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Plasma Glow Discharge as a Tool for Surface Modification of Catalytic Solid Oxides: A Case Study of La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3−δ Perovskite

Author

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  • Yanxiang Zhang

    (National Key Laboratory for Precision Hot Processing of Metals, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China)

  • Jingbo Ma

    (National Key Laboratory for Precision Hot Processing of Metals, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China)

  • Mei Li

    (CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China)

  • Yu Chen

    (Center for Innovative Fuel Cell and Battery Technologies, School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA)

  • Mufu Yan

    (National Key Laboratory for Precision Hot Processing of Metals, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China)

  • Changrong Xia

    (CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China)

Abstract

Performance of solid oxide fuel cells (SOFCs) is hindered by the sluggish catalytic kinetics on the surfaces of cathode materials. It has recently been reported that improved electrochemical activity of perovskite oxides can be obtained with the cations or the oxides of some metallic elements at the surface. Here, we used a cost-effective plasma glow charge method as a generic tool to deposit nano-size metallic particles onto the surface of SOFC materials. Ni nano-scale patterns were successfully coated on the La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3−δ (LSCF) surface. The microstructure could be well controlled. The kinetics of oxygen exchange on the modified LSCF surface was promoted significantly, confirmed by electrical conductivity relaxation (ECR) measurement.

Suggested Citation

  • Yanxiang Zhang & Jingbo Ma & Mei Li & Yu Chen & Mufu Yan & Changrong Xia, 2016. "Plasma Glow Discharge as a Tool for Surface Modification of Catalytic Solid Oxides: A Case Study of La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3−δ Perovskite," Energies, MDPI, vol. 9(10), pages 1-8, September.
    • Handle: RePEc:gam:jeners:v:9:y:2016:i:10:p:786-:d:79291
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    References listed on IDEAS

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    1. Choudhury, Arnab & Chandra, H. & Arora, A., 2013. "Application of solid oxide fuel cell technology for power generation—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 20(C), pages 430-442.
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