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Efficient iron single-atom catalysts for selective ammoxidation of alcohols to nitriles

Author

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  • Kangkang Sun

    (Nanjing University of Science & Technology, Xiaolingwei 200
    Leibniz-Institute für Katalyse)

  • Hongbin Shan

    (Nanjing University of Science & Technology, Xiaolingwei 200)

  • Helfried Neumann

    (Leibniz-Institute für Katalyse)

  • Guo-Ping Lu

    (Nanjing University of Science & Technology, Xiaolingwei 200)

  • Matthias Beller

    (Leibniz-Institute für Katalyse)

Abstract

Zeolitic imidazolate frameworks derived Fe1-N-C catalysts with isolated single iron atoms have been synthesized and applied for selective ammoxidation reactions. For the preparation of the different Fe-based materials, benzylamine as an additive proved to be essential to tune the morphology and size of ZIFs resulting in uniform and smaller particles, which allow stable atomically dispersed Fe–N4 active sites. The optimal catalyst Fe1-N-C achieves an efficient synthesis of various aryl, heterocyclic, allylic, and aliphatic nitriles from alcohols in water under very mild conditions. With its chemoselectivity, recyclability, high efficiency under mild conditions this new system complements the toolbox of catalysts for nitrile synthesis, which are important intermediates with many applications in life sciences and industry.

Suggested Citation

  • Kangkang Sun & Hongbin Shan & Helfried Neumann & Guo-Ping Lu & Matthias Beller, 2022. "Efficient iron single-atom catalysts for selective ammoxidation of alcohols to nitriles," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29074-1
    DOI: 10.1038/s41467-022-29074-1
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    References listed on IDEAS

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    1. Rajenahally V. Jagadeesh & Henrik Junge & Matthias Beller, 2014. "Green synthesis of nitriles using non-noble metal oxides-based nanocatalysts," Nature Communications, Nature, vol. 5(1), pages 1-8, September.
    2. Yuan Pan & Yinjuan Chen & Konglin Wu & Zheng Chen & Shoujie Liu & Xing Cao & Weng-Chon Cheong & Tao Meng & Jun Luo & Lirong Zheng & Chenguang Liu & Dingsheng Wang & Qing Peng & Jun Li & Chen Chen, 2019. "Regulating the coordination structure of single-atom Fe-NxCy catalytic sites for benzene oxidation," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    3. Hao Tian & Huajun Tian & Shijian Wang & Shuangming Chen & Fan Zhang & Li Song & Hao Liu & Jian Liu & Guoxiu Wang, 2020. "High-power lithium–selenium batteries enabled by atomic cobalt electrocatalyst in hollow carbon cathode," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
    4. Hao Tian & Huajun Tian & Shijian Wang & Shuangming Chen & Fan Zhang & Li Song & Hao Liu & Jian Liu & Guoxiu Wang, 2020. "Author Correction: High-power lithium–selenium batteries enabled by atomic cobalt electrocatalyst in hollow carbon cathode," Nature Communications, Nature, vol. 11(1), pages 1-1, December.
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