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Electrochemical on-surface synthesis of a strong electron-donating graphene nanoribbon catalyst

Author

Listed:
  • Hiroshi Sakaguchi

    (Kyoto University)

  • Takahiro Kojima

    (Kyoto University)

  • Yingbo Cheng

    (Kyoto University)

  • Shunpei Nobusue

    (Kyoto University)

  • Kazuhiro Fukami

    (Kyoto University)

Abstract

On-surface synthesis of edge-functionalized graphene nanoribbons (GNRs) has attracted much attention. However, producing such GNRs on a large scale through on-surface synthesis under ultra-high vacuum on thermally activated metal surfaces has been challenging. This is mainly due to the decomposition of functional groups at temperatures of 300 to 500 °C and limited monolayer GNR growth based on the metal catalysis. To overcome these obstacles, we developed an on-surface electrochemical technique that utilizes redox reactions of asymmetric precursors at an electric double layer where a strong electric field is confined to the liquid-solid interface. We successfully demonstrate layer-by-layer growth of strong electron-donating GNRs on electrodes at temperatures

Suggested Citation

  • Hiroshi Sakaguchi & Takahiro Kojima & Yingbo Cheng & Shunpei Nobusue & Kazuhiro Fukami, 2024. "Electrochemical on-surface synthesis of a strong electron-donating graphene nanoribbon catalyst," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50086-6
    DOI: 10.1038/s41467-024-50086-6
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    1. Jinming Cai & Pascal Ruffieux & Rached Jaafar & Marco Bieri & Thomas Braun & Stephan Blankenburg & Matthias Muoth & Ari P. Seitsonen & Moussa Saleh & Xinliang Feng & Klaus Müllen & Roman Fasel, 2010. "Atomically precise bottom-up fabrication of graphene nanoribbons," Nature, Nature, vol. 466(7305), pages 470-473, July.
    2. Raymond E. Blackwell & Fangzhou Zhao & Erin Brooks & Junmian Zhu & Ilya Piskun & Shenkai Wang & Aidan Delgado & Yea-Lee Lee & Steven G. Louie & Felix R. Fischer, 2021. "Spin splitting of dopant edge state in magnetic zigzag graphene nanoribbons," Nature, Nature, vol. 600(7890), pages 647-652, December.
    3. Daniel J. Rizzo & Gregory Veber & Ting Cao & Christopher Bronner & Ting Chen & Fangzhou Zhao & Henry Rodriguez & Steven G. Louie & Michael F. Crommie & Felix R. Fischer, 2018. "Topological band engineering of graphene nanoribbons," Nature, Nature, vol. 560(7717), pages 204-208, August.
    4. Amina Kimouche & Mikko M. Ervasti & Robert Drost & Simo Halonen & Ari Harju & Pekka M. Joensuu & Jani Sainio & Peter Liljeroth, 2015. "Ultra-narrow metallic armchair graphene nanoribbons," Nature Communications, Nature, vol. 6(1), pages 1-6, December.
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