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Enhancement of superconducting properties in the La–Ce–H system at moderate pressures

Author

Listed:
  • Wuhao Chen

    (Jilin University)

  • Xiaoli Huang

    (Jilin University)

  • Dmitrii V. Semenok

    (Center for High Pressure Science and Technology Advanced Research (HPSTAR))

  • Su Chen

    (Jilin University)

  • Di Zhou

    (Center for High Pressure Science and Technology Advanced Research (HPSTAR))

  • Kexin Zhang

    (Jilin University)

  • Artem R. Oganov

    (Skolkovo Innovation Center)

  • Tian Cui

    (Jilin University
    Ningbo University)

Abstract

Ternary hydrides are regarded as an important platform for exploring high-temperature superconductivity at relatively low pressures. Here, we successfully synthesized the hcp-(La,Ce)H9-10 at 113 GPa with the initial La/Ce ratio close to 3:1. The high-temperature superconductivity was strikingly observed at 176 K and 100 GPa with the extrapolated upper critical field Hc2(0) reaching 235 T. We also studied the binary La-H system for comparison, which exhibited a Tc of 103 K at 78 GPa. The Tc and Hc2(0) of the La-Ce-H are respectively enhanced by over 80 K and 100 T with respect to the binary La-H and Ce-H components. The experimental results and theoretical calculations indicate that the formation of the solid solution contributes not only to enhanced stability but also to superior superconducting properties. These results show how better superconductors can be engineered in the new hydrides by large addition of alloy-forming elements.

Suggested Citation

  • Wuhao Chen & Xiaoli Huang & Dmitrii V. Semenok & Su Chen & Di Zhou & Kexin Zhang & Artem R. Oganov & Tian Cui, 2023. "Enhancement of superconducting properties in the La–Ce–H system at moderate pressures," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38254-6
    DOI: 10.1038/s41467-023-38254-6
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    1. Jingkai Bi & Yuki Nakamoto & Peiyu Zhang & Katsuya Shimizu & Bo Zou & Hanyu Liu & Mi Zhou & Guangtao Liu & Hongbo Wang & Yanming Ma, 2022. "Giant enhancement of superconducting critical temperature in substitutional alloy (La,Ce)H9," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    2. Panpan Kong & Vasily S. Minkov & Mikhail A. Kuzovnikov & Alexander P. Drozdov & Stanislav P. Besedin & Shirin Mozaffari & Luis Balicas & Fedor Fedorovich Balakirev & Vitali B. Prakapenka & Stella Char, 2021. "Superconductivity up to 243 K in the yttrium-hydrogen system under high pressure," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. Zhiwen Li & Xin He & Changling Zhang & Xiancheng Wang & Sijia Zhang & Yating Jia & Shaomin Feng & Ke Lu & Jianfa Zhao & Jun Zhang & Baosen Min & Youwen Long & Richeng Yu & Luhong Wang & Meiyan Ye & Zh, 2022. "Superconductivity above 200 K discovered in superhydrides of calcium," Nature Communications, Nature, vol. 13(1), pages 1-5, December.
    4. Dan Sun & Vasily S. Minkov & Shirin Mozaffari & Ying Sun & Yanming Ma & Stella Chariton & Vitali B. Prakapenka & Mikhail I. Eremets & Luis Balicas & Fedor F. Balakirev, 2021. "High-temperature superconductivity on the verge of a structural instability in lanthanum superhydride," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    5. A. P. Drozdov & M. I. Eremets & I. A. Troyan & V. Ksenofontov & S. I. Shylin, 2015. "Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system," Nature, Nature, vol. 525(7567), pages 73-76, September.
    6. A. P. Drozdov & P. P. Kong & V. S. Minkov & S. P. Besedin & M. A. Kuzovnikov & S. Mozaffari & L. Balicas & F. F. Balakirev & D. E. Graf & V. B. Prakapenka & E. Greenberg & D. A. Knyazev & M. Tkacz & M, 2019. "Superconductivity at 250 K in lanthanum hydride under high pressures," Nature, Nature, vol. 569(7757), pages 528-531, May.
    7. Ion Errea & Francesco Belli & Lorenzo Monacelli & Antonio Sanna & Takashi Koretsune & Terumasa Tadano & Raffaello Bianco & Matteo Calandra & Ryotaro Arita & Francesco Mauri & José A. Flores-Livas, 2020. "Quantum crystal structure in the 250-kelvin superconducting lanthanum hydride," Nature, Nature, vol. 578(7793), pages 66-69, February.
    8. Xin Li & Xiaoli Huang & Defang Duan & Chris J. Pickard & Di Zhou & Hui Xie & Quan Zhuang & Yanping Huang & Qiang Zhou & Bingbing Liu & Tian Cui, 2019. "Polyhydride CeH9 with an atomic-like hydrogen clathrate structure," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
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    1. Y. L. Wu & X. H. Yu & J. Z. L. Hasaien & Fang Hong & P. F. Shan & Z. Y. Tian & Y. N. Zhai & J. P. Hu & J. G. Cheng & Jimin Zhao, 2024. "Ultrafast dynamics evidence of strong coupling superconductivity in LaH10±δ," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

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