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Construction of conducting bimetallic organic metal chalcogenides via selective metal metathesis and oxidation transformation

Author

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  • Yigang Jin

    (CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Yuhui Fang

    (Peking University)

  • Ze Li

    (CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Xiang Hao

    (CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Feng He

    (CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Bo Guan

    (CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Dongwei Wang

    (CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology)

  • Sha Wu

    (CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Yang Li

    (CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Caiming Liu

    (CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Xiaojuan Dai

    (CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Ye Zou

    (CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Yimeng Sun

    (CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Wei Xu

    (CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

Abstract

Conducting organic metal chalcogenides (OMCs) have attracted considerable interest for their superior electrical properties and fascinating functions. However, the electronic structural and functional regulation of OMCs are typically limited to the combination of monometallic nodes and graphene-like ligands. Here, we report a family of bimetallic OMCs ([CuAgx(C6S6)]n, x = 4 or 2) synthesized via selective metal metathesis and oxidation transformation. Both OMCs have alternatively stacked one-dimensional (1D) copper-dithiolene chains and 2D Ag-S networks, which can synergistically serve as charge transport pathways, rendering these bimetallic materials highly conductive. The incorporation of heterometallic nodes turned nonmagnetic [Ag5(C6S6)]n into paramagnetic metallic [CuAg4(C6S6)]n, which exhibited a coherence-incoherence crossover in magnetic susceptibility measurements and an unusually large Sommerfeld coefficient, reminiscent of the characteristics of Kondo lattice. This work opens up an avenue for tailoring the electronic structures of OMCs and provides a platform for studying the dichotomy between electronic localization and itinerancy.

Suggested Citation

  • Yigang Jin & Yuhui Fang & Ze Li & Xiang Hao & Feng He & Bo Guan & Dongwei Wang & Sha Wu & Yang Li & Caiming Liu & Xiaojuan Dai & Ye Zou & Yimeng Sun & Wei Xu, 2022. "Construction of conducting bimetallic organic metal chalcogenides via selective metal metathesis and oxidation transformation," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-34118-7
    DOI: 10.1038/s41467-022-34118-7
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    References listed on IDEAS

    as
    1. Yi-feng Yang & Zachary Fisk & Han-Oh Lee & J. D. Thompson & David Pines, 2008. "Scaling the Kondo lattice," Nature, Nature, vol. 454(7204), pages 611-613, July.
    2. Hengli Duan & Peng Guo & Chao Wang & Hao Tan & Wei Hu & Wensheng Yan & Chao Ma & Liang Cai & Li Song & Wenhua Zhang & Zhihu Sun & Linjun Wang & Wenbo Zhao & Yuewei Yin & Xiaoguang Li & Shiqiang Wei, 2019. "Beating the exclusion rule against the coexistence of robust luminescence and ferromagnetism in chalcogenide monolayers," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    3. Xing Huang & Peng Sheng & Zeyi Tu & Fengjiao Zhang & Junhua Wang & Hua Geng & Ye Zou & Chong-an Di & Yuanping Yi & Yimeng Sun & Wei Xu & Daoben Zhu, 2015. "A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    4. Yanzhou Li & Xiaoming Jiang & Zhihua Fu & Qingqing Huang & Guan-E. Wang & Wei-Hua Deng & Chen Wang & Zhenzhu Li & Wanjian Yin & Banglin Chen & Gang Xu, 2020. "Coordination assembly of 2D ordered organic metal chalcogenides with widely tunable electronic band gaps," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
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