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Control of zeolite framework flexibility for ultra-selective carbon dioxide separation

Author

Listed:
  • Peng Du

    (Nanjing Tech University)

  • Yuting Zhang

    (Nanjing Tech University)

  • Xuerui Wang

    (Nanjing Tech University)

  • Stefano Canossa

    (EMAT, University of Antwerp)

  • Zhou Hong

    (Nanjing Membrane Materials Industrial Technology Research Institute Co., Ltd.)

  • Gwilherm Nénert

    (Malvern Panalytical B. V.)

  • Wanqin Jin

    (Nanjing Tech University)

  • Xuehong Gu

    (Nanjing Tech University)

Abstract

Molecular sieving membranes with uniform pore size are highly desired for carbon dioxide separation. All-silica zeolite membranes feature well-defined micropores, but the size-exclusion effect is significantly compromised by the non-selective macro-pores generated during detemplation. Here we propose a template modulated crystal transition (TMCT) approach to tune the flexibility of Decadodecasil 3 R (DD3R) zeolite to prepare ultra-selective membranes for CO2/CH4 separation. An instantaneous overheating is applied to synchronize the template decomposition with the structure relaxation. The organic template molecules are transitionally converted to tight carbon species by the one-minute overheating at 700 °C, which are facilely burnt out by a following moderate thermal treatment. The resulting membranes exhibit CO2/CH4 selectivity of 157~1,172 and CO2 permeance of (890~1,540) × 10−10 mol m−2 s−1 Pa−1. The CO2 flux and CO2/CH4 mixture selectivity reach 3.6 Nm3 m−2 h−1 and 43 even at feed pressure up to 31 bar. Such strategy could pave the way of all-silica zeolite membranes to practical applications.

Suggested Citation

  • Peng Du & Yuting Zhang & Xuerui Wang & Stefano Canossa & Zhou Hong & Gwilherm Nénert & Wanqin Jin & Xuehong Gu, 2022. "Control of zeolite framework flexibility for ultra-selective carbon dioxide separation," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29126-6
    DOI: 10.1038/s41467-022-29126-6
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    1. Shen, Yafei, 2015. "Chars as carbonaceous adsorbents/catalysts for tar elimination during biomass pyrolysis or gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 281-295.
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