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Impact of Alkyl-Based Side Chains in Conjugated Materials for Bulk Heterojunction Organic Photovoltaic Cells—A Review

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  • Kathleen Isabelle Moineau-Chane Ching

    (CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, CEDEX 4, 31077 Toulouse, France
    LCC-CNRS, Université de Toulouse, CNRS, INPT, UPS, CEDEX 4, 31077 Toulouse, France)

Abstract

The research for efficient organic materials organized in bulk heterojunction (BHJ) thin films for organic photovoltaics (OPVs) has shown a significant breakthrough in the past decade. Desired structural organization can be attained through various strategies. In this regard, the current review highlights tuning of alkyl chains introduced on molecular structures of active materials. The recent wide literature is classified based on the introduction of alkyl chains on polymers and small molecules used as donor and acceptor materials. The design of these materials, the morphological aspects of the active layers, and the performances of the related photovoltaic cells are detailed. A comprehensive discussion on chemical structures of the different material families considered, their modification by alkyl chains of various natures, and the morphological aspects are reported and tabulated.

Suggested Citation

  • Kathleen Isabelle Moineau-Chane Ching, 2023. "Impact of Alkyl-Based Side Chains in Conjugated Materials for Bulk Heterojunction Organic Photovoltaic Cells—A Review," Energies, MDPI, vol. 16(18), pages 1-33, September.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:18:p:6639-:d:1240903
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    References listed on IDEAS

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    1. Xuelin Wang & Qianqian Sun & Jinhua Gao & Jian Wang & Chunyu Xu & Xiaoling Ma & Fujun Zhang, 2021. "Recent Progress of Organic Photovoltaics with Efficiency over 17%," Energies, MDPI, vol. 14(14), pages 1-27, July.
    2. Peter Peumans & Soichi Uchida & Stephen R. Forrest, 2003. "Efficient bulk heterojunction photovoltaic cells using small-molecular-weight organic thin films," Nature, Nature, vol. 425(6954), pages 158-162, September.
    3. Mehmood, Umer & Al-Ahmed, Amir & Hussein, Ibnelwaleed A., 2016. "Review on recent advances in polythiophene based photovoltaic devices," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 550-561.
    4. Boudia Mohamed El Amine & Yi Zhou & Hongying Li & Qiuwang Wang & Jun Xi & Cunlu Zhao, 2023. "Latest Updates of Single-Junction Organic Solar Cells up to 20% Efficiency," Energies, MDPI, vol. 16(9), pages 1-12, May.
    5. Nora Schopp & Viktor V. Brus, 2022. "A Review on the Materials Science and Device Physics of Semitransparent Organic Photovoltaics," Energies, MDPI, vol. 15(13), pages 1-15, June.
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    1. Agata Szlapa-Kula & Przemyslaw Ledwon & Agnieszka Krawiec & Slawomir Kula, 2023. "Dibenzofulvene Derivatives as Promising Materials for Photovoltaic and Organic Electronics," Energies, MDPI, vol. 16(24), pages 1-40, December.

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