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Ultra-selective uranium separation by in-situ formation of π-f conjugated 2D uranium-organic framework

Author

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  • Qing Yun Zhang

    (East China University of Technology)

  • Lin Juan Zhang

    (Chinese Academy of Sciences)

  • Jian Qiu Zhu

    (Chinese Academy of Sciences)

  • Le Le Gong

    (State Key Laboratory of NBC Protection for Civilian)

  • Zhe Cheng Huang

    (East China University of Technology)

  • Feng Gao

    (East China University of Technology)

  • Jian Qiang Wang

    (Chinese Academy of Sciences)

  • Xian Qing Xie

    (Jiangxi Normal University)

  • Feng Luo

    (East China University of Technology)

Abstract

With the rapid development of nuclear energy, problems with uranium supply chain and nuclear waste accumulation have motivated researchers to improve uranium separation methods. Here we show a paradigm for such goal based on the in-situ formation of π-f conjugated two-dimensional uranium-organic framework. After screening five π-conjugated organic ligands, we find that 1,3,5-triformylphloroglucinol would be the best one to construct uranium-organic framework, thus resulting in 100% uranium removal from both high and low concentration with the residual concentration far below the WHO drinking water standard (15 ppb), and 97% uranium capture from natural seawater (3.3 ppb) with a record uptake efficiency of 0.64 mg·g−1·d−1. We also find that 1,3,5-triformylphloroglucinol can overcome the ion-interference issue such as the presence of massive interference ions or a 21-ions mixed solution. Our finds confirm the superiority of our separation approach over established ones, and will provide a fundamental molecule design for separation upon metal-organic framework chemistry.

Suggested Citation

  • Qing Yun Zhang & Lin Juan Zhang & Jian Qiu Zhu & Le Le Gong & Zhe Cheng Huang & Feng Gao & Jian Qiang Wang & Xian Qing Xie & Feng Luo, 2024. "Ultra-selective uranium separation by in-situ formation of π-f conjugated 2D uranium-organic framework," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-023-44663-4
    DOI: 10.1038/s41467-023-44663-4
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