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Constructing chemical stable 4-carboxyl-quinoline linked covalent organic frameworks via Doebner reaction for nanofiltration

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  • Yongliang Yang

    (Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Ling Yu

    (Zhejiang University of Technology)

  • Tiancheng Chu

    (University of Chinese Academy of Sciences
    Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences
    Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences)

  • Hongyun Niu

    (Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences)

  • Jun Wang

    (University of Chinese Academy of Sciences
    Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences
    Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences)

  • Yaqi Cai

    (Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences
    University of Chinese Academy of Sciences
    Hangzhou Institute for Advanced Study, UCAS)

Abstract

Covalent linkages are the key component of covalent organic frameworks (COFs). The development of stable and functional linkages is essential to expand the COFs family and broaden their application prospects. In this work, we report the synthesis of crystalline and chemical stable 4-carboxyl-quinoline linked COFs (QL-COFs) via Doebner reactions in both one-pot (OP) and post-synthetic modification (PSM) methods. Both methods can be universally applied to most of the reported imine COFs family via bottom-up construction or linkage conversion. Owing to the contractive pore size, more hydrophilic structure and better chemical stability than the conventional imine COFs endowed by 4-carboxyl-quinoline linkage, QL-COFs are supposed to possess a wider application range. We further demonstrate the nanofiltration membrane (NFM) based on QL-COF exhibited a desirable separation capacity with high rejection for small dye molecules (> 90%), high water permeance (850 L m−2 h−1 MPa−1) and tolerance of extreme conditions (1 M HCl/NaOH), which were benefitted from the enhanced properties of QL-COFs. Additionally, efficient ion sieving properties were also achieved by QL-COF membrane. We anticipate that this work opens up a way for the construction of robust and functional COFs materials for practical applications.

Suggested Citation

  • Yongliang Yang & Ling Yu & Tiancheng Chu & Hongyun Niu & Jun Wang & Yaqi Cai, 2022. "Constructing chemical stable 4-carboxyl-quinoline linked covalent organic frameworks via Doebner reaction for nanofiltration," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-30319-2
    DOI: 10.1038/s41467-022-30319-2
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    References listed on IDEAS

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    1. Qianrong Fang & Zhongbin Zhuang & Shuang Gu & Robert B. Kaspar & Jie Zheng & Junhua Wang & Shilun Qiu & Yushan Yan, 2014. "Designed synthesis of large-pore crystalline polyimide covalent organic frameworks," Nature Communications, Nature, vol. 5(1), pages 1-8, December.
    2. Xinle Li & Changlin Zhang & Songliang Cai & Xiaohe Lei & Virginia Altoe & Fang Hong & Jeffrey J. Urban & Jim Ciston & Emory M. Chan & Yi Liu, 2018. "Facile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks," Nature Communications, Nature, vol. 9(1), pages 1-8, December.
    3. Frederik Haase & Erik Troschke & Gökcen Savasci & Tanmay Banerjee & Viola Duppel & Susanne Dörfler & Martin M. J. Grundei & Asbjörn M. Burow & Christian Ochsenfeld & Stefan Kaskel & Bettina V. Lotsch, 2018. "Topochemical conversion of an imine- into a thiazole-linked covalent organic framework enabling real structure analysis," Nature Communications, Nature, vol. 9(1), pages 1-10, December.
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    1. Jia-Rui Wang & Kepeng Song & Tian-Xiang Luan & Ke Cheng & Qiurong Wang & Yue Wang & William W. Yu & Pei-Zhou Li & Yanli Zhao, 2024. "Robust links in photoactive covalent organic frameworks enable effective photocatalytic reactions under harsh conditions," Nature Communications, Nature, vol. 15(1), pages 1-17, December.

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