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Autothermal Siberian Pine Nutshell Pyrolysis Maintained by Exothermic Reactions

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  • Alexander Astafev

    (Institute of Environmental and Agricultural Biology (X-BIO), University of Tyumen, 6 Volodarskogo Street, 625003 Tyumen, Russia
    School of Energy and Power Engineering, National Research Tomsk Polytechnic University, 30 Lenina Avenue, 634050 Tomsk, Russia)

  • Ivan Shanenkov

    (Institute of Environmental and Agricultural Biology (X-BIO), University of Tyumen, 6 Volodarskogo Street, 625003 Tyumen, Russia)

  • Kanipa Ibraeva

    (Institute of Environmental and Agricultural Biology (X-BIO), University of Tyumen, 6 Volodarskogo Street, 625003 Tyumen, Russia)

  • Roman Tabakaev

    (Institute of Environmental and Agricultural Biology (X-BIO), University of Tyumen, 6 Volodarskogo Street, 625003 Tyumen, Russia
    School of Energy and Power Engineering, National Research Tomsk Polytechnic University, 30 Lenina Avenue, 634050 Tomsk, Russia)

  • Sergei Preis

    (Department of Materials and Environmental Technology, Tallinn University of Technology, 5 Ehitajate Tee, 19086 Tallinn, Estonia)

Abstract

The global energy industry works towards an increased use of carbon-neutral biomass. Nutshell represents a regional bio-waste, i.e., a bio-energy resource. Pyrolysis is a common method for processing biomass into valuable energy products. The heat demand, however, limits pyrolysis applications. Yet, such demand may be addressed via exothermic pyrolysis reactions under selected operation conditions. Making the pyrolysis of Siberian pine nutshell autothermic comprised the objective of the study. The study involved analytical methods together with a pyrolysis experiment. The analytical methods included a thermogravimetric analysis combined with differential scanning calorimetry and an integrated gas analyzer. Thermophysical characterization was executed using a thermal diffusivity analyzer with the laser flash method. At 650 °C, pyrolytic heat was released in the amount of 1224.6 kJ/kg, exceeding the heat demand of 1179.5 kJ/kg. Pyrolysis at a lower temperature of 550 °C remained endothermic, although the combusted gas product provided 847.7 kJ/kg of heat, which, together with exothermic release, covered the required heat demand for the pyrolysis process.

Suggested Citation

  • Alexander Astafev & Ivan Shanenkov & Kanipa Ibraeva & Roman Tabakaev & Sergei Preis, 2022. "Autothermal Siberian Pine Nutshell Pyrolysis Maintained by Exothermic Reactions," Energies, MDPI, vol. 15(19), pages 1-15, September.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:19:p:7118-:d:927678
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    References listed on IDEAS

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