IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v16y2023i18p6634-d1240571.html
   My bibliography  Save this article

Thermal Characterization, Kinetic Analysis and Co-Combustion of Sewage Sludge Coupled with High Ash Ekibastuz Coal

Author

Listed:
  • Madiyar Aidabulov

    (Chemical and Materials Engineering, School of Engineering and Digital Sciences, Nazarbayev University, Astana 010000, Kazakhstan)

  • Daulet Zhakupov

    (Chemical and Materials Engineering, School of Engineering and Digital Sciences, Nazarbayev University, Astana 010000, Kazakhstan)

  • Khabiba Zhunussova

    (Chemical and Materials Engineering, School of Engineering and Digital Sciences, Nazarbayev University, Astana 010000, Kazakhstan)

  • Aknur Temireyeva

    (Chemical and Materials Engineering, School of Engineering and Digital Sciences, Nazarbayev University, Astana 010000, Kazakhstan)

  • Dhawal Shah

    (Chemical and Materials Engineering, School of Engineering and Digital Sciences, Nazarbayev University, Astana 010000, Kazakhstan)

  • Yerbol Sarbassov

    (Mechanical and Aerospace Engineering, School of Engineering and Digital Sciences, Nazarbayev University, Astana 010000, Kazakhstan)

Abstract

Efficient utilization of natural resources and possible valorization of solid waste materials such as sewage sludge into secondary materials via thermal conversion and simultaneously recovering energy is vital for sustainable development. The continuous increase in metropolises leads to an enormous production of wet sewage sludge, which creates major environmental and technical issues. In this paper, the samples of sewage sludge from Astana’s waste water treatment plant are analyzed for their thermochemical properties, followed by thermogravimetric and kinetic analysis using the Flynn–Wall–Ozawa and Kissinger–Akahira–Sunose methods. Overall, the calorific value of sewage sludge sample was 18.87 MJ/kg and was comparable to that of the bituminous coal samples. The activation energy varied from 140 to 410 kJ/mol with changing conversion from 0.1 to 0.7. Further, mono-combustion and co-combustion experiments of the sewage sludge with high ash bituminous coal were conducted using the laboratory scale bubbling fluidized bed rig, respectively. The difference in NO x emissions between mono-combustion of sewage sludge and co-combustion with coal were at around 150 ppm, while this value for SO 2 was similar in average, but fluctuates between 150 and 350 ppm. Overall, the findings of this study will be useful in developing a co-combustion technology for a sustainable disposal of municipal sewage sludge.

Suggested Citation

  • Madiyar Aidabulov & Daulet Zhakupov & Khabiba Zhunussova & Aknur Temireyeva & Dhawal Shah & Yerbol Sarbassov, 2023. "Thermal Characterization, Kinetic Analysis and Co-Combustion of Sewage Sludge Coupled with High Ash Ekibastuz Coal," Energies, MDPI, vol. 16(18), pages 1-13, September.
  • Handle: RePEc:gam:jeners:v:16:y:2023:i:18:p:6634-:d:1240571
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/16/18/6634/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/16/18/6634/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Boris V. Malozyomov & Nikita V. Martyushev & Elena V. Voitovich & Roman V. Kononenko & Vladimir Yu. Konyukhov & Vadim Tynchenko & Viktor Alekseevich Kukartsev & Yadviga Aleksandrovna Tynchenko, 2023. "Designing the Optimal Configuration of a Small Power System for Autonomous Power Supply of Weather Station Equipment," Energies, MDPI, vol. 16(13), pages 1-30, June.
    2. Gabriele Di Giacomo & Pietro Romano, 2022. "Evolution and Prospects in Managing Sewage Sludge Resulting from Municipal Wastewater Purification," Energies, MDPI, vol. 15(15), pages 1-33, August.
    3. Nadziakiewicz, Jan & Koziol, Michal, 2003. "Co-combustion of sludge with coal," Applied Energy, Elsevier, vol. 75(3-4), pages 239-248, July.
    4. Boris V. Malozyomov & Vladimir Ivanovich Golik & Vladimir Brigida & Vladislav V. Kukartsev & Yadviga A. Tynchenko & Andrey A. Boyko & Sergey V. Tynchenko, 2023. "Substantiation of Drilling Parameters for Undermined Drainage Boreholes for Increasing Methane Production from Unconventional Coal-Gas Collectors," Energies, MDPI, vol. 16(11), pages 1-16, May.
    5. Sarbassov, Yerbol & Kerimray, Aiymgul & Tokmurzin, Diyar & Tosato, GianCarlo & De Miglio, Rocco, 2013. "Electricity and heating system in Kazakhstan: Exploring energy efficiency improvement paths," Energy Policy, Elsevier, vol. 60(C), pages 431-444.
    6. Cheynesh B. Kongar-Syuryun & Alexander V. Aleksakhin & Evgeniya N. Eliseeva & Anna V. Zhaglovskaya & Roman V. Klyuev & Denis A. Petrusevich, 2023. "Modern Technologies Providing a Full Cycle of Geo-Resources Development," Resources, MDPI, vol. 12(4), pages 1-14, April.
    7. Wendi Chen & Fei Wang & Altaf Hussain Kanhar, 2017. "Sludge Acts as a Catalyst for Coal during the Co-Combustion Process Investigated by Thermogravimetric Analysis," Energies, MDPI, vol. 10(12), pages 1-11, December.
    8. Xuan Zhang & Xian-qing Wang & Dong-fang Wang, 2017. "Immobilization of Heavy Metals in Sewage Sludge during Land Application Process in China: A Review," Sustainability, MDPI, vol. 9(11), pages 1-19, November.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Nikita V. Martyushev & Boris V. Malozyomov & Svetlana N. Sorokova & Egor A. Efremenkov & Denis V. Valuev & Mengxu Qi, 2023. "Review Models and Methods for Determining and Predicting the Reliability of Technical Systems and Transport," Mathematics, MDPI, vol. 11(15), pages 1-31, July.
    2. Pavel V. Shishkin & Boris V. Malozyomov & Nikita V. Martyushev & Svetlana N. Sorokova & Egor A. Efremenkov & Denis V. Valuev & Mengxu Qi, 2024. "Development of a Mathematical Model of Operation Reliability of Mine Hoisting Plants," Mathematics, MDPI, vol. 12(12), pages 1-26, June.
    3. Boris V. Malozyomov & Nikita V. Martyushev & Svetlana N. Sorokova & Egor A. Efremenkov & Denis V. Valuev & Mengxu Qi, 2024. "Analysis of a Predictive Mathematical Model of Weather Changes Based on Neural Networks," Mathematics, MDPI, vol. 12(3), pages 1-17, February.
    4. Vladimir Brigida & Vladimir Ivanovich Golik & Elena V. Voitovich & Vladislav V. Kukartsev & Valeriy E. Gozbenko & Vladimir Yu. Konyukhov & Tatiana A. Oparina, 2024. "Technogenic Reservoirs Resources of Mine Methane When Implementing the Circular Waste Management Concept," Resources, MDPI, vol. 13(2), pages 1-14, February.
    5. Pavel V. Shishkin & Boris V. Malozyomov & Nikita V. Martyushev & Svetlana N. Sorokova & Egor A. Efremenkov & Denis V. Valuev & Mengxu Qi, 2024. "Mathematical Logic Model for Analysing the Controllability of Mining Equipment," Mathematics, MDPI, vol. 12(11), pages 1-20, May.
    6. Karatayev, Marat & Clarke, Michèle L., 2016. "A review of current energy systems and green energy potential in Kazakhstan," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 491-504.
    7. Pietro Romano & Nicola Stampone & Gabriele Di Giacomo, 2023. "Evolution and Prospects of Hydrothermal Carbonization," Energies, MDPI, vol. 16(7), pages 1-11, March.
    8. Valdas Rudelis & Tadas Dambrauskas & Agne Grineviciene & Kestutis Baltakys, 2019. "The Prospective Approach for the Reduction of Fluoride Ions Mobility in Industrial Waste by Creating Products of Commercial Value," Sustainability, MDPI, vol. 11(3), pages 1-18, January.
    9. Malwina Tytła, 2020. "Identification of the Chemical Forms of Heavy Metals in Municipal Sewage Sludge as a Critical Element of Ecological Risk Assessment in Terms of Its Agricultural or Natural Use," IJERPH, MDPI, vol. 17(13), pages 1-22, June.
    10. Li, Shiyuan & Xu, Mingxin & Jia, Lufei & Tan, Li & Lu, Qinggang, 2016. "Influence of operating parameters on N2O emission in O2/CO2 combustion with high oxygen concentration in circulating fluidized bed," Applied Energy, Elsevier, vol. 173(C), pages 197-209.
    11. Boris V. Malozyomov & Nikita V. Martyushev & Nikita V. Babyr & Alexander V. Pogrebnoy & Egor A. Efremenkov & Denis V. Valuev & Aleksandr E. Boltrushevich, 2024. "Modelling of Reliability Indicators of a Mining Plant," Mathematics, MDPI, vol. 12(18), pages 1-26, September.
    12. MacGregor, James, 2017. "Determining an optimal strategy for energy investment in Kazakhstan," Energy Policy, Elsevier, vol. 107(C), pages 210-224.
    13. Qiang Zhong & Jian Zhang & Yongbin Yang & Qian Li & Bin Xu & Tao Jiang, 2018. "Thermal Behavior of Coal Used in Rotary Kiln and Its Combustion Intensification," Energies, MDPI, vol. 11(5), pages 1-12, April.
    14. Vladimír Frišták & Diana Bošanská & Vladimír Turčan & Martin Pipíška & Christoph Pfeifer & Gerhard Soja, 2022. "Relevance of Pyrolysis Products Derived from Sewage Sludge for Soil Applications," Agriculture, MDPI, vol. 13(1), pages 1-14, December.
    15. Gómez, Antonio & Dopazo, César & Fueyo, Norberto, 2014. "The causes of the high energy intensity of the Kazakh economy: A characterization of its energy system," Energy, Elsevier, vol. 71(C), pages 556-568.
    16. Di Liang & Yimin Li & Zhongning Zhou, 2022. "Numerical Study of Thermochemistry and Trace Element Behavior during the Co-Combustion of Coal and Sludge in Boiler," Energies, MDPI, vol. 15(3), pages 1-16, January.
    17. Boris V. Malozyomov & Nikita V. Martyushev & Elena V. Voitovich & Roman V. Kononenko & Vladimir Yu. Konyukhov & Vadim Tynchenko & Viktor Alekseevich Kukartsev & Yadviga Aleksandrovna Tynchenko, 2023. "Designing the Optimal Configuration of a Small Power System for Autonomous Power Supply of Weather Station Equipment," Energies, MDPI, vol. 16(13), pages 1-30, June.
    18. Jia Wu & Na Wu & Qiang Feng & Chenning Deng & Xiaomin Zhang & Zeqiang Fu & Zeqian Zhang & Haisheng Li, 2023. "Design and Optimization of a Coal Substitution Path Based on Cost–Benefit Analysis: Evidence from Coal Resource-Based Cities in China," Sustainability, MDPI, vol. 15(21), pages 1-14, October.
    19. Shuncun Zhang & Tao Wang & Hao Wang & Qiangqiang Kang & Qian Zhou & Bo Chen, 2022. "Spatial Pattern, Sources Identification, and Risk Assessment of Heavy Metals in a Typical Soda Soil from Bayannur, Northwestern China," IJERPH, MDPI, vol. 19(21), pages 1-16, October.
    20. Anna Turek & Kinga Wieczorek & Wojciech M. Wolf, 2019. "Digestion Procedure and Determination of Heavy Metals in Sewage Sludge—An Analytical Problem," Sustainability, MDPI, vol. 11(6), pages 1-10, March.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:16:y:2023:i:18:p:6634-:d:1240571. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.