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Engineering unsymmetrically coordinated Cu-S1N3 single atom sites with enhanced oxygen reduction activity

Author

Listed:
  • Huishan Shang

    (School of Materials Science and Engineering, Beijing Institute of Technology)

  • Xiangyi Zhou

    (Tsinghua University)

  • Juncai Dong

    (Institute of High Energy Physics, Chinese Academy of Sciences)

  • Ang Li

    (Beijing University of Technology)

  • Xu Zhao

    (University of Science and Technology of China)

  • Qinghua Liu

    (University of Science and Technology of China)

  • Yue Lin

    (University of Science and Technology of China)

  • Jiajing Pei

    (Beijing University of Chemical Technology)

  • Zhi Li

    (Tsinghua University)

  • Zhuoli Jiang

    (School of Materials Science and Engineering, Beijing Institute of Technology)

  • Danni Zhou

    (School of Materials Science and Engineering, Beijing Institute of Technology)

  • Lirong Zheng

    (Institute of High Energy Physics, Chinese Academy of Sciences)

  • Yu Wang

    (Shanghai Institute of Applied Physics, Chinese Academy of Science)

  • Jing Zhou

    (Shanghai Institute of Applied Physics, Chinese Academy of Science)

  • Zhengkun Yang

    (University of Science and Technology of China)

  • Rui Cao

    (Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory)

  • Ritimukta Sarangi

    (Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory)

  • Tingting Sun

    (University of Science and Technology Beijing)

  • Xin Yang

    (Tsinghua University)

  • Xusheng Zheng

    (University of Science and Technology of China)

  • Wensheng Yan

    (University of Science and Technology of China)

  • Zhongbin Zhuang

    (Beijing University of Chemical Technology)

  • Jia Li

    (Tsinghua University)

  • Wenxing Chen

    (School of Materials Science and Engineering, Beijing Institute of Technology)

  • Dingsheng Wang

    (Tsinghua University)

  • Jiatao Zhang

    (School of Materials Science and Engineering, Beijing Institute of Technology)

  • Yadong Li

    (Tsinghua University)

Abstract

Atomic interface regulation is thought to be an efficient method to adjust the performance of single atom catalysts. Herein, a practical strategy was reported to rationally design single copper atoms coordinated with both sulfur and nitrogen atoms in metal-organic framework derived hierarchically porous carbon (S-Cu-ISA/SNC). The atomic interface configuration of the copper site in S-Cu-ISA/SNC is detected to be an unsymmetrically arranged Cu-S1N3 moiety. The catalyst exhibits excellent oxygen reduction reaction activity with a half-wave potential of 0.918 V vs. RHE. Additionally, through in situ X-ray absorption fine structure tests, we discover that the low-valent Cuprous-S1N3 moiety acts as an active center during the oxygen reduction process. Our discovery provides a universal scheme for the controllable synthesis and performance regulation of single metal atom catalysts toward energy applications.

Suggested Citation

  • Huishan Shang & Xiangyi Zhou & Juncai Dong & Ang Li & Xu Zhao & Qinghua Liu & Yue Lin & Jiajing Pei & Zhi Li & Zhuoli Jiang & Danni Zhou & Lirong Zheng & Yu Wang & Jing Zhou & Zhengkun Yang & Rui Cao , 2020. "Engineering unsymmetrically coordinated Cu-S1N3 single atom sites with enhanced oxygen reduction activity," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-16848-8
    DOI: 10.1038/s41467-020-16848-8
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    12. Zhimeng Tang & Lei Xu & Cheng Xie & Lirong Guo & Libo Zhang & Shenghui Guo & Jinhui Peng, 2023. "Synthesis of CuCo2S4@Expanded Graphite with crystal/amorphous heterointerface and defects for electromagnetic wave absorption," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    13. Juncai Dong & Yangyang Liu & Jiajing Pei & Haijing Li & Shufang Ji & Lei Shi & Yaning Zhang & Can Li & Cheng Tang & Jiangwen Liao & Shiqing Xu & Huabin Zhang & Qi Li & Shenlong Zhao, 2023. "Continuous electroproduction of formate via CO2 reduction on local symmetry-broken single-atom catalysts," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    14. Yangyang Liu & Can Li & Chunhui Tan & Zengxia Pei & Tao Yang & Shuzhen Zhang & Qianwei Huang & Yihan Wang & Zheng Zhou & Xiaozhou Liao & Juncai Dong & Hao Tan & Wensheng Yan & Huajie Yin & Zhao-Qing L, 2023. "Electrosynthesis of chlorine from seawater-like solution through single-atom catalysts," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    15. Meihuan Liu & Jing Zhang & Hui Su & Yaling Jiang & Wanlin Zhou & Chenyu Yang & Shuowen Bo & Jun Pan & Qinghua Liu, 2024. "In situ modulating coordination fields of single-atom cobalt catalyst for enhanced oxygen reduction reaction," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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