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Soluble organic matter Molecular atlas of Ryugu reveals cold hydrothermalism on C-type asteroid parent body

Author

Listed:
  • Philippe Schmitt-Kopplin

    (Technische Universität München, Analytische Lebensmittel Chemie
    Helmholtz Munich, Analytical BioGeoChemistry
    Max Planck Institute for Extraterrestrial Physics)

  • Norbert Hertkorn

    (Helmholtz Munich, Analytical BioGeoChemistry)

  • Mourad Harir

    (Helmholtz Munich, Analytical BioGeoChemistry)

  • Franco Moritz

    (Helmholtz Munich, Analytical BioGeoChemistry)

  • Marianna Lucio

    (Helmholtz Munich, Analytical BioGeoChemistry)

  • Lydie Bonal

    (Université Grenoble Alpes, CNRS, CNES, IPAG)

  • Eric Quirico

    (Université Grenoble Alpes, CNRS, CNES, IPAG)

  • Yoshinori Takano

    (Japan Agency for Marine-Earth Science and Technology (JAMSTEC))

  • Jason P. Dworkin

    (NASA Goddard Space Flight Center)

  • Hiroshi Naraoka

    (Kyushu University)

  • Shogo Tachibana

    (University of Tokyo
    Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Tomoki Nakamura

    (Tohoku University)

  • Takaaki Noguchi

    (Kyoto University)

  • Ryuji Okazaki

    (Kyushu University)

  • Hikaru Yabuta

    (Hiroshima University)

  • Hisayoshi Yurimoto

    (Hokkaido University)

  • Kanako Sakamoto

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Toru Yada

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Masahiro Nishimura

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Aiko Nakato

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Akiko Miyazaki

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Kasumi Yogata

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Masanao Abe

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Tomohiro Usui

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Makoto Yoshikawa

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Takanao Saiki

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Satoshi Tanaka

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Fuyuto Terui

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Satoru Nakazawa

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Tatsuaki Okada

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

  • Sei-ichiro Watanabe

    (Nagoya University)

  • Yuichi Tsuda

    (Japan Aerospace Exploration Agency (ISAS/JAXA))

Abstract

The sample from the near-Earth carbonaceous asteroid (162173) Ryugu is analyzed in the context of carbonaceous meteorites soluble organic matter. The analysis of soluble molecules of samples collected by the Hayabusa2 spacecraft shines light on an extremely high molecular diversity on the C-type asteroid. Sequential solvent extracts of increasing polarity of Ryugu samples are analyzed using mass spectrometry with complementary ionization methods and structural information confirmed by nuclear magnetic resonance spectroscopy. Here we show a continuum in the molecular size and polarity, and no organomagnesium molecules are detected, reflecting a low temperature and water-rich environment on the parent body approving earlier mineralogical and chemical data. High abundance of sulfidic and nitrogen rich compounds as well as high abundance of ammonium ions confirm the water processing. Polycyclic aromatic hydrocarbons are also detected in a structural continuum of carbon saturations and oxidations, implying multiple origins of the observed organic complexity, thus involving generic processes such as earlier carbonization and serpentinization with successive low temperature aqueous alteration.

Suggested Citation

  • Philippe Schmitt-Kopplin & Norbert Hertkorn & Mourad Harir & Franco Moritz & Marianna Lucio & Lydie Bonal & Eric Quirico & Yoshinori Takano & Jason P. Dworkin & Hiroshi Naraoka & Shogo Tachibana & Tom, 2023. "Soluble organic matter Molecular atlas of Ryugu reveals cold hydrothermalism on C-type asteroid parent body," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42075-y
    DOI: 10.1038/s41467-023-42075-y
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    References listed on IDEAS

    as
    1. Marie Catherine Sforna & Daniele Brunelli & Céline Pisapia & Valerio Pasini & Daniele Malferrari & Bénédicte Ménez, 2018. "Abiotic formation of condensed carbonaceous matter in the hydrating oceanic crust," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    2. Bair, Eric & Hastie, Trevor & Paul, Debashis & Tibshirani, Robert, 2006. "Prediction by Supervised Principal Components," Journal of the American Statistical Association, American Statistical Association, vol. 101, pages 119-137, March.
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    Cited by:

    1. Yoshinori Takano & Hiroshi Naraoka & Jason P. Dworkin & Toshiki Koga & Kazunori Sasaki & Hajime Sato & Yasuhiro Oba & Nanako O. Ogawa & Toshihiro Yoshimura & Kenji Hamase & Naohiko Ohkouchi & Eric T. , 2024. "Primordial aqueous alteration recorded in water-soluble organic molecules from the carbonaceous asteroid (162173) Ryugu," Nature Communications, Nature, vol. 15(1), pages 1-15, December.
    2. Toshihiro Yoshimura & Daisuke Araoka & Hiroshi Naraoka & Saburo Sakai & Nanako O. Ogawa & Hisayoshi Yurimoto & Mayu Morita & Morihiko Onose & Tetsuya Yokoyama & Martin Bizzarro & Satoru Tanaka & Naohi, 2024. "Breunnerite grain and magnesium isotope chemistry reveal cation partitioning during aqueous alteration of asteroid Ryugu," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

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