, 2014. "Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal–organic frameworks," Nature Communications, Nature, vol. 5(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms6723
    DOI: 10.1038/ncomms6723
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    Cited by:

    1. Chen Dong & Jia-Jia Yang & Lin-Hua Xie & Ganglong Cui & Wei-Hai Fang & Jian-Rong Li, 2022. "Catalytic ozone decomposition and adsorptive VOCs removal in bimetallic metal-organic frameworks," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Sujing Wang & Hong Giang T. Ly & Mohammad Wahiduzzaman & Charlotte Simms & Iurii Dovgaliuk & Antoine Tissot & Guillaume Maurin & Tatjana N. Parac-Vogt & Christian Serre, 2022. "A zirconium metal-organic framework with SOC topological net for catalytic peptide bond hydrolysis," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Ya Wang & Jian-Xin Wei & Hong-Liang Tang & Lu-Hua Shao & Long-Zhang Dong & Xiao-Yu Chu & Yan-Xia Jiang & Gui-Ling Zhang & Feng-Ming Zhang & Ya-Qian Lan, 2024. "Artificial photosynthetic system for diluted CO2 reduction in gas-solid phase," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

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