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Designed synthesis of large-pore crystalline polyimide covalent organic frameworks

Author

Listed:
  • Qianrong Fang

    (Center for Catalytic Science and Technology, University of Delaware)

  • Zhongbin Zhuang

    (Center for Catalytic Science and Technology, University of Delaware)

  • Shuang Gu

    (Center for Catalytic Science and Technology, University of Delaware)

  • Robert B. Kaspar

    (Center for Catalytic Science and Technology, University of Delaware)

  • Jie Zheng

    (Center for Catalytic Science and Technology, University of Delaware)

  • Junhua Wang

    (Center for Catalytic Science and Technology, University of Delaware)

  • Shilun Qiu

    (State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University)

  • Yushan Yan

    (Center for Catalytic Science and Technology, University of Delaware)

Abstract

Covalent organic frameworks (COFs) are an emerging class of porous crystalline polymers with a wide variety of applications. They are currently synthesized through only a few chemical reactions, limiting the access and exploitation of new structures and properties. Here we report that the imidization reaction can be used to prepare a series of polyimide (PI) COFs with pore size as large as 42 × 53 Å2, which is among the largest reported to date, and surface area as high as 2,346 m2 g−1, which exceeds that of all amorphous porous PIs and is among the highest reported for two-dimensional COFs. These PI COFs are thermally stable up to 530 °C. We also assemble a large dye molecule into a COF that shows sensitive temperature-dependent luminescent properties.

Suggested Citation

  • Qianrong Fang & Zhongbin Zhuang & Shuang Gu & Robert B. Kaspar & Jie Zheng & Junhua Wang & Shilun Qiu & Yushan Yan, 2014. "Designed synthesis of large-pore crystalline polyimide covalent organic frameworks," Nature Communications, Nature, vol. 5(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms5503
    DOI: 10.1038/ncomms5503
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    Cited by:

    1. Xiaomeng Yin & Hao Zhang & Xuezhi Qiao & Xinyuan Zhou & Zhenjie Xue & Xiangyu Chen & Haochen Ye & Cancan Li & Zhe Tang & Kailin Zhang & Tie Wang, 2024. "Artificial olfactory memory system based on conductive metal-organic frameworks," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Zhi-Bei Zhou & Peng-Ju Tian & Jin Yao & Ya Lu & Qiao-Yan Qi & Xin Zhao, 2022. "Toward azo-linked covalent organic frameworks by developing linkage chemistry via linker exchange," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Yongliang Yang & Ling Yu & Tiancheng Chu & Hongyun Niu & Jun Wang & Yaqi Cai, 2022. "Constructing chemical stable 4-carboxyl-quinoline linked covalent organic frameworks via Doebner reaction for nanofiltration," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    4. Wenwen Chi & Yuming Dong & Bing Liu & Chengsi Pan & Jiawei Zhang & Hui Zhao & Yongfa Zhu & Zeyu Liu, 2024. "A photocatalytic redox cycle over a polyimide catalyst drives efficient solar-to-H2O2 conversion," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    5. Qiao, Yuanting & Bailey, Josh J. & Huang, Qi & Ke, Xuebin & Wu, Chunfei, 2022. "Potential photo-switching sorbents for CO2 capture – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).

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