IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-38254-6.html
   My bibliography  Save this article

Enhancement of superconducting properties in the La–Ce–H system at moderate pressures

Author

Listed:
  • Wuhao Chen

    (Jilin University)

  • Xiaoli Huang

    (Jilin University)

  • Dmitrii V. Semenok

    (Center for High Pressure Science and Technology Advanced Research (HPSTAR))

  • Su Chen

    (Jilin University)

  • Di Zhou

    (Center for High Pressure Science and Technology Advanced Research (HPSTAR))

  • Kexin Zhang

    (Jilin University)

  • Artem R. Oganov

    (Skolkovo Innovation Center)

  • Tian Cui

    (Jilin University
    Ningbo University)

Abstract

Ternary hydrides are regarded as an important platform for exploring high-temperature superconductivity at relatively low pressures. Here, we successfully synthesized the hcp-(La,Ce)H9-10 at 113 GPa with the initial La/Ce ratio close to 3:1. The high-temperature superconductivity was strikingly observed at 176 K and 100 GPa with the extrapolated upper critical field Hc2(0) reaching 235 T. We also studied the binary La-H system for comparison, which exhibited a Tc of 103 K at 78 GPa. The Tc and Hc2(0) of the La-Ce-H are respectively enhanced by over 80 K and 100 T with respect to the binary La-H and Ce-H components. The experimental results and theoretical calculations indicate that the formation of the solid solution contributes not only to enhanced stability but also to superior superconducting properties. These results show how better superconductors can be engineered in the new hydrides by large addition of alloy-forming elements.

Suggested Citation

  • Wuhao Chen & Xiaoli Huang & Dmitrii V. Semenok & Su Chen & Di Zhou & Kexin Zhang & Artem R. Oganov & Tian Cui, 2023. "Enhancement of superconducting properties in the La–Ce–H system at moderate pressures," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38254-6
    DOI: 10.1038/s41467-023-38254-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-38254-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-38254-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Jingkai Bi & Yuki Nakamoto & Peiyu Zhang & Katsuya Shimizu & Bo Zou & Hanyu Liu & Mi Zhou & Guangtao Liu & Hongbo Wang & Yanming Ma, 2022. "Giant enhancement of superconducting critical temperature in substitutional alloy (La,Ce)H9," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    2. Panpan Kong & Vasily S. Minkov & Mikhail A. Kuzovnikov & Alexander P. Drozdov & Stanislav P. Besedin & Shirin Mozaffari & Luis Balicas & Fedor Fedorovich Balakirev & Vitali B. Prakapenka & Stella Char, 2021. "Superconductivity up to 243 K in the yttrium-hydrogen system under high pressure," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    3. Zhiwen Li & Xin He & Changling Zhang & Xiancheng Wang & Sijia Zhang & Yating Jia & Shaomin Feng & Ke Lu & Jianfa Zhao & Jun Zhang & Baosen Min & Youwen Long & Richeng Yu & Luhong Wang & Meiyan Ye & Zh, 2022. "Superconductivity above 200 K discovered in superhydrides of calcium," Nature Communications, Nature, vol. 13(1), pages 1-5, December.
    4. Dan Sun & Vasily S. Minkov & Shirin Mozaffari & Ying Sun & Yanming Ma & Stella Chariton & Vitali B. Prakapenka & Mikhail I. Eremets & Luis Balicas & Fedor F. Balakirev, 2021. "High-temperature superconductivity on the verge of a structural instability in lanthanum superhydride," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    5. A. P. Drozdov & M. I. Eremets & I. A. Troyan & V. Ksenofontov & S. I. Shylin, 2015. "Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system," Nature, Nature, vol. 525(7567), pages 73-76, September.
    6. A. P. Drozdov & P. P. Kong & V. S. Minkov & S. P. Besedin & M. A. Kuzovnikov & S. Mozaffari & L. Balicas & F. F. Balakirev & D. E. Graf & V. B. Prakapenka & E. Greenberg & D. A. Knyazev & M. Tkacz & M, 2019. "Superconductivity at 250 K in lanthanum hydride under high pressures," Nature, Nature, vol. 569(7757), pages 528-531, May.
    7. Ion Errea & Francesco Belli & Lorenzo Monacelli & Antonio Sanna & Takashi Koretsune & Terumasa Tadano & Raffaello Bianco & Matteo Calandra & Ryotaro Arita & Francesco Mauri & José A. Flores-Livas, 2020. "Quantum crystal structure in the 250-kelvin superconducting lanthanum hydride," Nature, Nature, vol. 578(7793), pages 66-69, February.
    8. Xin Li & Xiaoli Huang & Defang Duan & Chris J. Pickard & Di Zhou & Hui Xie & Quan Zhuang & Yanping Huang & Qiang Zhou & Bingbing Liu & Tian Cui, 2019. "Polyhydride CeH9 with an atomic-like hydrogen clathrate structure," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jingkai Bi & Yuki Nakamoto & Peiyu Zhang & Katsuya Shimizu & Bo Zou & Hanyu Liu & Mi Zhou & Guangtao Liu & Hongbo Wang & Yanming Ma, 2022. "Giant enhancement of superconducting critical temperature in substitutional alloy (La,Ce)H9," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    2. Dominique Laniel & Florian Trybel & Bjoern Winkler & Florian Knoop & Timofey Fedotenko & Saiana Khandarkhaeva & Alena Aslandukova & Thomas Meier & Stella Chariton & Konstantin Glazyrin & Victor Milman, 2022. "High-pressure synthesis of seven lanthanum hydrides with a significant variability of hydrogen content," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Liu-Cheng Chen & Tao Luo & Zi-Yu Cao & Philip Dalladay-Simpson & Ge Huang & Di Peng & Li-Li Zhang & Federico Aiace Gorelli & Guo-Hua Zhong & Hai-Qing Lin & Xiao-Jia Chen, 2024. "Synthesis and superconductivity in yttrium-cerium hydrides at high pressures," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    4. Dan Sun & Vasily S. Minkov & Shirin Mozaffari & Ying Sun & Yanming Ma & Stella Chariton & Vitali B. Prakapenka & Mikhail I. Eremets & Luis Balicas & Fedor F. Balakirev, 2021. "High-temperature superconductivity on the verge of a structural instability in lanthanum superhydride," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    5. V. S. Minkov & S. L. Bud’ko & F. F. Balakirev & V. B. Prakapenka & S. Chariton & R. J. Husband & H. P. Liermann & M. I. Eremets, 2022. "Magnetic field screening in hydrogen-rich high-temperature superconductors," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    6. Hui Wang & Pascal T. Salzbrenner & Ion Errea & Feng Peng & Ziheng Lu & Hanyu Liu & Li Zhu & Chris J. Pickard & Yansun Yao, 2023. "Quantum structural fluxion in superconducting lanthanum polyhydride," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    7. Xiangzhuo Xing & Chao Wang & Linchao Yu & Jie Xu & Chutong Zhang & Mengge Zhang & Song Huang & Xiaoran Zhang & Yunxian Liu & Bingchao Yang & Xin Chen & Yongsheng Zhang & Jiangang Guo & Zhixiang Shi & , 2023. "Observation of non-superconducting phase changes in nitrogen doped lutetium hydrides," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    8. Cesare Tresca & Pietro Maria Forcella & Andrea Angeletti & Luigi Ranalli & Cesare Franchini & Michele Reticcioli & Gianni Profeta, 2024. "Molecular hydrogen in the N-doped LuH3 system as a possible path to superconductivity," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    9. Zhiwen Li & Xin He & Changling Zhang & Xiancheng Wang & Sijia Zhang & Yating Jia & Shaomin Feng & Ke Lu & Jianfa Zhao & Jun Zhang & Baosen Min & Youwen Long & Richeng Yu & Luhong Wang & Meiyan Ye & Zh, 2022. "Superconductivity above 200 K discovered in superhydrides of calcium," Nature Communications, Nature, vol. 13(1), pages 1-5, December.
    10. Mengqi Wang & Yu Wang & Zhixian Liu & Ganyu Xu & Bo Yang & Pei Yu & Haoyu Sun & Xiangyu Ye & Jingwei Zhou & Alexander F. Goncharov & Ya Wang & Jiangfeng Du, 2024. "Imaging magnetic transition of magnetite to megabar pressures using quantum sensors in diamond anvil cell," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    11. Pedro P. Ferreira & Lewis J. Conway & Alessio Cucciari & Simone Cataldo & Federico Giannessi & Eva Kogler & Luiz T. F. Eleno & Chris J. Pickard & Christoph Heil & Lilia Boeri, 2023. "Search for ambient superconductivity in the Lu-N-H system," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    12. M. A. Rastkhadiv, 2023. "Criticality in electronic structure of two graphene layers containing praseodymium superhydride doped molecules," The European Physical Journal B: Condensed Matter and Complex Systems, Springer;EDP Sciences, vol. 96(6), pages 1-9, June.
    13. M. I. Eremets & V. S. Minkov & P. P. Kong & A. P. Drozdov & S. Chariton & V. B. Prakapenka, 2023. "Universal diamond edge Raman scale to 0.5 terapascal and implications for the metallization of hydrogen," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    14. Yufan Shen & Kousuke Ooe & Xueyou Yuan & Tomoaki Yamada & Shunsuke Kobayashi & Mitsutaka Haruta & Daisuke Kan & Yuichi Shimakawa, 2024. "Ferroelectric freestanding hafnia membranes with metastable rhombohedral structure down to 1-nm-thick," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    15. Anghel, Dragoş-Victor, 2021. "Multiple solutions for the equilibrium populations in BCS superconductors," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 572(C).
    16. Xiaozhou Zan & Xiangdong Guo & Aolin Deng & Zhiheng Huang & Le Liu & Fanfan Wu & Yalong Yuan & Jiaojiao Zhao & Yalin Peng & Lu Li & Yangkun Zhang & Xiuzhen Li & Jundong Zhu & Jingwei Dong & Dongxia Sh, 2024. "Electron/infrared-phonon coupling in ABC trilayer graphene," Nature Communications, Nature, vol. 15(1), pages 1-6, December.
    17. Roman Lucrezi & Pedro P. Ferreira & Markus Aichhorn & Christoph Heil, 2024. "Temperature and quantum anharmonic lattice effects on stability and superconductivity in lutetium trihydride," Nature Communications, Nature, vol. 15(1), pages 1-7, December.
    18. Cong Liu & Ion Errea & Chi Ding & Chris Pickard & Lewis J. Conway & Bartomeu Monserrat & Yue-Wen Fang & Qing Lu & Jian Sun & Jordi Boronat & Claudio Cazorla, 2023. "Excitonic insulator to superconductor phase transition in ultra-compressed helium," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    19. Marta Sośnicka & Volker Lüders, 2021. "Phase transitions in natural C-O-H-N-S fluid inclusions - implications for gas mixtures and the behavior of solid H2S at low temperatures," Nature Communications, Nature, vol. 12(1), pages 1-15, December.
    20. Cheng Hu & Jiajun Chen & Xianliang Zhou & Yufeng Xie & Xinyue Huang & Zhenghan Wu & Saiqun Ma & Zhichun Zhang & Kunqi Xu & Neng Wan & Yueheng Zhang & Qi Liang & Zhiwen Shi, 2024. "Collapse of carbon nanotubes due to local high-pressure from van der Waals encapsulation," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38254-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.