IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-28489-0.html
   My bibliography  Save this article

A new approach exploiting thermally activated delayed fluorescence molecules to optimize solar thermal energy storage

Author

Listed:
  • Fan-Yi Meng

    (National Taiwan University, R.O.C)

  • I-Han Chen

    (National Taiwan University, R.O.C)

  • Jiun-Yi Shen

    (National Taiwan University, R.O.C)

  • Kai-Hsin Chang

    (National Taiwan University, R.O.C)

  • Tai-Che Chou

    (National Taiwan University, R.O.C)

  • Yi-An Chen

    (National Taiwan University, R.O.C)

  • Yi-Ting Chen

    (National Taiwan University, R.O.C)

  • Chi-Lin Chen

    (National Taiwan University, R.O.C)

  • Pi-Tai Chou

    (National Taiwan University, R.O.C)

Abstract

We propose a new concept exploiting thermally activated delayed fluorescence (TADF) molecules as photosensitizers, storage units and signal transducers to harness solar thermal energy. Molecular composites based on the TADF core phenoxazine–triphenyltriazine (PXZ-TRZ) anchored with norbornadiene (NBD) were synthesized, yielding compounds PZDN and PZTN with two and four NBD units, respectively. Upon visible-light excitation, energy transfer to the triplet state of NBD occurred, followed by NBD → quadricyclane (QC) conversion, which can be monitored by changes in steady-state or time-resolved spectra. The small S1-T1 energy gap was found to be advantageous in optimizing the solar excitation wavelength. Upon tuning the molecule’s triplet state energy lower than that of NBD (61 kcal/mol), as achieved by another composite PZQN, the efficiency of the NBD → QC conversion decreased drastically. Upon catalysis, the reverse QC → NBD reaction occurred at room temperature, converting the stored chemical energy back to heat with excellent reversibility.

Suggested Citation

  • Fan-Yi Meng & I-Han Chen & Jiun-Yi Shen & Kai-Hsin Chang & Tai-Che Chou & Yi-An Chen & Yi-Ting Chen & Chi-Lin Chen & Pi-Tai Chou, 2022. "A new approach exploiting thermally activated delayed fluorescence molecules to optimize solar thermal energy storage," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28489-0
    DOI: 10.1038/s41467-022-28489-0
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-28489-0
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-28489-0?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Tschopp, Daniel & Tian, Zhiyong & Berberich, Magdalena & Fan, Jianhua & Perers, Bengt & Furbo, Simon, 2020. "Large-scale solar thermal systems in leading countries: A review and comparative study of Denmark, China, Germany and Austria," Applied Energy, Elsevier, vol. 270(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Li, Chuan & Li, Qi & Ge, Ruihuan, 2023. "Comparison of performance enhancement in a shell and tube based latent heat thermal energy storage device containing different structured fins," Renewable Energy, Elsevier, vol. 206(C), pages 994-1006.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yuan, Meng & Vad Mathiesen, Brian & Schneider, Noémi & Xia, Jianjun & Zheng, Wen & Sorknæs, Peter & Lund, Henrik & Zhang, Lipeng, 2024. "Renewable energy and waste heat recovery in district heating systems in China: A systematic review," Energy, Elsevier, vol. 294(C).
    2. Ilze Polikarpova & Roberts Kakis & Ieva Pakere & Dagnija Blumberga, 2021. "Optimizing Large-Scale Solar Field Efficiency: Latvia Case Study," Energies, MDPI, vol. 14(14), pages 1-13, July.
    3. Golmohamadi, Hessam & Larsen, Kim Guldstrand & Jensen, Peter Gjøl & Hasrat, Imran Riaz, 2022. "Integration of flexibility potentials of district heating systems into electricity markets: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    4. Ma, Qijie & Wang, Peijun & Fan, Jianhua & Klar, Assaf, 2022. "Underground solar energy storage via energy piles: An experimental study," Applied Energy, Elsevier, vol. 306(PB).
    5. Munćan, Vladimir & Mujan, Igor & Macura, Dušan & Anđelković, Aleksandar S., 2024. "The state of district heating and cooling in Europe - A literature-based assessment," Energy, Elsevier, vol. 304(C).
    6. Sifnaios, Ioannis & Sneum, Daniel Møller & Jensen, Adam R. & Fan, Jianhua & Bramstoft, Rasmus, 2023. "The impact of large-scale thermal energy storage in the energy system," Applied Energy, Elsevier, vol. 349(C).
    7. Bergsteinsson, Hjörleifur G. & Møller, Jan Kloppenborg & Nystrup, Peter & Pálsson, Ólafur Pétur & Guericke, Daniela & Madsen, Henrik, 2021. "Heat load forecasting using adaptive temporal hierarchies," Applied Energy, Elsevier, vol. 292(C).
    8. Zhang, Tongtong & She, Xiaohui & You, Zhanping & Zhao, Yanqi & Fan, Hongjun & Ding, Yulong, 2022. "Cryogenic thermoelectric generation using cold energy from a decoupled liquid air energy storage system for decentralised energy networks," Applied Energy, Elsevier, vol. 305(C).
    9. Guo, Jiacheng & Liu, Zhijian & Li, Ying & Wu, Di & Liu, Xuan & Zhang, Shicong & Yang, Xinyan & Ge, Hua & Zhang, Peiwen, 2022. "Thermodynamic performance analyses and optimization design method of a novel distributed energy system coupled with hybrid-energy storage," Renewable Energy, Elsevier, vol. 182(C), pages 1182-1200.
    10. Artur Wyrwa & Maciej Raczyński & Maciej Kulik & Oluwalana Oluwapelumi & Laura Mateusiak & Haoran Zhang & Marek Kempka, 2022. "Greening of the District Heating Systems—Case Study of Local Systems," Energies, MDPI, vol. 15(9), pages 1-20, April.
    11. Lizárraga-Morazán, Juan Ramón & Picón-Núñez, Martín, 2023. "Optimal sizing and control strategy of low temperature solar thermal utility systems," Energy, Elsevier, vol. 263(PC).
    12. Ana Cristina Ferreira & Angela Silva & José Carlos Teixeira & Senhorinha Teixeira, 2020. "Multi-Objective Optimization of Solar Thermal Systems Applied to Portuguese Dwellings," Energies, MDPI, vol. 13(24), pages 1-23, December.
    13. Saloux, Etienne & Candanedo, José A., 2021. "Model-based predictive control to minimize primary energy use in a solar district heating system with seasonal thermal energy storage," Applied Energy, Elsevier, vol. 291(C).
    14. Shilei Lv & Jiawen Zhu & Ran Wang, 2023. "Experimental Research on a Solar Energy Phase Change Heat Storage Heating System Applied in the Rural Area," Sustainability, MDPI, vol. 15(3), pages 1-20, January.
    15. Li, Haoran & Hou, Juan & Hong, Tianzhen & Ding, Yuemin & Nord, Natasa, 2021. "Energy, economic, and environmental analysis of integration of thermal energy storage into district heating systems using waste heat from data centres," Energy, Elsevier, vol. 219(C).
    16. Liu, Yanfeng & Tang, Huanlong & Chen, Yaowen & Wang, Dengjia & Song, Cong, 2022. "Optimization of layout and diameter for distributed solar heating network with multi-source and multi-sink," Energy, Elsevier, vol. 258(C).
    17. Golmohamadi, Hessam, 2021. "Stochastic energy optimization of residential heat pumps in uncertain electricity markets," Applied Energy, Elsevier, vol. 303(C).
    18. Lei Fang & Yujie Wang, 2022. "Exploring Application of Ice Source Heat Pump Technology in Solar Heating System for Space Heating," Energies, MDPI, vol. 15(11), pages 1-11, May.
    19. Johansen, Katinka & Werner, Sven, 2022. "Something is sustainable in the state of Denmark: A review of the Danish district heating sector," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    20. Victoria Popsueva & Andrés Franklin Olivares Lopez & Anna Kosinska & Oleg Nikolaev & Boris V. Balakin, 2021. "Field Study on the Thermal Performance of Vacuum Tube Solar Collectors in the Climate Conditions of Western Norway," Energies, MDPI, vol. 14(10), pages 1-12, May.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-28489-0. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.