IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-29074-1.html
   My bibliography  Save this article

Efficient iron single-atom catalysts for selective ammoxidation of alcohols to nitriles

Author

Listed:
  • Kangkang Sun

    (Nanjing University of Science & Technology, Xiaolingwei 200
    Leibniz-Institute für Katalyse)

  • Hongbin Shan

    (Nanjing University of Science & Technology, Xiaolingwei 200)

  • Helfried Neumann

    (Leibniz-Institute für Katalyse)

  • Guo-Ping Lu

    (Nanjing University of Science & Technology, Xiaolingwei 200)

  • Matthias Beller

    (Leibniz-Institute für Katalyse)

Abstract

Zeolitic imidazolate frameworks derived Fe1-N-C catalysts with isolated single iron atoms have been synthesized and applied for selective ammoxidation reactions. For the preparation of the different Fe-based materials, benzylamine as an additive proved to be essential to tune the morphology and size of ZIFs resulting in uniform and smaller particles, which allow stable atomically dispersed Fe–N4 active sites. The optimal catalyst Fe1-N-C achieves an efficient synthesis of various aryl, heterocyclic, allylic, and aliphatic nitriles from alcohols in water under very mild conditions. With its chemoselectivity, recyclability, high efficiency under mild conditions this new system complements the toolbox of catalysts for nitrile synthesis, which are important intermediates with many applications in life sciences and industry.

Suggested Citation

  • Kangkang Sun & Hongbin Shan & Helfried Neumann & Guo-Ping Lu & Matthias Beller, 2022. "Efficient iron single-atom catalysts for selective ammoxidation of alcohols to nitriles," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29074-1
    DOI: 10.1038/s41467-022-29074-1
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-29074-1
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-29074-1?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Rajenahally V. Jagadeesh & Henrik Junge & Matthias Beller, 2014. "Green synthesis of nitriles using non-noble metal oxides-based nanocatalysts," Nature Communications, Nature, vol. 5(1), pages 1-8, September.
    2. Hao Tian & Huajun Tian & Shijian Wang & Shuangming Chen & Fan Zhang & Li Song & Hao Liu & Jian Liu & Guoxiu Wang, 2020. "High-power lithium–selenium batteries enabled by atomic cobalt electrocatalyst in hollow carbon cathode," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
    3. Yuan Pan & Yinjuan Chen & Konglin Wu & Zheng Chen & Shoujie Liu & Xing Cao & Weng-Chon Cheong & Tao Meng & Jun Luo & Lirong Zheng & Chenguang Liu & Dingsheng Wang & Qing Peng & Jun Li & Chen Chen, 2019. "Regulating the coordination structure of single-atom Fe-NxCy catalytic sites for benzene oxidation," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    4. Hao Tian & Huajun Tian & Shijian Wang & Shuangming Chen & Fan Zhang & Li Song & Hao Liu & Jian Liu & Guoxiu Wang, 2020. "Author Correction: High-power lithium–selenium batteries enabled by atomic cobalt electrocatalyst in hollow carbon cathode," Nature Communications, Nature, vol. 11(1), pages 1-1, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Qingmeng & Han, Ning & Chai, Jiali & Zhang, Wei & Du, Jiakai & Tian, Hao & Liu, Hao & Wang, Guoxiu & Tang, Bohejin, 2023. "Strategies to improve metal-organic frameworks and their derived oxides as lithium storage anode materials," Energy, Elsevier, vol. 282(C).
    2. Maria Mechili & Christos Vaitsis & Nikolaos Argirusis & Pavlos K. Pandis & Georgia Sourkouni & Antonis A. Zorpas & Christos Argirusis, 2022. "Research Progress in Metal-Organic Framework Based Nanomaterials Applied in Battery Cathodes," Energies, MDPI, vol. 15(15), pages 1-30, July.
    3. Deyou Yu & Licong Xu & Kaixing Fu & Xia Liu & Shanli Wang & Minghua Wu & Wangyang Lu & Chunyu Lv & Jinming Luo, 2024. "Electronic structure modulation of iron sites with fluorine coordination enables ultra-effective H2O2 activation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    4. Jiabin Wu & Xianyu Zhu & Qun Li & Qiang Fu & Bingxue Wang & Beibei Li & Shanshan Wang & Qingchao Chang & Huandong Xiang & Chengliang Ye & Qiqiang Li & Liang Huang & Yan Liang & Dingsheng Wang & Yulian, 2024. "Enhancing radiation-resistance and peroxidase-like activity of single-atom copper nanozyme via local coordination manipulation," Nature Communications, Nature, vol. 15(1), pages 1-14, December.
    5. Shuo Zhang & Jianghua Wu & Mengting Zheng & Xin Jin & Zihan Shen & Zhonghua Li & Yanjun Wang & Quan Wang & Xuebin Wang & Hui Wei & Jiangwei Zhang & Peng Wang & Shanqing Zhang & Liyan Yu & Lifeng Dong , 2023. "Fe/Cu diatomic catalysts for electrochemical nitrate reduction to ammonia," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    6. Siliu Lyu & Chenxi Guo & Jianing Wang & Zhongjian Li & Bin Yang & Lecheng Lei & Liping Wang & Jianping Xiao & Tao Zhang & Yang Hou, 2022. "Exceptional catalytic activity of oxygen evolution reaction via two-dimensional graphene multilayer confined metal-organic frameworks," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    7. Wei Tan & Shaohua Xie & Duy Le & Weijian Diao & Meiyu Wang & Ke-Bin Low & Dave Austin & Sampyo Hong & Fei Gao & Lin Dong & Lu Ma & Steven N. Ehrlich & Talat S. Rahman & Fudong Liu, 2022. "Fine-tuned local coordination environment of Pt single atoms on ceria controls catalytic reactivity," Nature Communications, Nature, vol. 13(1), pages 1-16, December.
    8. Sheng Qian & Feng Xu & Yu Fan & Ningyan Cheng & Huaiguo Xue & Ye Yuan & Romain Gautier & Tengfei Jiang & Jingqi Tian, 2024. "Tailoring coordination environments of single-atom electrocatalysts for hydrogen evolution by topological heteroatom transfer," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    9. Li, Junyi & Jiang, Jinxia & Zhou, Yiguang & Chen, Mo & Xiao, Shuhao & Niu, Xiaobin & Wu, Rui & Yu, Le & Blackwood, Daniel John & Chen, Jun Song, 2023. "Nickel single-atom catalysts on porous carbon nanosheets for high-performance lithium-selenium batteries," Energy, Elsevier, vol. 285(C).
    10. Chunlong Dai & Linyu Hu & Hao Chen & Xuting Jin & Yuyang Han & Ying Wang & Xiangyang Li & Xinqun Zhang & Li Song & Maowen Xu & Huhu Cheng & Yang Zhao & Zhipan Zhang & Feng Liu & Liangti Qu, 2022. "Enabling fast-charging selenium-based aqueous batteries via conversion reaction with copper ions," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    11. Han, Ning & Wang, Shuo & Rana, Ashvinder K. & Asif, Saira & Klemeš, Jiří Jaromír & Bokhari, Awais & Long, Jinlin & Thakur, Vijay Kumar & Zhao, Xiaolin, 2022. "Rational design of boron nitride with different dimensionalities for sustainable applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 170(C).
    12. Jijia Xie & Xiyi Li & Jian Guo & Lei Luo & Juan J. Delgado & Natalia Martsinovich & Junwang Tang, 2023. "Highly selective oxidation of benzene to phenol with air at room temperature promoted by water," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    13. Dong Cao & Haoxiang Xu & Hongliang Li & Chen Feng & Jie Zeng & Daojian Cheng, 2022. "Volcano-type relationship between oxidation states and catalytic activity of single-atom catalysts towards hydrogen evolution," Nature Communications, Nature, vol. 13(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29074-1. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.