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Synthesis of Biodiesel from Ricinus communis L. Seed Oil, a Promising Non-Edible Feedstock Using Calcium Oxide Nanoparticles as a Catalyst

Author

Listed:
  • Hammad Ahmad Jan

    (Department of Botany, University of Buner, Buner 19290, Pakistan)

  • Igor Šurina

    (Department of Wood, Pulp and Paper, Institute of Natural and Synthetic Polymers, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Radlinského 9, 812 37 Bratislava, Slovakia)

  • Akhtar Zaman

    (Department of Botany, University of Buner, Buner 19290, Pakistan)

  • Ahmed S. Al-Fatesh

    (Chemical Engineering Department, College of Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia)

  • Fazli Rahim

    (Department of Botany, Bacha Khan University, Charsadda 24420, Pakistan)

  • Raja L. Al-Otaibi

    (National Petrochemical Technology Center (NPTC), Materials Science Research Institute (MSRI), King Abdulaziz City for Science and Technology (KACST), P.O. Box 6086, Riyadh 11442, Saudi Arabia)

Abstract

This work aimed to synthesize biodiesel from Ricinus communis L., using calcium oxide (CaO) nanoparticles as a catalyst. The CaO nanoparticles were examined by scanning electron microscopy (SEM) and X-Ray Diffraction (XRD). The physico-chemical properties of biodiesel were studied through H and C-NMR, GC-MS, FT-IR, and fuel properties were studied according to ASTM and EN standard methods. The oil content of the feedstock was 53.7% with a free fatty acid (FFA) content of 0.89 mg KOH/g. The suitable condition for the optimum yield (89%) of biodiesel was 1:15 of oil to methanol using 20 mg of catalyst at a temperature of 60 °C for 80 to 100 min of reaction time. The H and C-NMR confirm the biodiesel synthesis by showing important peaks at 3.661, 2.015–2.788, 24.83–34.16 and 174.26 and 130.15 ppm. Similarly, GC-MS spectroscopy confirmed 18 different types of fatty acid methyl esters (FAME) in the biodiesel sample. FT-IR spectroscopy confirmed the synthesis of biodiesel by showing characteristic peaks of biodiesel formation in the range of 1725–1750 cm −1 and 1000–1300 cm −1 . The fuel properties were compared with the international ASTM and EN standards. The physico-chemical properties confirm that RCB is both an engine and environmentally friendly fuel.

Suggested Citation

  • Hammad Ahmad Jan & Igor Šurina & Akhtar Zaman & Ahmed S. Al-Fatesh & Fazli Rahim & Raja L. Al-Otaibi, 2022. "Synthesis of Biodiesel from Ricinus communis L. Seed Oil, a Promising Non-Edible Feedstock Using Calcium Oxide Nanoparticles as a Catalyst," Energies, MDPI, vol. 15(17), pages 1-15, September.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:17:p:6425-:d:905620
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    References listed on IDEAS

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    1. Vikas Sharma & Abul K. Hossain & Ganesh Duraisamy, 2021. "Experimental Investigation of Neat Biodiesels’ Saturation Level on Combustion and Emission Characteristics in a CI Engine," Energies, MDPI, vol. 14(16), pages 1-18, August.
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    Cited by:

    1. Hammad Ahmad Jan & Igor Šurina & Ahmed S. Al-Fatesh & Abdulaziz M. Almutlaq & Sher Wali & Anton Lisý, 2022. "Biodiesel Synthesis from Milk Thistle ( Silybum marianum (L.) Gaertn.) Seed Oil using ZnO Nanoparticles as a Catalyst," Energies, MDPI, vol. 15(20), pages 1-18, October.

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