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Green Production of Biodiesel from High Acid Value Oil via Glycerol Esterification and Transesterification Catalyzed by Nano Hydrated Eggshell-Derived CaO

Author

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  • Zhenghui Weng

    (Biodiesel Laboratory of China Petroleum and Chemical Industry Federation, Zhejiang Provincial Key Laboratory of Biofuel, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China)

  • Yuanzhe Tao

    (Biodiesel Laboratory of China Petroleum and Chemical Industry Federation, Zhejiang Provincial Key Laboratory of Biofuel, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China)

  • Haotian Fei

    (Biodiesel Laboratory of China Petroleum and Chemical Industry Federation, Zhejiang Provincial Key Laboratory of Biofuel, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China)

  • Weishan Deng

    (Biodiesel Laboratory of China Petroleum and Chemical Industry Federation, Zhejiang Provincial Key Laboratory of Biofuel, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China)

  • Yiyao Chen

    (Biodiesel Laboratory of China Petroleum and Chemical Industry Federation, Zhejiang Provincial Key Laboratory of Biofuel, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China)

  • Zhiqi Zhao

    (Biodiesel Laboratory of China Petroleum and Chemical Industry Federation, Zhejiang Provincial Key Laboratory of Biofuel, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China)

  • Xiaojiang Liang

    (Biodiesel Laboratory of China Petroleum and Chemical Industry Federation, Zhejiang Provincial Key Laboratory of Biofuel, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China)

  • Yong Nie

    (Biodiesel Laboratory of China Petroleum and Chemical Industry Federation, Zhejiang Provincial Key Laboratory of Biofuel, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China)

Abstract

Biodiesel is a widely recognized and favored liquid biofuel, primarily attributed to its biodegradability and non-toxicity. However, the development of biodiesel is hindered by its high production costs. Here, we developed a method that combines glycerol esterification and transesterification reaction catalyzed using nano-hydrated CaO for the green production of biodiesel from high acid value oil. Waste eggshell was chosen as the calcium source to examine the effect of hydration temperature and duration. The catalysts were optimized using a synthesis process involving under calcination for 3 h at 875 °C, followed by hydration at 60 °C for 6 h and subsequent dehydration at 725 °C. The catalyst loading, alcohol-to-oil mass ratio, reaction temperature, and duration were optimized to 2.5 wt%, 35%, 60 °C, and 2 h, respectively. Under the optimized conditions, the yield of fatty acid methyl ester reached 94.44%. The catalyst was successfully reused eight cycles while maintaining a yield of fatty acid methyl ester at 80.52%. In addition, a comprehensive overview was summarized to compare the catalyst preparation methods, reaction conditions, biodiesel yield, and reusability in the production of biodiesel using eggshell-derived CaO.

Suggested Citation

  • Zhenghui Weng & Yuanzhe Tao & Haotian Fei & Weishan Deng & Yiyao Chen & Zhiqi Zhao & Xiaojiang Liang & Yong Nie, 2023. "Green Production of Biodiesel from High Acid Value Oil via Glycerol Esterification and Transesterification Catalyzed by Nano Hydrated Eggshell-Derived CaO," Energies, MDPI, vol. 16(18), pages 1-16, September.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:18:p:6717-:d:1243696
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    References listed on IDEAS

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    1. Hoora Mazaheri & Hwai Chyuan Ong & Zeynab Amini & Haji Hassan Masjuki & M. Mofijur & Chia Hung Su & Irfan Anjum Badruddin & T.M. Yunus Khan, 2021. "An Overview of Biodiesel Production via Calcium Oxide Based Catalysts: Current State and Perspective," Energies, MDPI, vol. 14(13), pages 1-23, July.
    2. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
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