IDEAS home Printed from https://ideas.repec.org/a/gam/jsusta/v15y2023i17p13044-d1228470.html
   My bibliography  Save this article

Selective Mechanisms of WO 3 Catalyzing CO 2 Desorption and Inhibiting NH 3 Escape

Author

Listed:
  • Fengming Chu

    (College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China)

  • Xi Liu

    (College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China)

  • Qianhong Gao

    (College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China)

  • Longchun Zhong

    (Key Laboratory of Cleaner Production and Integrated Resource Utilization of China National Light Industry, Beijing Technology and Business University, Beijing 100048, China)

  • Guozhen Xiao

    (College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
    Shandong GRINM RS Semiconductor Materials Co., Ltd., Dezhou 253084, China)

  • Qianlin Wang

    (College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China)

Abstract

The high regeneration energy consumption and ammonia escape in the ammonia regeneration process are regarded as the main barriers for the commercial application of CO 2 capture technology based on ammonia solutions. Metal oxides can enhance the CO 2 desorption process and inhibit the ammonia escape at the same time, which can reduce the energy consumption of CO 2 capture systems. Both ammonium carbamate (NH 2 COONH 4 ) and ammonium bicarbonate (NH 4 HCO 3 ) are examined as the rich ammonia solution. The results show that when the concentration of tungsten trioxide (WO 3 ) was 0.1 mol/L, the CO 2 desorption efficiency could be promoted by 18.8% and the ammonia escape efficiency could be reduced about 14%. The mechanism by which WO 3 increased the CO 2 desorption process was clarified by XRD analysis as the production of ammonium tungstate. In addition, the other nine metal oxides exert no catalytic influence on the regeneration process.

Suggested Citation

  • Fengming Chu & Xi Liu & Qianhong Gao & Longchun Zhong & Guozhen Xiao & Qianlin Wang, 2023. "Selective Mechanisms of WO 3 Catalyzing CO 2 Desorption and Inhibiting NH 3 Escape," Sustainability, MDPI, vol. 15(17), pages 1-9, August.
  • Handle: RePEc:gam:jsusta:v:15:y:2023:i:17:p:13044-:d:1228470
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2071-1050/15/17/13044/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/2071-1050/15/17/13044/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Cheng, Chin-hung & Li, Kangkang & Yu, Hai & Jiang, Kaiqi & Chen, Jian & Feron, Paul, 2018. "Amine-based post-combustion CO2 capture mediated by metal ions: Advancement of CO2 desorption using copper ions," Applied Energy, Elsevier, vol. 211(C), pages 1030-1038.
    2. Ma, Shuangchen & Chen, Gongda & Zhu, Sijie & Han, Tingting & Yu, Weijing, 2016. "Mass transfer of ammonia escape and CO2 absorption in CO2 capture using ammonia solution in bubbling reactor," Applied Energy, Elsevier, vol. 162(C), pages 354-362.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chu, Fengming & Yang, Lijun & Du, Xiaoze & Yang, Yongping, 2017. "Mass transfer and energy consumption for CO2 absorption by ammonia solution in bubble column," Applied Energy, Elsevier, vol. 190(C), pages 1068-1080.
    2. Wu, Xiaomei & Fan, Huifeng & Mao, Yuanhao & Sharif, Maimoona & Yu, Yunsong & Zhang, Zaoxiao & Liu, Guangxin, 2022. "Systematic study of an energy efficient MEA-based electrochemical CO2 capture process: From mechanism to practical application," Applied Energy, Elsevier, vol. 327(C).
    3. Zevenhoven, Ron & Legendre, Daniel & Said, Arshe & Järvinen, Mika, 2019. "Carbon dioxide dissolution and ammonia losses in bubble columns for precipitated calcium carbonate (PCC) production," Energy, Elsevier, vol. 175(C), pages 1121-1129.
    4. Chi, Changyun & Li, Yingjie & Zhang, Wan & Wang, Zeyan, 2019. "Synthesis of a hollow microtubular Ca/Al sorbent with high CO2 uptake by hard templating," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    5. Ji, Long & Yu, Hai & Li, Kangkang & Yu, Bing & Grigore, Mihaela & Yang, Qi & Wang, Xiaolong & Chen, Zuliang & Zeng, Ming & Zhao, Shuaifei, 2018. "Integrated absorption-mineralisation for low-energy CO2 capture and sequestration," Applied Energy, Elsevier, vol. 225(C), pages 356-366.
    6. Zhou, Xiaobin & Jing, Guohua & Lv, Bihong & Liu, Fan & Zhou, Zuoming, 2019. "Low-viscosity and efficient regeneration of carbon dioxide capture using a biphasic solvent regulated by 2-amino-2-methyl-1-propanol," Applied Energy, Elsevier, vol. 235(C), pages 379-390.
    7. Wang, Fu & Zhao, Jun & Miao, He & Zhao, Jiapei & Zhang, Houcheng & Yuan, Jinliang & Yan, Jinyue, 2018. "Current status and challenges of the ammonia escape inhibition technologies in ammonia-based CO2 capture process," Applied Energy, Elsevier, vol. 230(C), pages 734-749.
    8. Yifang Liu & Fengming Chu & Lijun Yang & Xiaoze Du & Yongping Yang, 2018. "CO2 absorption characteristics in a random packed column with various geometric structures and working conditions," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(1), pages 120-132, February.
    9. Song, Chunfeng & Xie, Meilian & Qiu, Yiting & Liu, Qingling & Sun, Luchang & Wang, Kailiang & Kansha, Yasuki, 2019. "Integration of CO2 absorption with biological transformation via using rich ammonia solution as a nutrient source for microalgae cultivation," Energy, Elsevier, vol. 179(C), pages 618-627.
    10. Wu, Xiao M. & Qin, Zhen & Yu, Yun S. & Zhang, Zao X., 2018. "Experimental and numerical study on CO2 absorption mass transfer enhancement for a diameter-varying spray tower," Applied Energy, Elsevier, vol. 225(C), pages 367-379.
    11. Qin, Qiaoyun & Liu, Hongyan & Zhang, Riguang & Ling, Lixia & Fan, Maohong & Wang, Baojun, 2018. "Application of density functional theory in studying CO2 capture with TiO2-supported K2CO3 being an example," Applied Energy, Elsevier, vol. 231(C), pages 167-178.
    12. Rashidi, Hamed & Rasouli, Parvaneh & Azimi, Hossein, 2022. "A green vapor suppressing agent for aqueous ammonia carbon dioxide capture solvent: Microcontactor mass transfer study," Energy, Elsevier, vol. 244(PA).
    13. Madeddu, Claudio & Errico, Massimiliano & Baratti, Roberto, 2018. "Process analysis for the carbon dioxide chemical absorption–regeneration system," Applied Energy, Elsevier, vol. 215(C), pages 532-542.
    14. Roussanaly, S. & Aasen, A. & Anantharaman, R. & Danielsen, B. & Jakobsen, J. & Heme-De-Lacotte, L. & Neji, G. & Sødal, A. & Wahl, P.E. & Vrana, T.K. & Dreux, R., 2019. "Offshore power generation with carbon capture and storage to decarbonise mainland electricity and offshore oil and gas installations: A techno-economic analysis," Applied Energy, Elsevier, vol. 233, pages 478-494.
    15. N.Borhani, Tohid & Wang, Meihong, 2019. "Role of solvents in CO2 capture processes: The review of selection and design methods," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    16. Zhang, Xiaowen & Huang, Yufei & Gao, Hongxia & Luo, Xiao & Liang, Zhiwu & Tontiwachwuthikul, Paitoon, 2019. "Zeolite catalyst-aided tri-solvent blend amine regeneration: An alternative pathway to reduce the energy consumption in amine-based CO2 capture process," Applied Energy, Elsevier, vol. 240(C), pages 827-841.
    17. Li, Kangkang & Jiang, Kaiqi & Jones, Timothy W. & Feron, Paul H.M. & Bennett, Robert D. & Hollenkamp, Anthony F., 2019. "CO2 regenerative battery for energy harvesting from ammonia-based post-combustion CO2 capture," Applied Energy, Elsevier, vol. 247(C), pages 417-425.
    18. Chu, Fengming & Liu, Yifang & Yang, Lijun & Du, Xiaoze & Yang, Yongping, 2017. "Ammonia escape mass transfer and heat transfer characteristics of CO2 absorption in packed absorbing column," Applied Energy, Elsevier, vol. 205(C), pages 1596-1604.
    19. Zhang, Xiaowen & Liu, Helei & Liang, Zhiwu & Idem, Raphael & Tontiwachwuthikul, Paitoon & Jaber Al-Marri, Mohammed & Benamor, Abdelbaki, 2018. "Reducing energy consumption of CO2 desorption in CO2-loaded aqueous amine solution using Al2O3/HZSM-5 bifunctional catalysts," Applied Energy, Elsevier, vol. 229(C), pages 562-576.
    20. Wu, Xiaomei & Fan, Huifeng & Sharif, Maimoona & Yu, Yunsong & Wei, Keming & Zhang, Zaoxiao & Liu, Guangxin, 2021. "Electrochemically-mediated amine regeneration of CO2 capture: From electrochemical mechanism to bench-scale visualization study," Applied Energy, Elsevier, vol. 302(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:15:y:2023:i:17:p:13044-:d:1228470. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.