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General synthesis and atomic arrangement identification of ordered Bi–Pd intermetallics with tunable electrocatalytic CO2 reduction selectivity

Author

Listed:
  • Wenjin Guo

    (Wuhan Textile University
    Wuhan Institute of Technology)

  • Guangfang Li

    (Huazhong University of Science and Technology)

  • Chengbo Bai

    (Wuhan Textile University)

  • Qiong Liu

    (Wuhan Institute of Technology)

  • Fengxi Chen

    (Wuhan Textile University)

  • Rong Chen

    (Wuhan Textile University
    Zhengzhou University)

Abstract

Intermetallic compounds (IMCs) with fixed chemical composition and ordered crystallographic arrangement are highly desirable platforms for elucidating the precise correlation between structures and performances in catalysis. However, diffusing a metal atom into a lattice of another metal to form a controllably regular metal occupancy remains a huge challenge. Herein, we develop a general and tractable solvothermal method to synthesize the Bi-Pd IMCs family, including Bi2Pd, BiPd, Bi3Pd5, Bi2Pd5, Bi3Pd8 and BiPd3. By employing electrocatalytic CO2 reduction as a model reaction, we deeply elucidated the interplay between Bi-Pd IMCs and key intermediates. Specific surface atomic arrangements endow Bi-Pd IMCs different relative surface binding affinities and adsorption configuration for *OCHO, *COOH and *H intermediate, thus exhibiting substantially selective generation of formate (Bi2Pd), CO (BiPd3) and H2 (Bi2Pd5). This work provides a comprehensive understanding of the specific structure-performance correlation of IMCs, which serves as a valuable paradigm for precisely modulating catalyst material structures.

Suggested Citation

  • Wenjin Guo & Guangfang Li & Chengbo Bai & Qiong Liu & Fengxi Chen & Rong Chen, 2024. "General synthesis and atomic arrangement identification of ordered Bi–Pd intermetallics with tunable electrocatalytic CO2 reduction selectivity," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46072-7
    DOI: 10.1038/s41467-024-46072-7
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    2. Yizhen Chen & Hongliang Li & Wanghui Zhao & Wenbo Zhang & Jiawei Li & Wei Li & Xusheng Zheng & Wensheng Yan & Wenhua Zhang & Junfa Zhu & Rui Si & Jie Zeng, 2019. "Optimizing reaction paths for methanol synthesis from CO2 hydrogenation via metal-ligand cooperativity," Nature Communications, Nature, vol. 10(1), pages 1-8, December.
    3. Yuvraj Y. Birdja & Elena Pérez-Gallent & Marta C. Figueiredo & Adrien J. Göttle & Federico Calle-Vallejo & Marc T. M. Koper, 2019. "Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels," Nature Energy, Nature, vol. 4(9), pages 732-745, September.
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