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Co-Pyrolysis of Woody Biomass and Oil Shale—A Kinetics and Modelling Study

Author

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  • Alejandro Lyons Ceron

    (Department of Energy Technology, Tallinn University of Technology, 19086 Tallinn, Estonia)

  • Richard Ochieng

    (Department of Manufacturing and Civil Engineering, Faculty of Engineering, Norwegian University of Science and Technology, 2815 Gjøvik, Norway)

  • Shiplu Sarker

    (Department of Manufacturing and Civil Engineering, Faculty of Engineering, Norwegian University of Science and Technology, 2815 Gjøvik, Norway)

  • Oliver Järvik

    (Department of Energy Technology, Tallinn University of Technology, 19086 Tallinn, Estonia)

  • Alar Konist

    (Department of Energy Technology, Tallinn University of Technology, 19086 Tallinn, Estonia)

Abstract

The co-pyrolysis of biomass and fossil fuels has been the subject of studies on sustainable energy. Co-feeding oil shale with woody biomass can contribute to a transition into carbon neutrality. The present study analysed the thermal decomposition behaviour of oil shale and biomass blends (0:1, 3:7, 1:1, 7:3, 9:1, and 1:0) through thermogravimetric analysis (TGA) at 80–630 °C with a heating rate of 10 °C/min in CO 2 and N 2 atmospheres. A comparison of theoretical and experimental residual mass yields of oil shale–biomass mixtures indicated no significant interactions between the fuels. The blends contributed to a decrease of up to 34.4 wt% in solid residues compared to individual pyrolysis of oil shale, and the TGA curves were shifted from up to 10 °C to a lower temperature when the biomass ratio increased. The use of a CO 2 atmosphere resulted in the production of solid residues, comparable to the one obtained with the N 2 atmosphere. CO 2 atmosphere can be used in oil shale–biomass co-pyrolysis, without affecting the decomposition process or increasing the yield of residues. A kinetic model method is proposed based on TGA data at 10, 20, and 30 °C/min. The apparent activation energies for a temperature range of 200–520 °C were in the order of 139, 155, 164, 197, 154, and 167 kJ/mol for oil shale–biomass 0:1, 3:7, 1:1, 7:3, 9:1, and 1:0 blends, respectively. From the isoconversional kinetic analysis, a two-stage pyrolysis was observed, which separated biomass and oil shale pyrolysis. A simulation of biomass and oil shale co-pyrolysis was conducted in Aspen Plus ® using TGA-derived kinetic data. The model prediction resulted in a close match with the experimental thermogravimetric data with absolute errors from 1.75 to 3.78%, which highlights the relevance of TGA analysis in simulating co-pyrolysis processes.

Suggested Citation

  • Alejandro Lyons Ceron & Richard Ochieng & Shiplu Sarker & Oliver Järvik & Alar Konist, 2024. "Co-Pyrolysis of Woody Biomass and Oil Shale—A Kinetics and Modelling Study," Energies, MDPI, vol. 17(5), pages 1-18, February.
  • Handle: RePEc:gam:jeners:v:17:y:2024:i:5:p:1055-:d:1344511
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    References listed on IDEAS

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    1. Joeri Rogelj & Michel den Elzen & Niklas Höhne & Taryn Fransen & Hanna Fekete & Harald Winkler & Roberto Schaeffer & Fu Sha & Keywan Riahi & Malte Meinshausen, 2016. "Paris Agreement climate proposals need a boost to keep warming well below 2 °C," Nature, Nature, vol. 534(7609), pages 631-639, June.
    2. Han, X.X. & Jiang, X.M. & Cui, Z.G., 2009. "Studies of the effect of retorting factors on the yield of shale oil for a new comprehensive utilization technology of oil shale," Applied Energy, Elsevier, vol. 86(11), pages 2381-2385, November.
    3. Lee, Jechan & Yang, Xiao & Cho, Seong-Heon & Kim, Jae-Kon & Lee, Sang Soo & Tsang, Daniel C.W. & Ok, Yong Sik & Kwon, Eilhann E., 2017. "Pyrolysis process of agricultural waste using CO2 for waste management, energy recovery, and biochar fabrication," Applied Energy, Elsevier, vol. 185(P1), pages 214-222.
    4. Haykiri-Acma, H. & Yaman, S., 2010. "Interaction between biomass and different rank coals during co-pyrolysis," Renewable Energy, Elsevier, vol. 35(1), pages 288-292.
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