IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v16y2023i15p5688-d1205796.html
   My bibliography  Save this article

Utilizing Sewage Sludge Slag, a By-Product of the Circulating Fluidized Bed Combustion Process, to Efficiently Remove Copper from Aquatic Environment

Author

Listed:
  • Tomasz Kalak

    (Department of Industrial Products and Packaging Quality, Institute of Quality Science, Poznań University of Economics and Business, Niepodległości 10, 61-875 Poznań, Poland)

  • Yu Tachibana

    (Department of Nuclear System Safety Engineering, Graduate School of Engineering, Nagaoka University of Technology, 1603-1, Nagaoka 940-2188, Japan)

Abstract

Currently, one of the greatest threats to the aquatic environment is industrial wastewater containing heavy metals and other toxic substances. Hence, it seems necessary to search for ecological and cheap technologies for removing metals from wastewater. In this research, slag was used as waste obtained in the circulating fluidized bed combustion technology (CFBC), which is considered to be a modern, clean, and very effective method of incineration of municipal sewage sludge. The physicochemical properties of the waste material were characterized using selected analytical techniques. Next, the processes of adsorption of Cu(II) ions on slag in aqueous solutions were investigated. The results showed a high metal removal efficiency of 98.8% at pH 1.8 and slag dosage 5 g/L. Numerous studies have demonstrated that high process efficiency at a level of at least 90% is attainable. Based on the Langmuir equation, the maximum adsorption capacity was calculated to be 70.3 mg/g. Kinetic analysis revealed that the process fits better into the pseudo-second-order reaction model and the Freundlich isotherm. The intraparticle diffusion model was considered as a rate-controlling step for Cu(II) adsorption. In summary, the slag waste produced in the CFBC technology seems to be a highly effective adsorbent for potential use in adsorption processes to remove heavy metals from the aquatic environment. This solution is in line with the current European ‘zero waste’ strategy and the assumptions of a sustainable development economy.

Suggested Citation

  • Tomasz Kalak & Yu Tachibana, 2023. "Utilizing Sewage Sludge Slag, a By-Product of the Circulating Fluidized Bed Combustion Process, to Efficiently Remove Copper from Aquatic Environment," Energies, MDPI, vol. 16(15), pages 1-24, July.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:15:p:5688-:d:1205796
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/16/15/5688/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/16/15/5688/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Fytili, D. & Zabaniotou, A., 2008. "Utilization of sewage sludge in EU application of old and new methods--A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(1), pages 116-140, January.
    2. Yuansheng, Huang & Mengshu, Shi, 2021. "What are the environmental advantages of circulating fluidized bed technology? ——A case study in China," Energy, Elsevier, vol. 220(C).
    3. Xinhui Zhan & Liping Xiao & Bing Liang, 2019. "Removal of Pb(II) from Acid Mine Drainage with Bentonite-Steel Slag Composite Particles," Sustainability, MDPI, vol. 11(16), pages 1-17, August.
    4. Bertanza, Giorgio & Baroni, Pietro & Canato, Matteo, 2016. "Ranking sewage sludge management strategies by means of Decision Support Systems: A case study," Resources, Conservation & Recycling, Elsevier, vol. 110(C), pages 1-15.
    5. Tomasz Kalak, 2023. "Potential Use of Industrial Biomass Waste as a Sustainable Energy Source in the Future," Energies, MDPI, vol. 16(4), pages 1-25, February.
    6. Dinko Đurđević & Saša Žiković & Paolo Blecich, 2022. "Sustainable Sewage Sludge Management Technologies Selection Based on Techno-Economic-Environmental Criteria: Case Study of Croatia," Energies, MDPI, vol. 15(11), pages 1-23, May.
    7. Marzena Smol, 2020. "Inventory of Wastes Generated in Polish Sewage Sludge Incineration Plants and Their Possible Circular Management Directions," Resources, MDPI, vol. 9(8), pages 1-24, July.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Dinko Đurđević & Saša Žiković & Paolo Blecich, 2022. "Sustainable Sewage Sludge Management Technologies Selection Based on Techno-Economic-Environmental Criteria: Case Study of Croatia," Energies, MDPI, vol. 15(11), pages 1-23, May.
    2. Shahbeig, Hossein & Nosrati, Mohsen, 2020. "Pyrolysis of municipal sewage sludge for bioenergy production: Thermo-kinetic studies, evolved gas analysis, and techno-socio-economic assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    3. Sanchez, M.E. & Otero, M. & Gómez, X. & Morán, A., 2009. "Thermogravimetric kinetic analysis of the combustion of biowastes," Renewable Energy, Elsevier, vol. 34(6), pages 1622-1627.
    4. Seongmin Kang & Changsang Cho & Ki-Hyun Kim & Eui-chan Jeon, 2018. "Fossil Carbon Fraction and Measuring Cycle for Sewage Sludge Waste Incineration," Sustainability, MDPI, vol. 10(8), pages 1-8, August.
    5. Jiawen Zhang & Zhiyi Liang & Toru Matsumoto & Tiejia Zhang, 2022. "Environmental and Economic Implication of Implementation Scale of Sewage Sludge Recycling Systems Considering Carbon Trading Price," Sustainability, MDPI, vol. 14(14), pages 1-16, July.
    6. Bidart, Christian & Fröhling, Magnus & Schultmann, Frank, 2014. "Electricity and substitute natural gas generation from the conversion of wastewater treatment plant sludge," Applied Energy, Elsevier, vol. 113(C), pages 404-413.
    7. Wang, Liping & Chang, Yuzhi & Li, Aimin, 2019. "Hydrothermal carbonization for energy-efficient processing of sewage sludge: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 423-440.
    8. Faubert, Patrick & Barnabé, Simon & Bouchard, Sylvie & Côté, Richard & Villeneuve, Claude, 2016. "Pulp and paper mill sludge management practices: What are the challenges to assess the impacts on greenhouse gas emissions?," Resources, Conservation & Recycling, Elsevier, vol. 108(C), pages 107-133.
    9. Junshen Qu & Daiying Wang & Zeyu Deng & Hejie Yu & Jianjun Dai & Xiaotao Bi, 2023. "Biochar Prepared by Microwave-Assisted Co-Pyrolysis of Sewage Sludge and Cotton Stalk: A Potential Soil Conditioner," Sustainability, MDPI, vol. 15(9), pages 1-18, April.
    10. Magdziarz, Aneta & Wilk, Małgorzata & Gajek, Marcin & Nowak-Woźny, Dorota & Kopia, Agnieszka & Kalemba-Rec, Izabela & Koziński, Janusz A., 2016. "Properties of ash generated during sewage sludge combustion: A multifaceted analysis," Energy, Elsevier, vol. 113(C), pages 85-94.
    11. Praspaliauskas, M. & Pedišius, N., 2017. "A review of sludge characteristics in Lithuania's wastewater treatment plants and perspectives of its usage in thermal processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 899-907.
    12. Grzegorz Maj & Kamil Buczyński & Kamila E. Klimek & Magdalena Kapłan, 2024. "Evaluation of Growth and Energy Parameters of One-Year-Old Raspberry Shoots, Depending on the Variety," Energies, MDPI, vol. 17(13), pages 1-12, June.
    13. Beegle, Jeffrey R. & Borole, Abhijeet P., 2018. "Energy production from waste: Evaluation of anaerobic digestion and bioelectrochemical systems based on energy efficiency and economic factors," Renewable and Sustainable Energy Reviews, Elsevier, vol. 96(C), pages 343-351.
    14. Vito Horvatić & Helena Bakić Begić & Davor Romić & Marko Černe & Smiljana Goreta Ban & Monika Zovko & Marija Romić, 2021. "Evaluation of Land Potential for Use of Biosolids in the Coastal Mediterranean Karst Region," Land, MDPI, vol. 10(10), pages 1-22, October.
    15. Zhai, Yunbo & Peng, Chuan & Xu, Bibo & Wang, Tengfei & Li, Caiting & Zeng, Guangming & Zhu, Yun, 2017. "Hydrothermal carbonisation of sewage sludge for char production with different waste biomass: Effects of reaction temperature and energy recycling," Energy, Elsevier, vol. 127(C), pages 167-174.
    16. Tan, Kun & Zhao, Xiaoqing & Pu, Junwei & Li, Sinan & Li, Yuhao & Miao, Peipei & Wang, Qian, 2021. "Zoning regulation and development model for water and land resources in the Karst Mountainous Region of Southwest China," Land Use Policy, Elsevier, vol. 109(C).
    17. Dinko Đurđević & Saša Žiković & Tomislav Čop, 2022. "Socio-Economic, Technical and Environmental Indicators for Sustainable Sewage Sludge Management and LEAP Analysis of Emissions Reduction," Energies, MDPI, vol. 15(16), pages 1-15, August.
    18. Wu, Junnan & Liao, Yanfen & Lin, Yan & Tian, Yunlong & Ma, Xiaoqian, 2019. "Study on thermal decomposition kinetics model of sewage sludge and wheat based on multi distributed activation energy," Energy, Elsevier, vol. 185(C), pages 795-803.
    19. Gadsbøll, Rasmus Østergaard & Clausen, Lasse Røngaard & Thomsen, Tobias Pape & Ahrenfeldt, Jesper & Henriksen, Ulrik Birk, 2019. "Flexible TwoStage biomass gasifier designs for polygeneration operation," Energy, Elsevier, vol. 166(C), pages 939-950.
    20. Tsiligiannis, Aristeides & Tsiliyannis, Christos, 2020. "Oil refinery sludge and renewable fuel blends as energy sources for the cement industry," Renewable Energy, Elsevier, vol. 157(C), pages 55-70.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:16:y:2023:i:15:p:5688-:d:1205796. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.