IDEAS home Printed from https://ideas.repec.org/a/gam/jijerp/v19y2022i10p6037-d816496.html
   My bibliography  Save this article

Magnetic Nanoparticle-Based Dispersive Solid-Phase Microextraction of Three UV Blockers Prior to Their Determination by HPLC-DAD

Author

Listed:
  • Suad E. Abughrin

    (Department of Analytical Chemistry, Faculty of Pharmacy, Near East University, TRNC, Mersin 10, Nicosia 99138, Turkey
    Center for Solar Energy Research and Studies, Department of Renewable Energy, Libyan Authority for Scientific Research, Tripoli P.O. Box 30454, Libya)

  • Usama Alshana

    (Department of Analytical Chemistry, Faculty of Pharmacy, Near East University, TRNC, Mersin 10, Nicosia 99138, Turkey
    Department of Chemistry, College of Science, Sultan Qaboos University, 123 Al Khod, Muscat P.O. Box 50, Oman)

  • Sezgin Bakirdere

    (Department of Chemistry, Faculty of Arts and Science, Yıldız Technical University, Istanbul 34349, Turkey)

Abstract

The need for proper handling of environmental samples is significant, owing to their environmental effects on both humans and animals, as well as their immediate surroundings. In the current study, magnetic nanoparticle-based dispersive solid-phase microextraction was combined with high-performance liquid chromatography using a diode array as the detector (HPLC-DAD) for both the separation and determination of three different UV blockers, namely octocrylene, ethylhexyl methoxycinnamate, and avobenzone. The optimum conditions for the extraction were found to be as follows: Stearic acid magnetic nanoparticles (20 mg) as the sorbent, acetonitrile (100 µL) as the eluent, as well as a sample pH of 2.50, adsorption and desorption time of 1.0 min, with a 3.0 mL sample volume. The limits of detection were as low as 0.05 µg mL −1 . The coefficient of determination (R 2 ) was above 0.9950, while the percentages of relative recoveries (%RR) were between 81.2 and 112% for the three UV blockers from the environmental water samples and sunscreen products.

Suggested Citation

  • Suad E. Abughrin & Usama Alshana & Sezgin Bakirdere, 2022. "Magnetic Nanoparticle-Based Dispersive Solid-Phase Microextraction of Three UV Blockers Prior to Their Determination by HPLC-DAD," IJERPH, MDPI, vol. 19(10), pages 1-14, May.
    • Handle: RePEc:gam:jijerp:v:19:y:2022:i:10:p:6037-:d:816496
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1660-4601/19/10/6037/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1660-4601/19/10/6037/
    Download Restriction: no
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Tamara Tadić & Bojana Marković & Jelena Radulović & Jelena Lukić & Ljiljana Suručić & Aleksandra Nastasović & Antonije Onjia, 2022. "A Core-Shell Amino-Functionalized Magnetic Molecularly Imprinted Polymer Based on Glycidyl Methacrylate for Dispersive Solid-Phase Microextraction of Aniline," Sustainability, MDPI, vol. 14(15), pages 1-15, July.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jijerp:v:19:y:2022:i:10:p:6037-:d:816496. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.