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Solar Salt above 600 °C: Impact of Experimental Design on Thermodynamic Stability Results

Author

Listed:
  • Julian Steinbrecher

    (German Aerospace Center (DLR), Institute of Engineering Thermodynamics, D-70569 Stuttgart, Germany)

  • Markus Braun

    (German Aerospace Center (DLR), Institute of Engineering Thermodynamics, D-70569 Stuttgart, Germany)

  • Thomas Bauer

    (German Aerospace Center (DLR), Institute of Engineering Thermodynamics, D-51147 Cologne, Germany)

  • Sebastian Kunkel

    (German Aerospace Center (DLR), Institute of Engineering Thermodynamics, D-70569 Stuttgart, Germany)

  • Alexander Bonk

    (German Aerospace Center (DLR), Institute of Engineering Thermodynamics, D-70569 Stuttgart, Germany)

Abstract

Thermal energy storage (TES) based on molten salts has been identified as a key player in the transition from fossil fuels to renewable energy sources. Solar Salt, a mixture of NaNO 3 (60 wt%) and KNO 3 (40 wt%), is currently the most advanced heat transfer and storage material used in concentrating solar power (CSP) plants. Here, it is utilized to produce electricity via a Rankine cycle, with steam temperatures reaching 550 °C. The goal of this study is to increase the operating temperature of solar salt to over 600 °C, allowing it to be adapted for use in high-temperature Rankine cycles with steam temperatures greater than 600 °C. Yet, this goal is impaired by the lack of available thermodynamic data given the salt’s complex high-temperature decomposition and corrosion chemistry. The study explores the thermodynamics of the decomposition reactions in solar salt, with a focus on suppressing decomposition into corrosive oxide ions up to a temperature of 620 °C. The results provide a new understanding of the stabilization of solar salt at previously unexplored temperatures with effective utilization of gas management techniques.

Suggested Citation

  • Julian Steinbrecher & Markus Braun & Thomas Bauer & Sebastian Kunkel & Alexander Bonk, 2023. "Solar Salt above 600 °C: Impact of Experimental Design on Thermodynamic Stability Results," Energies, MDPI, vol. 16(14), pages 1-16, July.
  • Handle: RePEc:gam:jeners:v:16:y:2023:i:14:p:5241-:d:1189560
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    References listed on IDEAS

    as
    1. Wei, Xiaolan & Yang, Chuntao & Lu, Jianfeng & Wang, Weilong & Ding, Jing, 2017. "The mechanism of NOx emissions from binary molten nitrate salts contacting nickel base alloy in thermal energy storage process," Applied Energy, Elsevier, vol. 207(C), pages 265-273.
    2. Villada, Carolina & Bonk, Alexander & Bauer, Thomas & Bolívar, Francisco, 2018. "High-temperature stability of nitrate/nitrite molten salt mixtures under different atmospheres," Applied Energy, Elsevier, vol. 226(C), pages 107-115.
    3. Yang, Chuntao & Wei, Xiaolan & Wang, Weilong & Lin, Zihao & Ding, Jing & Wang, Yan & Peng, Qiang & Yang, Jianping, 2016. "NOx emissions and the component changes of ternary molten nitrate salts in thermal energy storage process," Applied Energy, Elsevier, vol. 184(C), pages 346-352.
    4. Bauer, Thomas & Pfleger, Nicole & Breidenbach, Nils & Eck, Markus & Laing, Doerte & Kaesche, Stefanie, 2013. "Material aspects of Solar Salt for sensible heat storage," Applied Energy, Elsevier, vol. 111(C), pages 1114-1119.
    5. Wei, Xiaolan & Wang, Yan & Peng, Qiang & Yang, Jianping & Yang, Xiaoxi & Ding, Jing, 2014. "NOx emissions and NO2- formation in thermal energy storage process of binary molten nitrate salts," Energy, Elsevier, vol. 74(C), pages 215-221.
    6. Bonk, Alexander & Braun, Markus & Sötz, Veronika A. & Bauer, Thomas, 2020. "Solar Salt – Pushing an old material for energy storage to a new limit," Applied Energy, Elsevier, vol. 262(C).
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