IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v6y2015i1d10.1038_ncomms8408.html
   My bibliography  Save this article

A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour

Author

Listed:
  • Xing Huang

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Peng Sheng

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Zeyi Tu

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Fengjiao Zhang

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Junhua Wang

    (The Daniel Chee Tsui Laboratory, Institute of Physics, Chinese Academy of Sciences)

  • Hua Geng

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Ye Zou

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Chong-an Di

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Yuanping Yi

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Yimeng Sun

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Wei Xu

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Daoben Zhu

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

Abstract

Currently, studies on organic two-dimensional (2D) materials with special optic-electronic properties are attracting great research interest. However, 2D organic systems possessing promising electrical transport properties are still rare. Here a highly crystalline thin film of a copper coordination polymer, Cu-BHT (BHT=benzenehexathiol), is prepared via a liquid–liquid interface reaction between BHT/dichloromethane and copper(II) nitrate/H2O. The morphology and structure characterization reveal that this film is piled up by nanosheets of 2D lattice of [Cu3(C6S6)]n, which is further verified by quantum simulation. Four-probe measurements show that the room temperature conductivity of this material can reach up to 1,580 S cm−1, which is the highest value ever reported for coordination polymers. Meanwhile, it displays ambipolar charge transport behaviour and extremely high electron and hole mobilities (99 cm2V−1s−1 for holes and 116 cm2V−1s−1 for electrons) under field-effect modulation.

Suggested Citation

  • Xing Huang & Peng Sheng & Zeyi Tu & Fengjiao Zhang & Junhua Wang & Hua Geng & Ye Zou & Chong-an Di & Yuanping Yi & Yimeng Sun & Wei Xu & Daoben Zhu, 2015. "A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    • Handle: RePEc:nat:natcom:v:6:y:2015:i:1:d:10.1038_ncomms8408
    DOI: 10.1038/ncomms8408
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/ncomms8408
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/ncomms8408?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yigang Jin & Yuhui Fang & Ze Li & Xiang Hao & Feng He & Bo Guan & Dongwei Wang & Sha Wu & Yang Li & Caiming Liu & Xiaojuan Dai & Ye Zou & Yimeng Sun & Wei Xu, 2022. "Construction of conducting bimetallic organic metal chalcogenides via selective metal metathesis and oxidation transformation," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Lingxin Luo & Lingxiang Hou & Xueping Cui & Pengxin Zhan & Ping He & Chuying Dai & Ruian Li & Jichen Dong & Ye Zou & Guoming Liu & Yanpeng Liu & Jian Zheng, 2024. "Self-condensation-assisted chemical vapour deposition growth of atomically two-dimensional MOF single-crystals," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    3. Sihua Feng & Hengli Duan & Hao Tan & Fengchun Hu & Chaocheng Liu & Yao Wang & Zhi Li & Liang Cai & Yuyang Cao & Chao Wang & Zeming Qi & Li Song & Xuguang Liu & Zhihu Sun & Wensheng Yan, 2023. "Intrinsic room-temperature ferromagnetism in a two-dimensional semiconducting metal-organic framework," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Shengcong Shang & Changsheng Du & Youxing Liu & Minghui Liu & Xinyu Wang & Wenqiang Gao & Ye Zou & Jichen Dong & Yunqi Liu & Jianyi Chen, 2022. "A one-dimensional conductive metal-organic framework with extended π-d conjugated nanoribbon layers," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    5. Abdelkareem, Mohammad Ali & Abbas, Qaisar & Sayed, Enas Taha & Shehata, N. & Parambath, J.B.M. & Alami, Abdul Hai & Olabi, A.G., 2024. "Recent advances on metal-organic frameworks (MOFs) and their applications in energy conversion devices: Comprehensive review," Energy, Elsevier, vol. 299(C).
    6. Zhichao Pan & Xing Huang & Yunlong Fan & Shaoze Wang & Yiyu Liu & Xuzhong Cong & Tingsong Zhang & Shichao Qi & Ying Xing & Yu-Qing Zheng & Jian Li & Xiaoming Zhang & Wei Xu & Lei Sun & Jian Wang & Jin, 2024. "Synthesis and structure of a non-van-der-Waals two-dimensional coordination polymer with superconductivity," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:6:y:2015:i:1:d:10.1038_ncomms8408. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.