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Multistate structures in a hydrogen-bonded polycatenation non-covalent organic framework with diverse resistive switching behaviors

Author

Listed:
  • Shimin Chen

    (Fujian Normal University)

  • Yan Ju

    (Fujian Normal University)

  • Yisi Yang

    (Fujian Normal University)

  • Fahui Xiang

    (Fujian Normal University)

  • Zizhu Yao

    (Fujian Normal University)

  • Hao Zhang

    (Fujian Normal University)

  • Yunbin Li

    (Fujian Normal University)

  • Yongfan Zhang

    (Fuzhou University)

  • Shengchang Xiang

    (Fujian Normal University)

  • Banglin Chen

    (Fujian Normal University)

  • Zhangjing Zhang

    (Fujian Normal University)

Abstract

The inherent structural flexibility and reversibility of non-covalent organic frameworks have enabled them to exhibit switchable multistate structures under external stimuli, providing great potential in the field of resistive switching (RS), but not well explored yet. Herein, we report the 0D+1D hydrogen-bonded polycatenation non-covalent organic framework (HOF-FJU-52), exhibiting diverse and reversible RS behaviors with the high performance. Triggered by the external stimulus of electrical field E at room temperature, HOF-FJU-52 has excellent resistive random-access memory (RRAM) behaviors, comparable to the state-of-the-art materials. When cooling down below 200 K, it was transferred to write-once-read-many-times memory (WORM) behaviors. The two memory behaviors exhibit reversibility on a single crystal device through the temperature changes. The RS mechanism of this non-covalent organic framework has been deciphered at the atomic level by the detailed single-crystal X-ray diffraction analyses, demonstrating that the structural dual-flexibility both in the asymmetric hydrogen bonded dimers within the 0D loops and in the infinite π–π stacking column between the loops and chains contribute to reversible structure transformations between multi-states and thus to its dual RS behaviors.

Suggested Citation

  • Shimin Chen & Yan Ju & Yisi Yang & Fahui Xiang & Zizhu Yao & Hao Zhang & Yunbin Li & Yongfan Zhang & Shengchang Xiang & Banglin Chen & Zhangjing Zhang, 2024. "Multistate structures in a hydrogen-bonded polycatenation non-covalent organic framework with diverse resistive switching behaviors," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
  • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-023-44214-x
    DOI: 10.1038/s41467-023-44214-x
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    References listed on IDEAS

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    1. Yadong Shi & Shuodong Wang & Wei Tao & Jingjing Guo & Sheng Xie & Yanglan Ding & Guoyong Xu & Cheng Chen & Xiaoyu Sun & Zengming Zhang & Zikai He & Peifa Wei & Ben Zhong Tang, 2022. "Multiple yet switchable hydrogen-bonded organic frameworks with white-light emission," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Angeles Pulido & Linjiang Chen & Tomasz Kaczorowski & Daniel Holden & Marc A. Little & Samantha Y. Chong & Benjamin J. Slater & David P. McMahon & Baltasar Bonillo & Chloe J. Stackhouse & Andrew Steph, 2017. "Functional materials discovery using energy–structure–function maps," Nature, Nature, vol. 543(7647), pages 657-664, March.
    3. Guosheng Chen & Linjing Tong & Siming Huang & Shuyao Huang & Fang Zhu & Gangfeng Ouyang, 2022. "Hydrogen-bonded organic framework biomimetic entrapment allowing non-native biocatalytic activity in enzyme," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
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