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In situ X-ray spectroscopies beyond conventional X-ray absorption spectroscopy on deciphering dynamic configuration of electrocatalysts

Author

Listed:
  • Jiali Wang

    (National Taiwan University)

  • Chia-Shuo Hsu

    (National Taiwan University)

  • Tai-Sing Wu

    (National Synchrotron Radiation Research Center)

  • Ting-Shan Chan

    (National Synchrotron Radiation Research Center)

  • Nian-Tzu Suen

    (Yangzhou University)

  • Jyh-Fu Lee

    (National Synchrotron Radiation Research Center)

  • Hao Ming Chen

    (National Taiwan University
    National Synchrotron Radiation Research Center
    Taipei Medical University)

Abstract

Realizing viable electrocatalytic processes for energy conversion/storage strongly relies on an atomic-level understanding of dynamic configurations on catalyst-electrolyte interface. X-ray absorption spectroscopy (XAS) has become an indispensable tool to in situ investigate dynamic natures of electrocatalysts but still suffers from limited energy resolution, leading to significant electronic transitions poorly resolved. Herein, we highlight advanced X-ray spectroscopies beyond conventional XAS, with emphasis on their unprecedented capabilities of deciphering key configurations of electrocatalysts. The profound complementarities of X-ray spectroscopies from various aspects are established in a probing energy-dependent “in situ spectroscopy map” for comprehensively understanding the solid-liquid interface. This perspective establishes an indispensable in situ research model for future studies and offers exciting research prospects for scientists and spectroscopists.

Suggested Citation

  • Jiali Wang & Chia-Shuo Hsu & Tai-Sing Wu & Ting-Shan Chan & Nian-Tzu Suen & Jyh-Fu Lee & Hao Ming Chen, 2023. "In situ X-ray spectroscopies beyond conventional X-ray absorption spectroscopy on deciphering dynamic configuration of electrocatalysts," Nature Communications, Nature, vol. 14(1), pages 1-23, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42370-8
    DOI: 10.1038/s41467-023-42370-8
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    1. Ali Firouzi & Ruimin Qiao & Shahrokh Motallebi & Christian W. Valencia & Hannah S. Israel & Mai Fujimoto & L. Andrew Wray & Yi-De Chuang & Wanli Yang & Colin D. Wessells, 2018. "Monovalent manganese based anodes and co-solvent electrolyte for stable low-cost high-rate sodium-ion batteries," Nature Communications, Nature, vol. 9(1), pages 1-10, December.
    2. Lichen Bai & Chia-Shuo Hsu & Duncan T. L. Alexander & Hao Ming Chen & Xile Hu, 2021. "Double-atom catalysts as a molecular platform for heterogeneous oxygen evolution electrocatalysis," Nature Energy, Nature, vol. 6(11), pages 1054-1066, November.
    3. Chia-Shuo Hsu & Jiali Wang & You-Chiuan Chu & Jui-Hsien Chen & Chia-Ying Chien & Kuo-Hsin Lin & Li Duan Tsai & Hsiao-Chien Chen & Yen-Fa Liao & Nozomu Hiraoka & Yuan-Chung Cheng & Hao Ming Chen, 2023. "Activating dynamic atomic-configuration for single-site electrocatalyst in electrochemical CO2 reduction," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    4. Sheng-Chih Lin & Chun-Chih Chang & Shih-Yun Chiu & Hsiao-Tien Pai & Tzu-Yu Liao & Chia-Shuo Hsu & Wei-Hung Chiang & Ming-Kang Tsai & Hao Ming Chen, 2020. "Operando time-resolved X-ray absorption spectroscopy reveals the chemical nature enabling highly selective CO2 reduction," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
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