IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-52219-3.html
   My bibliography  Save this article

Enhancing electrochemical carbon dioxide capture with supercapacitors

Author

Listed:
  • Zhen Xu

    (University of Cambridge)

  • Grace Mapstone

    (University of Cambridge)

  • Zeke Coady

    (University of Cambridge)

  • Mengnan Wang

    (Imperial College London)

  • Tristan L. Spreng

    (University of Cambridge)

  • Xinyu Liu

    (University of Cambridge)

  • Davide Molino

    (University of Cambridge
    Dipartimento di Scienza Applicata e Tecnologia (DISAT))

  • Alexander C. Forse

    (University of Cambridge)

Abstract

Supercapacitors are emerging as energy-efficient and robust devices for electrochemical CO2 capture. However, the impacts of electrode structure and charging protocols on CO2 capture performance remain unclear. Therefore, this study develops structure-property-performance correlations for supercapacitor electrodes at different charging conditions. We find that electrodes with large surface areas and low oxygen functionalization generally perform best, while a combination of micro- and mesopores is important to achieve fast CO2 capture rates. With these structural features and tunable charging protocols, YP80F activated carbon electrodes show the best CO2 capture performance with a capture rate of 350 mmolCO2 kg–1 h–1 and a low electrical energy consumption of 18 kJ molCO2–1 at 300 mA g–1 under CO2, together with a long lifetime over 12000 cycles at 150 mA g–1 under CO2 and excellent CO2 selectivity over N2 and O2. Operated in a “positive charging mode”, the system achieves excellent electrochemical reversibility with Coulombic efficiencies over 99.8% in the presence of approximately 15% O2, alongside stable cycling performance over 1000 cycles. This study paves the way for improved supercapacitor electrodes and charging protocols for electrochemical CO2 capture.

Suggested Citation

  • Zhen Xu & Grace Mapstone & Zeke Coady & Mengnan Wang & Tristan L. Spreng & Xinyu Liu & Davide Molino & Alexander C. Forse, 2024. "Enhancing electrochemical carbon dioxide capture with supercapacitors," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-52219-3
    DOI: 10.1038/s41467-024-52219-3
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-52219-3
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/s41467-024-52219-3?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Shijian Jin & Min Wu & Yan Jing & Roy G. Gordon & Michael J. Aziz, 2022. "Low energy carbon capture via electrochemically induced pH swing with electrochemical rebalancing," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Shuai Pang & Shijian Jin & Fengcun Yang & Maia Alberts & Lu Li & Dawei Xi & Roy G. Gordon & Pan Wang & Michael J. Aziz & Yunlong Ji, 2023. "A phenazine-based high-capacity and high-stability electrochemical CO2 capture cell with coupled electricity storage," Nature Energy, Nature, vol. 8(10), pages 1126-1136, October.
    3. Wang, Miao & Rahimi, Mohammad & Kumar, Amit & Hariharan, Subrahmaniam & Choi, Wonyoung & Hatton, T. Alan, 2019. "Flue gas CO2 capture via electrochemically mediated amine regeneration: System design and performance," Applied Energy, Elsevier, vol. 255(C).
    4. Kevin Rennert & Frank Errickson & Brian C. Prest & Lisa Rennels & Richard G. Newell & William Pizer & Cora Kingdon & Jordan Wingenroth & Roger Cooke & Bryan Parthum & David Smith & Kevin Cromar & Dela, 2022. "Comprehensive evidence implies a higher social cost of CO2," Nature, Nature, vol. 610(7933), pages 687-692, October.
    5. Xing Li & Xunhua Zhao & Yuanyue Liu & T. Alan Hatton & Yayuan Liu, 2022. "Redox-tunable Lewis bases for electrochemical carbon dioxide capture," Nature Energy, Nature, vol. 7(11), pages 1065-1075, November.
    6. Hyowon Seo & T. Alan Hatton, 2023. "Electrochemical direct air capture of CO2 using neutral red as reversible redox-active material," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    7. Peng Zhu & Zhen-Yu Wu & Ahmad Elgazzar & Changxin Dong & Tae-Ung Wi & Feng-Yang Chen & Yang Xia & Yuge Feng & Mohsen Shakouri & Jung Yoon (Timothy) Kim & Zhiwei Fang & T. Alan Hatton & Haotian Wang, 2023. "Continuous carbon capture in an electrochemical solid-electrolyte reactor," Nature, Nature, vol. 618(7967), pages 959-966, June.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xing Li & Xunhua Zhao & Lingyu Zhang & Anmol Mathur & Yu Xu & Zhiwei Fang & Luo Gu & Yuanyue Liu & Yayuan Liu, 2024. "Redox-tunable isoindigos for electrochemically mediated carbon capture," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    2. Yaowei Huang & Da Xu & Shuai Deng & Meng Lin, 2024. "A hybrid electro-thermochemical device for methane production from the air," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Wu, Xiaomei & Mao, Yuanhao & Fan, Huifeng & Sultan, Sayd & Yu, Yunsong & Zhang, Zaoxiao, 2023. "Investigation on the performance of EDA-based blended solvents for electrochemically mediated CO2 capture," Applied Energy, Elsevier, vol. 349(C).
    4. Qian Zhou & Feng Gui & Benxuan Zhao & Jingyi Liu & Huiwen Cai & Kaida Xu & Sheng Zhao, 2024. "Examining the Social Costs of Carbon Emissions and the Ecosystem Service Value in Island Ecosystems: An Analysis of the Zhoushan Archipelago," Sustainability, MDPI, vol. 16(2), pages 1-19, January.
    5. Ambec, Stefan & Esposito, Federico & Pacelli, Antonia, 2024. "The economics of carbon leakage mitigation policies," Journal of Environmental Economics and Management, Elsevier, vol. 125(C).
    6. Tracey Osborne & Sylvia Cifuentes & Laura Dev & Seánna Howard & Elisa Marchi & Lauren Withey & Marcelo Santos Rocha da Silva, 2024. "Climate justice, forests, and Indigenous Peoples: toward an alternative to REDD + for the Amazon," Climatic Change, Springer, vol. 177(8), pages 1-28, August.
    7. Schleich, Joachim & Alsheimer, Sven, 2024. "The relationship between willingness to pay and carbon footprint knowledge: Are individuals willing to pay more to offset their carbon footprint if they learn about its size and distance to the 1.5 °C," Ecological Economics, Elsevier, vol. 219(C).
    8. Azizbek Kamolov & Zafar Turakulov & Patrik Furda & Miroslav Variny & Adham Norkobilov & Marcos Fallanza, 2024. "Techno-Economic Feasibility Analysis of Post-Combustion Carbon Capture in an NGCC Power Plant in Uzbekistan," Clean Technol., MDPI, vol. 6(4), pages 1-32, October.
    9. John Bistline & Geoffrey Blanford & Maxwell Brown & Dallas Burtraw & Maya Domeshek & Jamil Farbes & Allen Fawcett & Anne Hamilton & Jesse Jenkins & Ryan Jones & Ben King & Hannah Kolus & John Larsen &, 2023. "Emissions and Energy Impacts of the Inflation Reduction Act," Papers 2307.01443, arXiv.org.
    10. Mohammadpour, Hossein & Cord-Ruwisch, Ralf & Pivrikas, Almantas & Ho, Goen, 2022. "Simple energy-efficient electrochemically-driven CO2 scrubbing for biogas upgrading," Renewable Energy, Elsevier, vol. 195(C), pages 274-282.
    11. Tol, Richard S.J., 2024. "A meta-analysis of the total economic impact of climate change," Energy Policy, Elsevier, vol. 185(C).
    12. Lin, Zi & Liu, Xiaolei & Lao, Liyun & Liu, Hengxu, 2020. "Prediction of two-phase flow patterns in upward inclined pipes via deep learning," Energy, Elsevier, vol. 210(C).
    13. Majid Hashemi & Glenn P. Jenkins & Frank Milne, 2023. "Renewable Energy Support Through Feed-in Tariffs: A Retrospective Stakeholder Analysis," Development Discussion Papers 2023-08, JDI Executive Programs.
    14. Davis G. Nelson & Elena A. Mikhailova & Hamdi A. Zurqani & Lili Lin & Zhenbang Hao & Christopher J. Post & Mark A. Schlautman & George B. Shepherd, 2024. "Soil-Based Emissions and Context-Specific Climate Change Planning to Support the United Nations (UN) Sustainable Development Goal (SDG) on Climate Action: A Case Study of Georgia (USA)," Land, MDPI, vol. 13(10), pages 1-24, October.
    15. Ilea, Flavia-Maria & Cormos, Ana-Maria & Cristea, Vasile-Mircea & Cormos, Calin-Cristian, 2023. "Enhancing the post-combustion carbon dioxide carbon capture plant performance by setpoints optimization of the decentralized multi-loop and cascade control system," Energy, Elsevier, vol. 275(C).
    16. Weiwei Xiong & Katsumasa Tanaka & Philippe Ciais & Daniel J. A. Johansson & Mariliis Lehtveer, 2022. "emIAM v1.0: an emulator for Integrated Assessment Models using marginal abatement cost curves," Papers 2212.12060, arXiv.org.
    17. Wu, Xiaomei & Fan, Huifeng & Mao, Yuanhao & Sharif, Maimoona & Yu, Yunsong & Zhang, Zaoxiao & Liu, Guangxin, 2022. "Systematic study of an energy efficient MEA-based electrochemical CO2 capture process: From mechanism to practical application," Applied Energy, Elsevier, vol. 327(C).
    18. Tarsia, Romano, 2024. "Heterogeneous effects of weather shocks on firm economic performance," LSE Research Online Documents on Economics 124251, London School of Economics and Political Science, LSE Library.
    19. Gössling, Stefan & Kees, Jessica & Litman, Todd & Humpe, Andreas, 2023. "The economic cost of a 130 kph speed limit in Germany," Ecological Economics, Elsevier, vol. 209(C).
    20. Wozny, Florian, 2024. "Tax Incidence in Heterogeneous Markets: The Pass-through of Air Passenger Taxes on Airfares," IZA Discussion Papers 16783, Institute of Labor Economics (IZA).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-52219-3. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.