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Chiral multiferroicity in two-dimensional hybrid organic-inorganic perovskites

Author

Listed:
  • Haining Zheng

    (International Campus of Tianjin University
    National University of Singapore)

  • Arup Ghosh

    (National University of Singapore)

  • M. J. Swamynadhan

    (SRM Institute of Science and Technology)

  • Qihan Zhang

    (National University of Singapore)

  • Walter P. D. Wong

    (National University of Singapore)

  • Zhenyue Wu

    (National University of Singapore)

  • Rongrong Zhang

    (National University of Singapore)

  • Jingsheng Chen

    (National University of Singapore)

  • Fanica Cimpoesu

    (Institute of Physical Chemistry)

  • Saurabh Ghosh

    (SRM Institute of Science and Technology)

  • Branton J. Campbell

    (Brigham Young University)

  • Kai Wang

    (Beijing Jiaotong University)

  • Alessandro Stroppa

    (c/o Dip.to di Scienze Fisiche e Chimiche - University of L’Aquila)

  • Ramanathan Mahendiran

    (National University of Singapore)

  • Kian Ping Loh

    (International Campus of Tianjin University
    National University of Singapore)

Abstract

Chiral multiferroics offer remarkable capabilities for controlling quantum devices at multiple levels. However, these materials are rare due to the competing requirements of long-range orders and strict symmetry constraints. In this study, we present experimental evidence that the coexistence of ferroelectric, magnetic orders, and crystallographic chirality is achievable in hybrid organic-inorganic perovskites [(R/S)-β-methylphenethylamine]2CuCl4. By employing Landau symmetry mode analysis, we investigate the interplay between chirality and ferroic orders and propose a novel mechanism for chirality transfer in hybrid systems. This mechanism involves the coupling of non-chiral distortions, characterized by defining a pseudo-scalar quantity, $$\xi={{{{{\bf{p}}}}}}{{\cdot }}{{{{{\bf{r}}}}}}$$ ξ = p ⋅ r ( $${{{{{\bf{p}}}}}}$$ p represents the ferroelectric displacement vector and $${{{{{\bf{r}}}}}}$$ r denotes the ferro-rotational vector), which distinguishes between (R)- and (S)-chirality based on its sign. Moreover, the reversal of this descriptor’s sign can be associated with coordinated transitions in ferroelectric distortions, Jahn-Teller antiferro-distortions, and Dzyaloshinskii-Moriya vectors, indicating the mediating role of crystallographic chirality in magnetoelectric correlations.

Suggested Citation

  • Haining Zheng & Arup Ghosh & M. J. Swamynadhan & Qihan Zhang & Walter P. D. Wong & Zhenyue Wu & Rongrong Zhang & Jingsheng Chen & Fanica Cimpoesu & Saurabh Ghosh & Branton J. Campbell & Kai Wang & Ale, 2024. "Chiral multiferroicity in two-dimensional hybrid organic-inorganic perovskites," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49708-w
    DOI: 10.1038/s41467-024-49708-w
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    References listed on IDEAS

    as
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