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Halide Perovskite Inducing Anomalous Nonvolatile Polarization in Poly(vinylidene fluoride)-based Flexible Nanocomposites

Author

Listed:
  • Yao Wang

    (Beihang University)

  • Chen Huang

    (Beihang University)

  • Ziwei Cheng

    (Beihang University)

  • Zhenghao Liu

    (Southern University of Science and Technology
    Southern University of Science and Technology)

  • Yuan Zhang

    (Southern University of Science and Technology
    Southern University of Science and Technology)

  • Yantao Zheng

    (Beihang University)

  • Shulin Chen

    (Peking University)

  • Jie Wang

    (Zhejiang University)

  • Peng Gao

    (Peking University
    Collaborative Innovation Center of Quantum Matter)

  • Yang Shen

    (Tsinghua University)

  • Chungang Duan

    (East China Normal University)

  • Yuan Deng

    (Beihang University)

  • Ce-Wen Nan

    (Tsinghua University)

  • Jiangyu Li

    (Southern University of Science and Technology
    Southern University of Science and Technology)

Abstract

Ferroelectric materials have important applications in transduction, data storage, and nonlinear optics. Inorganic ferroelectrics such as lead zirconate titanate possess large polarization, though they are rigid and brittle. Ferroelectric polymers are light weight and flexible, yet their polarization is low, bottlenecked at 10 μC cm−2. Here we show poly(vinylidene fluoride) nanocomposite with only 0.94% of self-nucleated CH3NH3PbBr3 nanocrystals exhibits anomalously large polarization (~19.6 μC cm−2) while retaining superior stretchability and photoluminance, resulting in unprecedented electromechanical figures of merit among ferroelectrics. Comprehensive analysis suggests the enhancement is accomplished via delicate defect engineering, with field-induced Frenkel pairs in halide perovskite stabilized by the poled ferroelectric polymer through interfacial coupling. The strategy is general, working in poly(vinylidene fluoride-co-hexafluoropropylene) as well, and the nanocomposite is stable. The study thus presents a solution for overcoming the electromechanical dilemma of ferroelectrics while enabling additional optic-activity, ideal for multifunctional flexible electronics applications.

Suggested Citation

  • Yao Wang & Chen Huang & Ziwei Cheng & Zhenghao Liu & Yuan Zhang & Yantao Zheng & Shulin Chen & Jie Wang & Peng Gao & Yang Shen & Chungang Duan & Yuan Deng & Ce-Wen Nan & Jiangyu Li, 2024. "Halide Perovskite Inducing Anomalous Nonvolatile Polarization in Poly(vinylidene fluoride)-based Flexible Nanocomposites," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48348-4
    DOI: 10.1038/s41467-024-48348-4
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    References listed on IDEAS

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