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A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour

Author

Listed:
  • Xing Huang

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Peng Sheng

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Zeyi Tu

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Fengjiao Zhang

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Junhua Wang

    (The Daniel Chee Tsui Laboratory, Institute of Physics, Chinese Academy of Sciences)

  • Hua Geng

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Ye Zou

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Chong-an Di

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Yuanping Yi

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Yimeng Sun

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Wei Xu

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

  • Daoben Zhu

    (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences)

Abstract

Currently, studies on organic two-dimensional (2D) materials with special optic-electronic properties are attracting great research interest. However, 2D organic systems possessing promising electrical transport properties are still rare. Here a highly crystalline thin film of a copper coordination polymer, Cu-BHT (BHT=benzenehexathiol), is prepared via a liquid–liquid interface reaction between BHT/dichloromethane and copper(II) nitrate/H2O. The morphology and structure characterization reveal that this film is piled up by nanosheets of 2D lattice of [Cu3(C6S6)]n, which is further verified by quantum simulation. Four-probe measurements show that the room temperature conductivity of this material can reach up to 1,580 S cm−1, which is the highest value ever reported for coordination polymers. Meanwhile, it displays ambipolar charge transport behaviour and extremely high electron and hole mobilities (99 cm2V−1s−1 for holes and 116 cm2V−1s−1 for electrons) under field-effect modulation.

Suggested Citation

  • Xing Huang & Peng Sheng & Zeyi Tu & Fengjiao Zhang & Junhua Wang & Hua Geng & Ye Zou & Chong-an Di & Yuanping Yi & Yimeng Sun & Wei Xu & Daoben Zhu, 2015. "A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour," Nature Communications, Nature, vol. 6(1), pages 1-8, November.
    • Handle: RePEc:nat:natcom:v:6:y:2015:i:1:d:10.1038_ncomms8408
    DOI: 10.1038/ncomms8408
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    Cited by:

    1. Yigang Jin & Yuhui Fang & Ze Li & Xiang Hao & Feng He & Bo Guan & Dongwei Wang & Sha Wu & Yang Li & Caiming Liu & Xiaojuan Dai & Ye Zou & Yimeng Sun & Wei Xu, 2022. "Construction of conducting bimetallic organic metal chalcogenides via selective metal metathesis and oxidation transformation," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Lingxin Luo & Lingxiang Hou & Xueping Cui & Pengxin Zhan & Ping He & Chuying Dai & Ruian Li & Jichen Dong & Ye Zou & Guoming Liu & Yanpeng Liu & Jian Zheng, 2024. "Self-condensation-assisted chemical vapour deposition growth of atomically two-dimensional MOF single-crystals," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    3. Sihua Feng & Hengli Duan & Hao Tan & Fengchun Hu & Chaocheng Liu & Yao Wang & Zhi Li & Liang Cai & Yuyang Cao & Chao Wang & Zeming Qi & Li Song & Xuguang Liu & Zhihu Sun & Wensheng Yan, 2023. "Intrinsic room-temperature ferromagnetism in a two-dimensional semiconducting metal-organic framework," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Shengcong Shang & Changsheng Du & Youxing Liu & Minghui Liu & Xinyu Wang & Wenqiang Gao & Ye Zou & Jichen Dong & Yunqi Liu & Jianyi Chen, 2022. "A one-dimensional conductive metal-organic framework with extended π-d conjugated nanoribbon layers," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    5. Abdelkareem, Mohammad Ali & Abbas, Qaisar & Sayed, Enas Taha & Shehata, N. & Parambath, J.B.M. & Alami, Abdul Hai & Olabi, A.G., 2024. "Recent advances on metal-organic frameworks (MOFs) and their applications in energy conversion devices: Comprehensive review," Energy, Elsevier, vol. 299(C).

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